WANG Xiu-min,ZHANG Yan-ru,HAO Yi-lei,CHENG Meng.Corrosin-resisting Behavior of the Hastelloy C-276 Alloy in the Bromine Glue Mixture[J],46(9):223-228
Corrosin-resisting Behavior of the Hastelloy C-276 Alloy in the Bromine Glue Mixture
Received:March 15, 2017  Revised:September 20, 2017
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DOI:10.16490/j.cnki.issn.1001-3660.2017.09.035
KeyWord:C-276 alloy  bromine  corrosin-resisting behavior  corrosion morphology  corrosion rate  corrosion law
           
AuthorInstitution
WANG Xiu-min China University of Petroleum, Qingdao , China
ZHANG Yan-ru Gas Storage Administrative Office of Huabei Oilfield Company, Langfang , China
HAO Yi-lei China University of Petroleum, Qingdao , China
CHENG Meng China University of Petroleum, Qingdao , China
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Abstract:
      To study the corrosion resistance, analyze the corrosion mechanism and failure mechanism of Hastelloy C-276 alloy in brominated butyl rubber solution. Weight-loss method was performed and the corrosion environment of Br-rubber mixer in brominated butyl rubber production process was simulated to research the effects of temperature, liquid bromine content, water content and rotating speed, ect. on the corrosion of Hastelloy C-276 alloy. Then Scanning electron microscope (SEM) and X-ray diffraction (XRD) techniques were respectively applied to characterize the corrosion morphology and corrosion products. Obtained results reveal that NiBr2, FeBr2, MoBr2, CrBr2, etc. were main corrosion products of Hastelloy C-276 alloy in the bromine-containing corrosion solution. The corrosion rate of Hastelloy C-276 alloy increased with temperature, water content, liquid bromine content and the rotating speed increase, which play important roles in Hastelloy C-276 alloy corrosion The corrosion mainly occurs in the form of general corrosion accompanied with intergranular corrosion. It is concluded that severe electrochemical corrosion of Hastelloy C-276 alloy happens in brominated butyl rubber environment and the increase of temperature, liquid bromine content, water content and rotating speed can obviously enhance the corrosion rate of Hastelloy C-276 alloy. Thus, Hastelloy C-276 alloy can not sever as the main material of Br-rubber mixer in the production of brominated butyl rubber.
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