XU Yi-bing,HE De-liang,ZHOU Zhou,ZHONG Jian-fang.Effects of Surfactant on Electrochemical Deposition of Silane Films on Aluminum Alloy[J],37(3):1-3,57
Effects of Surfactant on Electrochemical Deposition of Silane Films on Aluminum Alloy
Received:March 29, 2008  Revised:June 10, 2008
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KeyWord:Surfactant  Aluminum  Critical cathodic potential  Silane film  Electrochemical deposition
           
AuthorInstitution
XU Yi-bing State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha , China
HE De-liang State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha , China
ZHOU Zhou State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha , China
ZHONG Jian-fang State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha , China
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Abstract:
      The effect of surfactant on deposition of Bis-1,2-[ triethoxysilylpropyl] tetrasulfide ( BTSPS) silane films on aluminum alloy at different conditions was mvestigated by the electrochemical impedance spectroscopy ( EIS). The results show that the decreasing of electrodeposition potential, the hydrogen evolution and the improvement of interface region of electrode could be reached while the surfactant is added into the silane solution. It can be found that the optimum concentration of surfactant is 0.030/o , and a critical cathodic potential for silane deposition is -1. 6V under experimental conditions.
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