田斌,刘宝辉,岳文,王成彪.W、Mo离子注入对离子镀TiN薄膜表面结构和性能的影响[J].表面技术,2017,46(6):174-179. TIAN Bin,LIU Bao-hui,YUE Wen,WANG Cheng-biao.Effects of W and Mo Ion Implantations on Surface Structures and Properties of Ion-plated Titanium Nitride Coatings[J].Surface Technology,2017,46(6):174-179 |
W、Mo离子注入对离子镀TiN薄膜表面结构和性能的影响 |
Effects of W and Mo Ion Implantations on Surface Structures and Properties of Ion-plated Titanium Nitride Coatings |
投稿时间:2017-01-15 修订日期:2017-06-20 |
DOI:10.16490/j.cnki.issn.1001-3660.2017.06.027 |
中文关键词: 离子注入 氮化钛 摩擦 磨损 钨离子 钼离子 |
英文关键词:ion implantations titanium nitride friction wear tungsten ions molybdenum ions |
基金项目:国家自然科学基金面上项目(41572362);北京市教育委员会科技计划一般项目(SQKM201710011002);中央高校基本科研业务费优秀教师研究项目(2652015077);高等学校博士学科点专项基金资助课题(20130022110004) |
作者 | 单位 |
田斌 | 北京工商大学 材料与机械工程学院,北京 100048 |
刘宝辉 | 北京工商大学 材料与机械工程学院,北京 100048 |
岳文 | 中国地质大学(北京) 工程技术学院,北京 100083 |
王成彪 | 中国地质大学(北京) 工程技术学院,北京 100083 |
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Author | Institution |
TIAN Bin | School of Material and Mechanical Engineering, Beijing Technology and Business University, Beijing 100048, China |
LIU Bao-hui | School of Material and Mechanical Engineering, Beijing Technology and Business University, Beijing 100048, China |
YUE Wen | School of Engineering and Technology, China University of Geosciences (Beijing), Beijing 100083, China |
WANG Cheng-biao | School of Engineering and Technology, China University of Geosciences (Beijing), Beijing 100083, China |
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中文摘要: |
目的 进一步改善氮化钛薄膜的摩擦学性能。方法 利用金属蒸汽真空弧源(MEVVA)在离子镀TiN薄膜表面进行等剂量W、Mo离子注入。采用扫描俄歇系统、光学三维形貌仪、X射线衍射仪和纳米压痕仪,分别分析了TiN薄膜的离子注入深度、表面形貌及粗糙度、相结构和不同压入深度的薄膜硬度。在球盘滑动摩擦磨损试验机上考察了TiN薄膜的摩擦学性能,并利用扫描电子显微镜和三维形貌仪对其磨损形貌进行分析。结果 等剂量离子注入后,TiN表面注入层中W离子的含量明显大于Mo离子,两种离子注入对TiN薄膜的表面形貌和硬度的影响较小。XRD结果表明,W离子和Mo离子注入后均发现了Ti2N硬质相。两种离子注入均可以不同程度地降低TiN薄膜的摩擦系数和磨损率。结论 W、Mo离子注入均可显著改善TiN薄膜的摩擦学性能,但Mo离子更有利于其摩擦系数的降低,而W离子注入更有利于TiN薄膜磨损率的降低。 |
英文摘要: |
The work aims to further improve tribological properties of TiN coatings. W and Mo ion implantations at same doses were performed on ion-plated TiN coatings using metal vapor vacuum arc (MEVVA) source. Ion implantation depth, morphology, surface roughness, phase structure, and nano-hardness at different implantation depth of TiN coatings were analyzed with scanning auger microprobe (SAM), three-dimensional optical profilometer, X-ray diffractometer (XRD) and nano indentor, respectively. Tribological peroperties of TiN coatings were investigated on a ball-on-disk sliding tribometer. Also, wear appearance was analyzed with scanning electron microscopy (SEM) and three-dimensional optical profilometer. Content of W ions in TiN coatings was obviously higher than that of Mo ions after the same dose implantations. W and Mo ion implantations had less effect on surface morphology and hardness of TiN coatings. The XRD results showed that Ti2N phases appeared on TiN coatings after W and Mo ion implantations. The friction coefficient and wear rate of TiN coatings decreased to different extent after W and Mo ion implantations. Tribological properties of the ion-plated TiN coatings cab be improved by both W and Mo implantations. However, the Mo ion implantation is more conducive to reduction of friction coefficient while the W ion implantation is more conducive to redcution of wear rate. |
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