杨子毅,付永强,王优强,谷炎琦,黄淑元,孟凤云.YSZ基热障涂层研究进展[J].表面技术,2025,54(5):27-43.
YANG Ziyi,FU Yongqiang,WANG Youqiang,GU Yanqi,HUANG Shuyuan,MENG Fengyun.Research Progress on YSZ-based Thermal Barrier Coatings[J].Surface Technology,2025,54(5):27-43 |
| YSZ基热障涂层研究进展 |
| Research Progress on YSZ-based Thermal Barrier Coatings |
| 投稿时间：2024-06-13 修订日期：2024-08-29 |
| DOI：10.16490/j.cnki.issn.1001-3660.2025.05.002 |
| 中文关键词: 热障涂层 氧化钇部分稳定氧化锆 YSZ掺杂改性 涂层制备技术 涂层失效 |
| 英文关键词:thermal barrier coatings yttria partially stabilized zirconia YSZ doping modification coating preparation techniques coating failure |
| 基金项目:国家自然科学基金青年项目(52205204);山东省自然科学基金面上项目(ZR2021ME063);山东省高等学校青年创新团队项目(2023KJ116) |
| 作者 | 单位 |
| 杨子毅 | 青岛理工大学 机械与汽车工程学院，山东 青岛 266525 |
| 付永强 | 青岛理工大学 机械与汽车工程学院，山东 青岛 266525 |
| 王优强 | 青岛理工大学 机械与汽车工程学院，山东 青岛 266525 |
| 谷炎琦 | 北京航空航天大学 航空发动机研究院，北京 100191 |
| 黄淑元 | 山东梁山亨通机械制造有限公司，山东 济宁 272600 |
| 孟凤云 | 山东梁山亨通机械制造有限公司，山东 济宁 272600 |
|
| Author | Institution |
| YANG Ziyi | School of Mechanical and Automotive Engineering, Qingdao University of Technology, Shandong Qingdao 266525, China |
| FU Yongqiang | School of Mechanical and Automotive Engineering, Qingdao University of Technology, Shandong Qingdao 266525, China |
| WANG Youqiang | School of Mechanical and Automotive Engineering, Qingdao University of Technology, Shandong Qingdao 266525, China |
| GU Yanqi | Research Institute of Aero-Engine, Beihang University, Beijing 100191, China |
| HUANG Shuyuan | Shandong Liangshan Hengtong Machinery Manufacturing Limited Corporation, Shandong Jining 272600, China |
| MENG Fengyun | Shandong Liangshan Hengtong Machinery Manufacturing Limited Corporation, Shandong Jining 272600, China |
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| 中文摘要: |
| 随着航空技术的不断进步，航空发动机涡轮前温度不断攀升，对热端部件的耐高温性能及相应的冷却手段也提出了更高的要求。热障涂层作为热端部件(尤其是涡轮叶片)隔热冷却性能的关键技术之一，其研究和应用受到广泛关注。综述了氧化钇部分稳定的氧化锆(YSZ)基热障涂层的研究进展，重点探讨了YSZ涂层的改性方法、制备技术及失效机理。通过涂层设计的材料(如稀土或过渡金属氧化物等)角度，综述了它对YSZ涂层热导率、高温相稳定性和抗烧结等性能的影响，并详细探讨了单元氧化物掺杂和多元氧化物共掺杂对YSZ涂层改性的机理和影响。同时，介绍了大气等离子喷涂(APS)、电子束物理气相沉积(EB-PVD)和等离子喷涂-物理气相沉积(PS-PVD)等主要YSZ涂层制备技术，对比了它们的优势和局限性。此外，探讨了热障涂层的主要失效模式，包括热膨胀系数不匹配、热生长氧化物(TGO)、CMAS腐蚀及Na2SO4+V2O5熔盐腐蚀失效，并总结了热障涂层的失效机理。最后对未来YSZ基热障涂层的发展方向进行了展望。 |
| 英文摘要: |
| With the relentless pursuit of higher efficiency in aviation, the turbine inlet temperature of aero-engines has been pushing the boundaries, necessitating superior thermal insulation capabilities from hot-end components. Thermal barrier coatings (TBCs), particularly those based on Yttria Stabilized Zirconia (YSZ), have emerged as a pivotal technology for enhancing the thermal resistance and lifespan of turbine blades. The work aims to delve into the research progress of YSZ-based TBCs, providing a detailed analysis of the modification methods, preparation techniques, and failure mechanisms of the coatings. The effects of coating design by doping of rare earth elements or non-rare earth oxides on the thermal conductivity, high-temperature phase stability, and resistance to sintering of YSZ-based coatings are comprehensively discussed in the review. Additionally, a detailed exploration is provided, clarifying the modification mechanisms and significant impacts that single oxide doping and multi-oxide co-doping have on the properties of YSZ-based coatings. The intricate relationship between the atomic mass, ionic radius, and the resultant phonon scattering has been elucidated, providing a theoretical foundation for the design of low thermal conductivity ceramics. The common YSZ-based coating preparation techniques are introduced, including atmospheric plasma spraying (APS), electron beam physical vapor deposition (EB-PVD), and plasma spray-physical vapor deposition (PS-PVD), and their advantages and disadvantages are summarized. APS YSZ-based coatings offer low thermal conductivity due to their porous, layered structure but have issues with low elasticity, weak adhesion, and limited thermal cycle life. EB-PVD YSZ has a robust columnar structure with high strength but the highest thermal conductivity and is susceptible to high-temperature oxidation and corrosion. PS-PVD merges the benefits of the both, enabling the adjustment of the microstructure for rapid, uniform, and dense coating deposition by varying process parameters. In addition, the primary failure modes of TBCs, including thermal expansion coefficient mismatch, thermally grown oxide (TGO) growth, Calcium-Magnesium-Alumino-Silicate (CMAS) corrosion, and molten salt corrosion by Na2SO4+V2O5, are discussed, along with the corresponding failure mechanisms. The mismatch of thermal expansion coefficients among the bond coat, ceramic layer, and TGO may induce thermally induced stress, which can promote crack extension and lead to spallation. The study of TGO growth is particularly crucial as it can significantly alter the stress intensity and distribution, resulting in the initiation of cracks within the coating. CMAS is capable of penetrating the porous structure of TBCs and reacting with the coating, depleting the yttrium element and forming monoclinic zirconia, thus accelerating the failure of the coating. The corrosion by Na2SO4+V2O5 is especially severe in environments with high concentrations of vanadium and sulfur, where Na2SO4+V2O5 can react with the coating material at high temperature, leading to a loss of adhesion and increased susceptibility to spallation. The interplay between these factors and their synergistic impact on coating degradation is discussed, highlighting the need for a comprehensive understanding to foster the development of robust TBCs. Currently, YSZ-based TBCs have made significant advancements, yet the path to optimization remains challenging. Future research directions are expected to focus on optimizing existing dopant combinations and exploring new stabilizers, integrating experimental and computational approaches, and developing smart maintenance strategies. |
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