李涌泉,杜晓娟,蒋亮,张小丽,魏杰.活性元素Y 对高Nb-TiAl 合金表面硅化物渗层组织的影响[J].表面技术,2016,45(10):28-33.
LI Yong-quan,DU Xiao-juan,JIANG Liang,ZHANG Xiao-li,WEI Jie.Effects of Active Element Y on Formation of Silicide Co-deposition Coatings on High Nb-TiAl Alloy[J].Surface Technology,2016,45(10):28-33 |
| 活性元素Y 对高Nb-TiAl 合金表面硅化物渗层组织的影响 |
| Effects of Active Element Y on Formation of Silicide Co-deposition Coatings on High Nb-TiAl Alloy |
| 投稿时间：2016-04-18 修订日期：2016-10-20 |
| DOI：10.16490/j.cnki.issn.1001-3660.2016.10.005 |
| 中文关键词: TiAlNb9 合金 Si-Y 共渗层 渗层结构 活性元素Y |
| 英文关键词:TiAlNb9 alloy Si-Y co-deposition coating microstructure active element Y |
| 基金项目:宁夏高等学校科学技术研究项目（NGY2015146） |
| 作者 | 单位 |
| 李涌泉 | 北方民族大学 材料科学与工程学院，银川 750021 |
| 杜晓娟 | 特种能源集团西安庆华公司 计量理化中心，西安 710025 |
| 蒋亮 | 北方民族大学 材料科学与工程学院，银川 750021 |
| 张小丽 | 北方民族大学 材料科学与工程学院，银川 750021 |
| 魏杰 | 北方民族大学 材料科学与工程学院，银川 750021 |
|
| Author | Institution |
| LI Yong-quan | School of Material Science & Engineering, Beifang University of Nationalities, Yinchuan 750021, China |
| DU Xiao-juan | Measuring Physical and Chemical Center, Special Energy Group of Xi'an Qinghua, Xi'an 710025, China |
| JIANG Liang | School of Material Science & Engineering, Beifang University of Nationalities, Yinchuan 750021, China |
| ZHANG Xiao-li | School of Material Science & Engineering, Beifang University of Nationalities, Yinchuan 750021, China |
| WEI Jie | School of Material Science & Engineering, Beifang University of Nationalities, Yinchuan 750021, China |
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| 中文摘要: |
| 目的 提高Nb-TiAl 合金的抗高温氧化性能。方法 采用NaF 为催化剂、1080 ℃下Si-Y 扩散共渗5 h 的方法，在高Nb-TiAl 表面制备了Y 改性硅化物渗层，利用SEM、EDS 和XRD 分析了渗剂中Y2O3 含量对共渗层组织及相组成的影响。结果 采用不同含量Y2O3 所制备的Si-Y 共渗层具有多层复合结构，共渗层的厚度随Y 元素的添加呈先增大后减小的趋势，共渗层的内层均由γ-TiAl 相组成；当渗剂中Y2O3 含量为2%和3%(质量分数)时，共渗层的外层主要为(Ti, Nb)Si2 相，中间层分为上下两层，分别为(Ti, Nb)5Si4 相和(Ti, Nb)5Si3 相，其中2% Y2O3 的Si-Y 共渗层有一层富Al 的(Ti, Nb)5Si4 和(Ti,Nb)5Si3 相组成的浅表层；当渗剂中Y2O3 含量为0%、1%和5%时，共渗层外层以(Ti, Nb)5Si4 相为主，中间层主要为(Ti, Nb)5Si3 相。结论 稀土Y 元素质量分数为2%~3%时具有明显的促渗作用，且获得的Si-Y 渗层组织结构致密，但添加过量的稀土元素会抑制Si 元素的吸附与扩散，使得Si-Y 共渗层中产生较多的孔洞，同时渗层的组织结构发生了改变。 |
| 英文摘要: |
| The work aims to improve high temperature oxidation resistance of Nb-TiAl alloy. In this paper, Y modified silicide coating was prepared on high Nb-TiAl surface by taking NaF as catalyst and diffusing and co-penetrating Si-Y for 5 h under 1080 ℃. Effects of Y2O3 content in permeating agent on co-deposition coating and its phase composition were analyzed by virtue of XRD, SEM and EDS. All Si-Y coatings prepared with different contents of Y2O3 were provided with a multi-layer composite structure. Thickness of the coatings firstly increased and then decreased with the addition of Y element in the pack. All inlayers of the coatings were mainly composed of a γ-TiAl phase. The outer layers of the coatings prepared at 1080 ℃ for 5 h with the pack mixture containing 2% or 3% Y2O3 were mainly composed of (Ti，Nb)Si2 phase, and the middle layer was divided into upper and lower layers composing of (Ti, X)5Si4 and (Ti, X)5Si3 respectively. Moreover, a superficial layer consisting of Al-rich (Ti,Nb)5Si4 and (Ti,Nb)5Si3 was detected in the coating prepared with 2% Y2O3. However, the constituent phase turned to (Ti, Nb)5Si4 in the out layer and (Ti, X)5Si3 in the middle layer of the co-deposition coating when the pack mixture contained 0%, 1% or 5% Y2O3. The coating growth can be catalyzed obviously when the content of Y2O3 in the pack mixtures ranges between 2%~3%. However, excess addition of rare earth element will restrain the adsorption and diffusion of Si element, and thus a number of holes will appear on Si-Y co-deposition coating and the layer structure will change. |
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