顾天真,刘雨薇,彭灿,张鹏,王振尧,汪川,孙力.热浸镀Zn-Al-Mg镀层在模拟湿热海洋大气环境中的腐蚀行为研究[J].表面技术,2024,53(2):110-119.
GU Tianzhen,LIU Yuwei,PENG Can,ZHANG Peng,WANG Zhenyao,WANG Chuan,SUN Li.Corrosion Behavior of Hot-dip Zn-Al-Mg Coating Exposed to a Simulated Hot and Humid Marine Atmosphere[J].Surface Technology,2024,53(2):110-119 |
| 热浸镀Zn-Al-Mg镀层在模拟湿热海洋大气环境中的腐蚀行为研究 |
| Corrosion Behavior of Hot-dip Zn-Al-Mg Coating Exposed to a Simulated Hot and Humid Marine Atmosphere |
| 投稿时间：2022-11-22 修订日期：2023-02-03 |
| DOI：10.16490/j.cnki.issn.1001-3660.2024.02.010 |
| 中文关键词: 热浸镀Zn-Al-Mg镀层 湿热海洋大气 大气腐蚀 质量损失 腐蚀产物结构 |
| 英文关键词:hot-dip Zn-Al-Mg coating hot and humid marine atmosphere atmospheric corrosion mass loss corrosion products structure |
| 基金项目:河北省自然科学基金资助项目(E2021318006) |
| 作者 | 单位 |
| 顾天真 | 中国科学院金属研究所，沈阳 110016;中国科学技术大学 材料科学与工程学院，沈阳 110016;辽宁沈阳土壤大气环境材料腐蚀国家野外科学观测研究站，沈阳 110016 |
| 刘雨薇 | 中国科学院金属研究所，沈阳 110016;辽宁沈阳土壤大气环境材料腐蚀国家野外科学观测研究站，沈阳 110016 |
| 彭灿 | 中国科学院金属研究所，沈阳 110016;中国科学技术大学 材料科学与工程学院，沈阳 110016;辽宁沈阳土壤大气环境材料腐蚀国家野外科学观测研究站，沈阳 110016 |
| 张鹏 | 河钢集团钢研总院，石家庄 050023 |
| 王振尧 | 中国科学院金属研究所，沈阳 110016;辽宁沈阳土壤大气环境材料腐蚀国家野外科学观测研究站，沈阳 110016 |
| 汪川 | 中国科学院金属研究所，沈阳 110016;辽宁沈阳土壤大气环境材料腐蚀国家野外科学观测研究站，沈阳 110016 |
| 孙力 | 河钢集团钢研总院，石家庄 050023 |
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| Author | Institution |
| GU Tianzhen | Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China;School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China;Liaoning Shenyang Soil and Atmosphere Corrosion of Materials National Observation and Research Station, Shenyang 110016, China |
| LIU Yuwei | Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China;Liaoning Shenyang Soil and Atmosphere Corrosion of Materials National Observation and Research Station, Shenyang 110016, China |
| PENG Can | Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China;School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China;Liaoning Shenyang Soil and Atmosphere Corrosion of Materials National Observation and Research Station, Shenyang 110016, China |
| ZHANG Peng | HBIS Group Technology Research Institute, Shijiazhuang 050023, China |
| WANG Zhenyao | Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China;Liaoning Shenyang Soil and Atmosphere Corrosion of Materials National Observation and Research Station, Shenyang 110016, China |
| WANG Chuan | Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China;Liaoning Shenyang Soil and Atmosphere Corrosion of Materials National Observation and Research Station, Shenyang 110016, China |
| SUN Li | HBIS Group Technology Research Institute, Shijiazhuang 050023, China |
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| 中文摘要: |
| 目的 为详细研究热浸镀Zn-Al-Mg镀层在模拟湿热海洋大气下的腐蚀行为及作用机理，同时为热浸镀Zn-Al-Mg镀层在湿热海洋大气环境中服役提供数据参考。方法 采用腐蚀失重、XRD、SEM、电化学等测试方法对热浸镀Zn-Al-Mg镀层在模拟湿热海洋大气环境下的腐蚀行为进行研究。结果 腐蚀产物主要由Zn5(OH)8Cl2.H2O组成，腐蚀一段时间后，发现少量ZnO、Zn5(OH)6CO3，腐蚀产物具有与锌腐蚀类似的层状结构，1 848 h呈“三明治”型，相比于上下两层暗色物质，中层亮色腐蚀产物富集更多的Cl元素。热浸镀Zn-Al-Mg镀层腐蚀速率大体随时间延长呈上升趋势，只在672~840 h腐蚀速率下降，对比镀锌在模拟环境和锌在湿热大气环境中的腐蚀，热浸镀Zn-Al-Mg镀层在模拟湿热海洋大气中表现出较好的耐蚀性。结论 热浸镀Zn-Al-Mg镀层在模拟湿热海洋大气下腐蚀产物演变与腐蚀过程中Mg的参与有关。腐蚀672~840 h阶段腐蚀速率下降的原因与腐蚀产物中ZnO的减少和Zn5(OH)8Cl2.H2O占比增加有关。对比镀锌在模拟环境和锌在湿热大气环境中的腐蚀，预测热浸镀Zn-Al-Mg镀层在严酷湿热海洋大气中仍具有较高的耐蚀性，可以优先考虑作为湿热海洋环境的建设用材。 |
| 英文摘要: |
| The work aims to explore the corrosion behavior and mechanism of hot-dip Zn-Al-Mg coatings in a hot and humid marine atmosphere and provide data references for hot-dip Zn-Al-Mg coatings serving in the hot and humid marine atmosphere. The corrosion behavior of the hot-dip Zn-Al-Mg coating in a simulated hot and humid marine atmosphere was analyzed by corrosion weight loss, X-ray diffraction (XRD), scanning electron microscopy (SEM), electrochemical impedance spectroscopy (EIS) and other test methods. The results showed that the corrosion product was mainly composed of Zn5(OH)8Cl2.H2O. After a period of corrosion, a small amount of ZnO and Zn5(OH)6CO3 were found. The corrosion product evolution was related to the participation of Mg in the corrosion process. The corrosion product had a lamellar structure, which was like a "sandwich" at 1 848 h. Compared with the upper and lower layers of dark substances, the bright-colored corrosion product in the middle layer had more Cl elements concentration. The corrosion rate of the hot-dip Zn-Al-Mg coating generally increased with time, and only dropped sharply in the stage of 672-840 h. Comparison of galvanized coatings corrosion in a simulated hot and humid marine environment and zinc corrosion in a hot and humid outdoor marine atmospheric environment showed that the hot-dip Zn-Al-Mg coating had high corrosion resistance in the simulated hot and humid marine atmosphere environment. The evolution of corrosion products of the hot dip Zn-Al-Mg coating in a simulated hot and humid Marine atmosphere is related to Mg in the corrosion process. The reason for the decrease of corrosion rate at 672-840 h is related to the decrease of ZnO and the increase of Zn5(OH)8Cl2.H2O in corrosion products. It is predicted that the hot-dip Zn-Al-Mg coating still has high corrosion resistance in the hot and humid harsh marine atmosphere, and it can be given priority as a construction material for hot and humid marine atmosphere environment. |
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