高媛媛,田晓,张颖,张晓杰,韩家乐,李卫.储氢合金表面修饰方法的研究进展[J].表面技术,2025,54(8):51-63.
GAO Yuanyuan,TIAN Xiao,ZHANG Ying,ZHANG Xiaojie,HAN Jiale,LI Wei.Research Advances of Surface Modification Methods for Hydrogen Storage Alloys[J].Surface Technology,2025,54(8):51-63 |
| 储氢合金表面修饰方法的研究进展 |
| Research Advances of Surface Modification Methods for Hydrogen Storage Alloys |
| 投稿时间：2024-09-11 修订日期：2025-03-03 |
| DOI：10.16490/j.cnki.issn.1001-3660.2025.08.004 |
| 中文关键词: 储氢合金 表面修饰 储氢性能 微观结构 电化学性能 |
| 英文关键词:s of the 2017 Annual Meeting of the Chinese Rare Earth Society. Beijing:Chinese Rare Earth Society, 2017. |
| 基金项目:内蒙古自治区自然科学基金项目(2024MS05017);内蒙古自治区高等学校碳达峰碳中和研究专项(STZX202207);内蒙古自治区科技计划项目(2023YFHH0059，2020GG0166);支持地方高校改革发展资金(物理学一流学科培育) |
| 作者 | 单位 |
| 高媛媛 | 内蒙古师范大学 物理与电子信息学院，呼和浩特 010022 |
| 田晓 | 内蒙古师范大学 物理与电子信息学院，呼和浩特 010022;内蒙古师范大学 稀土功能新能源储能材料内蒙古自治区工程研究中心，呼和浩特 010022;内蒙古自治区应用凝聚态物理重点实验室，呼和浩特 010022 |
| 张颖 | 内蒙古师范大学 物理与电子信息学院，呼和浩特 010022 |
| 张晓杰 | 内蒙古师范大学 物理与电子信息学院，呼和浩特 010022 |
| 韩家乐 | 内蒙古师范大学 物理与电子信息学院，呼和浩特 010022 |
| 李卫 | 内蒙古师范大学 物理与电子信息学院，呼和浩特 010022;内蒙古师范大学 稀土功能新能源储能材料内蒙古自治区工程研究中心，呼和浩特 010022;内蒙古自治区应用凝聚态物理重点实验室，呼和浩特 010022 |
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| Author | Institution |
| GAO Yuanyuan | School of Physics and Electronic Information,Hohhot 010022, China |
| TIAN Xiao | School of Physics and Electronic Information,Hohhot 010022, China ;Inner Mongolia Key Laboratory of Applied Condensed Matter Physics, Inner Mongolia Normal University, Hohhot 010022, China;Inner Mongolia Key Laboratory of Applied Condensed Matter Physics, Hohhot 010022, China |
| ZHANG Ying | School of Physics and Electronic Information,Hohhot 010022, China |
| ZHANG Xiaojie | School of Physics and Electronic Information,Hohhot 010022, China |
| HAN Jiale | School of Physics and Electronic Information,Hohhot 010022, China |
| LI Wei | School of Physics and Electronic Information,Hohhot 010022, China ;Inner Mongolia Key Laboratory of Applied Condensed Matter Physics, Inner Mongolia Normal University, Hohhot 010022, China;Inner Mongolia Key Laboratory of Applied Condensed Matter Physics, Hohhot 010022, China |
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| 中文摘要: |
| 金属储氢合金是迄今为止储氢密度高、安全性好、使用便捷的最佳储氢候选材料。为了改善储氢合金的活化性能、吸放氢性能、抗腐蚀性能、抗氧化性能以及抗杂质气体毒化性能等，研究人员常对储氢合金进行表面修饰。表面修饰通常是通过调控合金表面的微观结构、化学组成以及物理状态来改善合金的理化性质。对近几十年储氢合金的表面修饰相关研究成果进行梳理、分析，并加以归纳和分类。将储氢合金的表面修饰方法大体分为两大类:物理表面修饰和化学表面修饰。其中，物理表面修饰方法包括气相沉积技术、激光处理技术、机械合金化技术和剧烈塑性变形技术。化学表面修饰方法包括化学镀技术、电镀技术、阳极氧化技术以及其他化学修饰方法(酸处理、碱处理、盐处理、氟化处理等)。这些方法是通过在合金表面形成保护层，引入纳米晶结构、增加活性位点等来提高合金的综合性能。对这些表面修饰方法进行了详细的综述，并对照了不同修饰方法对部分储氢合金的性能影响，同时对储氢合金的表面修饰方法在今后的发展进行了展望。 |
| 英文摘要: |
| Hydrogen energy is a kind of secondary energy which is abundant, green and low carbon and widely used. The key to application of hydrogen energy is hydrogen storage. Metal hydrogen storage alloys are by far the best hydrogen storage candidate materials with high hydrogen storage density, high safety and ease of use. In order to improve the activation properties, hydrogen absorption and release properties, corrosion resistance, oxidation resistance and anti-impurity gas toxicity properties of hydrogen storage alloys, researchers often modify the surface of hydrogen storage alloys. Surface modification refers to the method of changing the surface structural characteristics of an alloy by physical, chemical or composite methods in order to improve one or several properties of the alloy, such as removing the oxidized layer of the alloy, increasing the active sites, and coating the film layer. There are many kinds of surface modification methods for hydrogen storage alloys, and the improvement degree of properties is different. In this paper, the research results of surface modification of hydrogen storage alloys in recent decades are reviewed, analyzed, summarized and classified. The surface modification methods of hydrogen storage alloys can be roughly divided into two categories:physical surface modification and chemical surface modification. Among them, the physical surface modification methods include vapor deposition technology, laser treatment technology, mechanical alloying technology and severe plastic deformation technology. Chemical surface modification methods include electroless composite plating technology, electroplating technology, anodizing technology and other chemical modification methods (acid treatment, alkali treatment, salt treatment, fluoride treatment, etc.). These surface modification methods are reviewed in detail, and the future development of surface modification methods for hydrogen storage alloys is also prospected. |
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