姚彦,丁雪峰,杨丽景,鞠鹏飞,何燕霖,宋振纶.镁锂合金腐蚀行为及干法镀膜防护工艺研究[J].表面技术,2016,45(12):56-61.
YAO Yan,DING Xue-feng,YANG Li-jing,JU Peng-fei,HE Yan-lin,SONG Zhen-lun.Corrosion Behavior and Dry Coating Protection of Magnesium Lithium Alloy[J].Surface Technology,2016,45(12):56-61 |
| 镁锂合金腐蚀行为及干法镀膜防护工艺研究 |
| Corrosion Behavior and Dry Coating Protection of Magnesium Lithium Alloy |
| 投稿时间：2016-03-04 修订日期：2016-12-20 |
| DOI：10.16490/j.cnki.issn.1001-3660.2016.12.009 |
| 中文关键词: 镁锂合金 腐蚀行为 PVD 纯铝膜 组织形貌 |
| 英文关键词:Mg-Li alloy corrosion behavior PVD pure aluminium film microstructure morphology |
| 基金项目:浙江省公益项目（2015C31031） |
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| Author | Institution |
| YAO Yan | 1.School of Materials Science and Engineering, Shanghai University, Shanghai 200072, China; 2.Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China |
| DING Xue-feng | Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China |
| YANG Li-jing | Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China |
| JU Peng-fei | Shanghai Spaceflight Manufacture (Group) Co., Ltd, Shanghai 200245, China |
| HE Yan-lin | School of Materials Science and Engineering, Shanghai University, Shanghai 200072, China |
| SONG Zhen-lun | Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China |
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| 中文摘要: |
| 目的 利用PVD磁控溅射技术，在样品上沉积纯铝膜，以提高镁锂合金的耐腐蚀性能。方法 采用动态极化曲线、交流阻抗方法研究镁锂合金在去离子水和3.5%NaCl溶液两种介质中的电化学行为，并利用感应耦合等离子体发射光谱仪技术和荧光金相显微镜，分别测定合金的成分，分析微观组织结构。采用扫描电子显微镜和EDS能谱仪分析镁锂合金纯铝膜的组织形貌与结构成分。此外，采用电化学技术测试纯铝膜的保护行为。结果 在3.5%NaCl溶液中，镁锂合金的腐蚀电流密度比去离子水介质中的高约两个数量级，且腐蚀电位较负；交流阻抗结果显示，比去离子水中的阻抗模值低一个数量级，说明镁锂合金抗Cl侵蚀的能力较差。通过磁控溅射技术，获得了厚度为4 μm致密的纯铝膜。镀铝后，镁锂合金的腐蚀电流密度降低了约一个数量级，腐蚀电位正移，耐蚀性提高。结论 致密的纯铝膜在3.5%NaCl溶液介质中容易发生钝化，阻碍Cl的扩散，进而提高了镁锂合金耐Cl侵蚀性。 |
| 英文摘要: |
| The work aims to improve corrosion resistance of Mg-Li alloy by depositing pure Al film on a sample by means of PVD magnetron sputtering technology. The electrochemical behavior of Mg-Li alloy in deionized water and 3.5% NaCl solution was studied by virtue of dynamic polarization curve and AC impedance spectrum. The alloy composition was determined and microstructure was analyzed by virtue of inductively coupled plasma emission spectrometer (inductively coupled plasma-AES) and fluorescence metallographic microscope. The morphology and compositionof pure Al film on Mg-Li alloy were analyzed by scanning electron microscope (SEM) and energy disperse spectroscopy. The electrochemical behavior of the sample with pure Al film was also tested on electrochemical workstation. For uncoated Mg-Li alloy, the corrosion current density was two orders of magnitude higher than that in deionized water when tested in 3.5% NaCl solution, the corrosion potential was more negative. According to alternating-current impedance results, the impedance modulus value obtained in 3.5% NaCl solution was about one order of magnitude lower than that in deionized water. Compared with uncoated alloy, resistance of Mg-Li alloy to Cl corrosion was weaker. A 4 μm dense pure Al film was obtained by virtue of magnetron sputtering technology. After being aluminized, corrosion current density of the Mg-Li alloy reduced by nearly one order of magnitude, the corrosion potential moved positively and corrosion resistance increased. Dense pure Al film is susceptible to passivation in 3.5% NaCl solution, hindering the diffusion of Cl and further improving the erosion resistance of Mg-Li alloy to Cl. |
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