朱以亮,闫莹,周浩,吴来明,吴雪威,史笔函,蔡兰坤.臭氧气氛下LED灯光对银质文物模拟材料腐蚀变色的影响[J].表面技术,2017,46(3):209-215.
ZHU Yi-liang,YAN Ying,ZHOU Hao,WU Lai-ming,WU Xue-wei,SHI Bi-han,CAI Lan-kun.Effects of LED Light on Tarnishing of Silver Relics Simulation Materials in Ozone[J].Surface Technology,2017,46(3):209-215 |
| 臭氧气氛下LED灯光对银质文物模拟材料腐蚀变色的影响 |
| Effects of LED Light on Tarnishing of Silver Relics Simulation Materials in Ozone |
| 投稿时间：2016-12-14 修订日期：2017-03-20 |
| DOI：10.16490/j.cnki.issn.1001-3660.2017.03.032 |
| 中文关键词: 银 文物 LED灯光 臭氧 腐蚀 石英晶体微天平 |
| 英文关键词:silver cultural relics LED light ozone corrosion quartz crystal microbalance |
| 基金项目:国家自然科学基金项目（51671117）；上海市科委科研计划重点支撑项目（13231203000） |
| 作者 | 单位 |
| 朱以亮 | 华东理工大学，上海 200237 |
| 闫莹 | 华东理工大学，上海 200237 |
| 周浩 | 上海博物馆，上海 200050 |
| 吴来明 | 上海博物馆，上海 200050 |
| 吴雪威 | 华东理工大学，上海 200237 |
| 史笔函 | 华东理工大学，上海 200237 |
| 蔡兰坤 | 华东理工大学，上海 200237 |
|
| Author | Institution |
| ZHU Yi-liang | East China University of Science and Technology, Shanghai 200237, China |
| YAN Ying | East China University of Science and Technology, Shanghai 200237, China |
| ZHOU Hao | Shanghai Museum, Shanghai 200050, China |
| WU Lai-ming | Shanghai Museum, Shanghai 200050, China |
| WU Xue-wei | East China University of Science and Technology, Shanghai 200237, China |
| SHI Bi-han | East China University of Science and Technology, Shanghai 200237, China |
| CAI Lan-kun | East China University of Science and Technology, Shanghai 200237, China |
|
| 摘要点击次数: |
| 全文下载次数: |
| 中文摘要: |
| 目的 研究臭氧与LED灯光共同作用于银质文物模拟材料的腐蚀行为和规律。方法 采用石英晶体微天平（QCM）反应性监测及SEM-EDS等方法，研究了暴露于臭氧和LED灯下的银质文物模拟材料的腐蚀行为及其表面特征。结果 暴露于LED灯或臭氧条件下的石英晶振片频率均有所下降，而暴露于LED灯加臭氧复合条件下的石英晶振片频率下降速率更快且最终下降值更多。此外，升高LED灯色温、增大臭氧浓度或提高环境温度，均会使石英晶振片频率下降速率更快且最终下降值更大。在臭氧质量浓度为5 μg/L环境中，与无光照条件相比，LED光照下的银片表面的腐蚀产物及氧元素含量较多，并且LED灯的色温越高，其光照下的银片表面生成的腐蚀产物越多，但不同品牌的LED灯下的银片表面腐蚀产物生成量及氧元素含量均相近。结论 臭氧与LED灯光均会加速银的腐蚀，两者共同作用时，会使银腐蚀更严重。升高LED灯色温、增加臭氧浓度或提升环境温度也同样会加速银的腐蚀，但不同品牌LED灯对银腐蚀的影响却相差无几。 |
| 英文摘要: |
| The work aims to study the corrosion behavior and mechanism of silver relics simulation materials which were exposed to ozone and LED lighting. Quartz crystal microbalance (QCM) and SEM-EDS were used to study the corrosion behavior and surface characteristics of silver relics simulation materials which were exposed to ozone and LED lighting. Frequency of silver-electrodeposited quartz crystal exposed to LED lighting or ozone decreased slightly, while that of silver-electrodeposited quartz crystal exposed to the compound condition of LED lighting and ozone decreased faster and more. Besides, the frequency of silver-electrodeposited quartz crystal decreased faster and more as color temperature of LED, ozone concentration or ambient temperature increased. Compared with light-free condition, more corrosion products and higher oxygen content were generated on the surface of silver exposed to LED lighting in an ozone environment with mass concentration of 5 μg/L. The higher the color temperature of LED lighting was, the more corrosion products were generated on the surface of silver. However, the production of corrosion products and the content of oxygen element on the surface of silver exposed to different brands of LED were similar. Ozone and LED lights will accelerate the corrosion of silver especially when the two coexist. The corrosion rate of silver increases with the increase of the LED color temperature, ozone concentration or ambient temperature while LED brands have similar influence on the silver corrosion. |
| 查看全文 查看/发表评论 下载PDF阅读器 |
| 关闭 |
|
|
|
渝公网安备 50010702501715号