ZHANG Fan,YE Chen,CUI Nai-yuan,GUO Pei,WU Ming-liang,LYU Le,LIN Cheng-te,ZHAN Zhao-lin.Recent Advances in Surfactant Assisted Water-phase Exfoliation for Graphene Preparation[J],48(6):20-29
Recent Advances in Surfactant Assisted Water-phase Exfoliation for Graphene Preparation
Received:October 31, 2018  Revised:June 20, 2019
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DOI:10.16490/j.cnki.issn.1001-3660.2019.06.002
KeyWord:surfactant  graphene  liquid-phase exfoliation  water  dispersion  environmentally friendly
                       
AuthorInstitution
ZHANG Fan 1.School of Materials Science and Engineering, Kunming University of Science and Technology, Kunming , China; 2.Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Division of Surface Engineering and Remanufacturing, Ningbo Institute of Materials Technology and Engineering of Chinese Academy of Sciences, Ningbo ,China
YE Chen 2.Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Division of Surface Engineering and Remanufacturing, Ningbo Institute of Materials Technology and Engineering of Chinese Academy of Sciences, Ningbo ,China
CUI Nai-yuan 2.Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Division of Surface Engineering and Remanufacturing, Ningbo Institute of Materials Technology and Engineering of Chinese Academy of Sciences, Ningbo ,China
GUO Pei 2.Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Division of Surface Engineering and Remanufacturing, Ningbo Institute of Materials Technology and Engineering of Chinese Academy of Sciences, Ningbo ,China
WU Ming-liang 2.Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Division of Surface Engineering and Remanufacturing, Ningbo Institute of Materials Technology and Engineering of Chinese Academy of Sciences, Ningbo ,China
LYU Le 2.Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Division of Surface Engineering and Remanufacturing, Ningbo Institute of Materials Technology and Engineering of Chinese Academy of Sciences, Ningbo ,China
LIN Cheng-te 2.Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Division of Surface Engineering and Remanufacturing, Ningbo Institute of Materials Technology and Engineering of Chinese Academy of Sciences, Ningbo ,China
ZHAN Zhao-lin 1.School of Materials Science and Engineering, Kunming University of Science and Technology, Kunming , China
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Abstract:
      Surfactant-assisted aqueous phase exfoliation is an effective method for preparing high-quality graphene. The advantages of surfactant-assisted aqueous phase exfoliation method were summarized, including environmentally-friendly, suitable for large-scale production and can easily obtained high quality and high yield of graphene. On this basis, the research progress of different surfactant-assisted aqueous phase exfoliation methods in recent years was reviewed. Among them, ionic sur-factant-assisted exfoliation of graphene, including alkyl anionic surfactant-assisted exfoliation of graphite, biliary surfactant-assisted exfoliation of graphite and pyrene derivative-assisted exfoliation of graphite were emphasized. Non-ionic surfactant assisted graphene stripping, including polyvinyl pyrrolidone assisted graphite stripping, polyether surfactant assisted graphite stripping and polyvinyl imid-azole polymer assisted graphite stripping. The preparation process, physicochemical properties of surfactants and the structure and properties of prepared graphene were summarized and compared for various surfactant-assisted aqueous phase stripping methods. Finally, we prospected the development trend of liquid phase exfoliation method for preparing graphene.
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