农毅,邱长军,杨育洁,刘赞.Al2O3-TiO2复相陶瓷涂层在动态LBE中的耐腐蚀行为[J].表面技术,2017,46(4):235-239.
NONG Yi,QIU Chang-jun,YANGYu-jie,LIU Zan.Anticorrosion Behavior of Al2O3-TiO2 Composite Ceramic Coating in Flowing LBE[J].Surface Technology,2017,46(4):235-239 |
| Al2O3-TiO2复相陶瓷涂层在动态LBE中的耐腐蚀行为 |
| Anticorrosion Behavior of Al2O3-TiO2 Composite Ceramic Coating in Flowing LBE |
| 投稿时间：2016-10-10 修订日期：2017-04-20 |
| DOI：10.16490/j.cnki.issn.1001-3660.2017.04.038 |
| 中文关键词: Al2O3-TiO2复相陶瓷涂层 CLAM钢 铅铋合金 腐蚀 |
| 英文关键词:Al2O3-TiO2 composite ceramic coating CLAM steel lead-bismuth eutectic (LBE) corrosion |
| 基金项目:国家自然科学基金资助项目（91326114） |
| 作者 | 单位 |
| 农毅 | 南华大学 a.机械工程学院，湖南 衡阳 421001 |
| 邱长军 | 南华大学 a.机械工程学院，湖南 衡阳 421001 |
| 杨育洁 | 南华大学 a.机械工程学院，湖南 衡阳 421001 |
| 刘赞 | 南华大学 b.创新创业学院，湖南 衡阳 421001 |
|
| Author | Institution |
| NONG Yi | a.School of Mechanical Engineering, University of South China, Hengyang 421001, China |
| QIU Chang-jun | a.School of Mechanical Engineering, University of South China, Hengyang 421001, China |
| YANGYu-jie | a.School of Mechanical Engineering, University of South China, Hengyang 421001, China |
| LIU Zan | b.School of Innovation and Entrepreneurship, University of South China, Hengyang 421001, China |
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| 中文摘要: |
| 目的 分析研究Al2O3-TiO2复相陶瓷涂层在高温流动铅铋合金中的耐腐蚀行为。方法 以纯Ti粉末、FeAl粉末、CrFe粉末为原料制得复合粉末，在CLAM钢基材表面上采用热喷涂-激光原位合成复合工艺制备了Al2O3-TiO2复相陶瓷涂层。试样在500 ℃，流速为0.3 m/s的液态铅铋合金中进行了时长1000 h的动态腐蚀实验，分别采用X射线衍射仪（XRD）、扫描电镜（SEM）、能谱仪（EDS）等分析测试手段对涂层试样在动态LBE中的耐腐蚀行为进行了研究表征。结果 在CLAM钢基材表面制备的Al2O3-TiO2复相陶瓷涂层表面形貌整体较腐蚀前仍保持完好，涂层物相成分保持稳定，截面分析显示铅铋合金在腐蚀过程在涂层中未见渗透；而没有涂层保护的CLAM钢基材在腐蚀后表面发生明显的氧化腐蚀现象，生成结构疏松的Fe3O4氧化层，铅铋合金在氧化层中有扩散分布。结论 通过火焰热喷涂-激光原位合成复合工艺在CLAM钢表面制备得到的Al2O3-TiO2复相陶瓷涂层在高温流动的铅铋合金腐蚀条件下组织结构稳定，具有良好的适用性，能有效地阻止高温流动铅铋合金对CLAM钢基体材料的腐蚀。 |
| 英文摘要: |
| The work aims to analyze anticorrosion behavior of Al2O3-TiO2 composite ceramic coating in flowing super LBE. Al2O3-TiO2 composite ceramic coating was prepared on the CLAM steel in oxyacetylene flame spraying-laser in-situ synthesis reaction compound technology with pure Ti, FeAl and CrFe powders. Anticorrosion behavior of the coating in flowing lead-bismuth eutectic (LBE) alloy was investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) by carrying out 1000 h dynamic corrosion test to the sample in liquid LBE alloy at 500 ℃ with flow velocity of 0.3 m/s. The overall morphology of Al2O3-TiO2 composite ceramic coating surface remained intact compared to that before corrosion, coating phase composition remained stable, sectional analysis of lead-bismuth alloy was free from penetration in the coating during corrosion. The CLAM steel substrate without a protective coating was subject to obvious oxidation corrosion on the surface, loose structure of Fe3O4 oxide layer was generated, the lead-bismuth alloy was dispersed in the oxide layer. The Al2O3-TiO2 composite ceramic coating prepared in oxyacetylene flame spraying-laser in-situ reaction method exhibits stable structure and excellent applicability, and can protect the substrate CLAM steel effectively in flowing lead-bismuth eutectic (LBE) alloy. |
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