JIA Ming-zi,ZHANG Zhe,RUAN Le,WU Feng-mei.Corrosion Inhibition Action of Imidazole Derivatives Self-assembled Films for 316 Stainless Steel[J],42(3):23-27,41
Corrosion Inhibition Action of Imidazole Derivatives Self-assembled Films for 316 Stainless Steel
  
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KeyWord:imidazole derivatives  self-assembled films  stainless steel  EIS  polarization curves
           
AuthorInstitution
JIA Ming-zi College of Chemistry and Bioengineering,Guilin University of Technology, Guilin , China
ZHANG Zhe College of Chemistry and Bioengineering,Guilin University of Technology, Guilin , China;Key Laboratory on New Building Energy and Energy Conservation of Guangxi, Guilin , China;Key Laboratory on New Technique of Applied Chemistry of Universities of Guangxi, Guilin , China
RUAN Le College of Chemistry and Bioengineering,Guilin University of Technology, Guilin , China
WU Feng-mei College of Chemistry and Bioengineering,Guilin University of Technology, Guilin , China
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Abstract:
      The corrosion inhibition action of imidazole, 1-dodecylimidazole, 1-benzylimidazole, benzimidazole self-assembled films for 316 stainless steel in 0 . 5 mol / L H2SO4solution was investigated by electrochemical impedance spectroscopy,polarization curves and quantum chemical calculations. Results showed that four inhibitors were all cathodic inhibitors and performed pretty inhibiting efficiency for 316 stainless steel . As the concentration of inhibitors were 1 X10-3mol / L,the longer the assembled time,the better the effect of inhibition. The inhibition efficiency of the four inhibitors was up to the value of EHOMO. The inhibition efficiency of the four inhibitors decreased as follows:benzimidazole>1-dodecylimidazole>1-benzylimidazole> imidazole.
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