白雪冰,李金龙,朱丽慧,王永欣,王立平.多弧离子镀制备TiSiN-Cu涂层的结构和摩擦学性能[J].表面技术,2017,46(11):96-103.
BAI Xue-bing,LI Jin-long,ZHU Li-hui,WANG Yong-xin,WANG Li-ping.Structure and Tribological Properties of TiSiN-Cu Coatings Prepared by Multi-arc Iron Plating[J].Surface Technology,2017,46(11):96-103 |
| 多弧离子镀制备TiSiN-Cu涂层的结构和摩擦学性能 |
| Structure and Tribological Properties of TiSiN-Cu Coatings Prepared by Multi-arc Iron Plating |
| 投稿时间：2017-06-04 修订日期：2017-11-20 |
| DOI：10.16490/j.cnki.issn.1001-3660.2017.11.014 |
| 中文关键词: TiSiN-Cu涂层 多弧离子镀 结构 润滑 海水 机械性能 摩擦磨损 |
| 英文关键词:TiSiN-Cu coating multi-arc iron plating structure lubrication seawater mechanical properties frictional wear |
| 基金项目:国家自然科学基金（51101051） |
| 作者 | 单位 |
| 白雪冰 | 1.上海大学 材料科学与工程学院，上海 200072；2.中国科学院宁波材料技术与工程研究所 中国科学院海洋新材料与应用技术重点实验室 浙江省海洋材料与防护技术重点实验室，浙江 宁波 315201 |
| 李金龙 | 中国科学院宁波材料技术与工程研究所 中国科学院海洋新材料与应用技术重点实验室 浙江省海洋材料与防护技术重点实验室，浙江 宁波 315201 |
| 朱丽慧 | 上海大学 材料科学与工程学院，上海 200072 |
| 王永欣 | 中国科学院宁波材料技术与工程研究所 中国科学院海洋新材料与应用技术重点实验室 浙江省海洋材料与防护技术重点实验室，浙江 宁波 315201 |
| 王立平 | 中国科学院宁波材料技术与工程研究所 中国科学院海洋新材料与应用技术重点实验室 浙江省海洋材料与防护技术重点实验室，浙江 宁波 315201 |
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| Author | Institution |
| BAI Xue-bing | 1.School of Materials Science and Engineering, Shanghai University, Shanghai 200072, China;2.Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China |
| LI Jin-long | Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Tech-nologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China |
| ZHU Li-hui | School of Materials Science and Engineering, Shanghai University, Shanghai 200072, China |
| WANG Yong-xin | Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Tech-nologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China |
| WANG Li-ping | Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Tech-nologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China |
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| 中文摘要: |
| 目的 通过在TiSiN涂层中掺杂软金属Cu，提高TiSiN涂层的摩擦性能。方法 采用多弧离子镀技术，在316L不锈钢基体上沉积TiSiN-Cu涂层。用扫描电子显微镜（SEM）观察涂层的表面形貌，用X射线光电子能谱仪（XPS）和X射线衍射仪（XRD）来分析涂层的元素组成和相组成，通过纳米压痕硬度测试和摩擦磨损实验，表征不同Cu含量TiSiN-Cu涂层的力学性能和摩擦学性能。结果 Cu含量对TiSiN涂层的结构、硬度和摩擦性能有明显影响。Cu在涂层中主要以单质形式存在，由于与空气接触，涂层表面有少量的CuO。随着Cu含量的增加，TiN的晶粒尺寸先减小后增加，硬度先升高后降低。在Cu原子数分数为6.28%时，硬度达到最大值29.26 GPa。在干摩擦条件下，TiSiN-Cu涂层的磨损率在Cu原子数分数为12.93%时达到最低，为6.65×10−7 mm3/(N•m)。在海水环境下，涂层的磨损率较大。结论 软金属Cu作为固体润滑颗粒可以明显改善TiSiN涂层的干摩擦性能，在海水条件下，摩擦与腐蚀的交互作用加速了涂层材料的损耗。 |
| 英文摘要: |
| The work aims to improve tribological properties of TiSiN-Cu coating by doping the coating with soft metal Cu. TiSiN-Cu coating was deposited on 316L stainless steel by adopting multi-arc ion plating technology. Surface morphology of the coating was observed with scanning electron microscopy (SEM). Element composition and phase structure of the coating was analyzed with X-ray photoelectron spectrometer (XPS) and X-ray diffractometer (XRD), respectively. Mechanical properties and tribological properties of TiSiN-Cu coatings with different Cu contents were characterized with nano indentation hardness test as well as friction and wear test. Cu content had great influences on microstructure, hardness and tribological properties of the TiSiN-Cu coatings. Copper existed in the form of elementary substance. There was a little CuO on the surface of coatings owing to exposure to air. As the Cu content increased, grain size of TiN first decreased and then increased, the hardness first increased and then decreased. When the Cu content was 6.28 at.%, the hardness reached 29.26 GPa. Under dry friction conditions, the wear rate was 6.65×10−7 mm3/(N•m) (the minimum) when Cu content was 12.93 at.%. However, the wear rate was higher in seawater environment. Soft metal Cu can significantly improve the dry friction of the TiSiN coating as solid lubrication particle. However, the interaction of friction and corrosion can accelerate wear of the coatings in seawater. |
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