GAO Fu-yong,ZHAO Ming,LI Ting-ting,FU Ya-nan.In Situ Imaging Study of the Formation Process of Chromium-free Chemical Conversion Coating of AZ31 Magnesium Alloy[J],(4):118-121
In Situ Imaging Study of the Formation Process of Chromium-free Chemical Conversion Coating of AZ31 Magnesium Alloy
Received:April 26, 2012  Revised:August 20, 2012
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KeyWord:magnesium alloy  synchrotron radiation  conversion coating  chemical composition
           
AuthorInstitution
GAO Fu-yong College of Mechanical and Electrical Engineering, North China University of Technology, Beijing , China
ZHAO Ming College of Mechanical and Electrical Engineering, North China University of Technology, Beijing , China
LI Ting-ting College of Mechanical and Electrical Engineering, North China University of Technology, Beijing , China
FU Ya-nan Chinese Academy of Sciences, Shanghai Institute of Applied Physics, Shanghai , China
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Abstract:
      The influences of H3PO4, KMnO4 and MnCO3 on the formation process of chromium-free chemical conversion coating at magnesium alloy/conversion treatment solution interface by using synchrotron radiation were in situ studied. Furthermore, we analyzed the surface morphology of magnesium alloys through the sweep electron microscopy. The result shows that the high-energy synchrotron radiation X-ray can penetrate through the magnesium alloy/conversion treatment solution interface, the formation process of conversion coating can be observed in real time using in situ imaging technology. The potassium permanganate can improved the formation of conversion coating significantly, and the surface of the coating is smooth with less cracks. However, manganous carbonate can limitely improve the formation of the coating.
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