李水娥,周绪忠,崔同明,李慧赢.表面处理活性炭及其对二氧化碳吸附性能研究[J].表面技术,2017,46(7):134-138.
LI Shui-e,ZHOU Xu-zhong,CUI Tong-ming,LI Hui-ying.Surface Treated Activated Carbon and Its Adsorption Property to CO2[J].Surface Technology,2017,46(7):134-138 |
| 表面处理活性炭及其对二氧化碳吸附性能研究 |
| Surface Treated Activated Carbon and Its Adsorption Property to CO2 |
| 投稿时间：2017-02-23 修订日期：2017-07-20 |
| DOI：10.16490/j.cnki.issn.1001-3660.2017.07.022 |
| 中文关键词: DETA 浸渍 表面处理 活性炭 吸附CO2 |
| 英文关键词:DETA impregnation surface treatment activated carbon CO2 adsorption |
| 基金项目:贵州省科技厅、贵州大学2014联合资助项目（黔科合LH字[2014]7647号）；贵州省教育厅项目（黔教合KY字[2014]222号）；贵州省重点学科建设项目（黔学位和字ZDXK[2015]6号） |
| 作者 | 单位 |
| 李水娥 | 1.贵州大学 材料与冶金学院，贵阳 550025；2.贵州省冶金工程与过程节能重点实验室，贵阳 550025 |
| 周绪忠 | 贵州财经大学图书馆，贵阳 550025 |
| 崔同明 | 1.贵州大学 材料与冶金学院，贵阳 550025；2.贵州省冶金工程与过程节能重点实验室，贵阳 550025 |
| 李慧赢 | 1.贵州大学 材料与冶金学院，贵阳 550025；2.贵州省冶金工程与过程节能重点实验室，贵阳 550025 |
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| Author | Institution |
| LI Shui-e | 1.School of Materials and Metallurgy, Guizhou University, Guiyang 550025, China; 2.Guizhou Provincial Key Laboratory of Metallurgical Engineering and Process Energy Conservation, Guiyang 550025, China |
| ZHOU Xu-zhong | Library of Guizhou University of Finance and Economic, Guiyang 550025, China |
| CUI Tong-ming | 1.School of Materials and Metallurgy, Guizhou University, Guiyang 550025, China; 2.Guizhou Provincial Key Laboratory of Metallurgical Engineering and Process Energy Conservation, Guiyang 550025, China |
| LI Hui-ying | 1.School of Materials and Metallurgy, Guizhou University, Guiyang 550025, China; 2.Guizhou Provincial Key Laboratory of Metallurgical Engineering and Process Energy Conservation, Guiyang 550025, China |
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| 中文摘要: |
| 目的 提高活性炭对二氧化碳的吸附性能。方法 用二乙烯三胺浸渍方法对活性炭进行表面处理，利用X射线衍射仪对活性炭表面处理前后进行物相分析，利用全自动比表面及空隙度分析仪，对活性炭表面处理前后进行比表面积和孔结构分析。最后对活性炭表面处理前后进行吸附实验，并对其进行理论分析。结果 表面处理后，活性炭中的碳由三方晶系变为六方晶系，并且活性炭表面增加了氨基。活性炭的比表面积增加了2.13倍；微孔容增加了1.80倍，由0.056 cm3/g增加至0.157 cm3/g；总孔容增加了3.24倍，由0.078 cm3/g增加至0.331 cm3/g；中孔容增加量为0.152 cm3/g；平均孔径减小了0.27 nm，由7.14 nm减少至6.87 nm。活性炭的吸附量由0.92 mmol/g增加至3.55 mmol/g，是表面处理前的3.86倍，其饱和吸附时间从10 min增加至40 min。结论 此方法可以有效提高活性炭的吸附性能。 |
| 英文摘要: |
| The work aims to improve adsorption property of activated carbon for CO2. Phase of activated carbon before and after surface treatment was analyzed with X-ray diffractometer in DETA impregnation method. Specific surface area and pore structure of the activated carbon before and after surface treatment were analyzed with full-automatic specific surface & voidage analyzer. Finally, an adsorption experiment and theoretical analysis were performed to the activated carbon before and after surface treatment. Carbon in the activated carbon subject to surface treatment changed from trigonal system to hexagonal system. And amino group was added on the surface of activated carbon. Specific surface area of the activated carbon increased by 2.13 times; microporosity increased by 1.80 times, from 0.056 cm3/g to 0.157 cm3/g; total porosity increased by 3.24 times, from 0.078 cm3/g to 0.331 cm3/g; increment of midporosity was 0.152 cm3/g; mean pore size decreased by 0.27 nm, from 7.14 nm to 6.87 nm. Adsorption capacity of the activated carbon increased from 0.92 mmol/g to 3.55 mmol/g, which was 3.86 times as high as that before surface treatment. Saturated adsorption time increased from 10 min to 40 min. This method can effectively improve the adsorption property of activated carbon. |
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