王丹,周小平.AZ31B镁合金表面喷熔Al涂层的组织和性能[J].表面技术,2016,45(9):51-55.
WANG Dan,ZHOU Xiao-ping.Microstructure and Properties of Al Coating Sprayed on the Surface of AZ31B Magnesium Alloy[J].Surface Technology,2016,45(9):51-55 |
| AZ31B镁合金表面喷熔Al涂层的组织和性能 |
| Microstructure and Properties of Al Coating Sprayed on the Surface of AZ31B Magnesium Alloy |
| 投稿时间：2016-04-22 修订日期：2016-09-20 |
| DOI：10.16490/j.cnki.issn.1001-3660.2016.09.008 |
| 中文关键词: 氧乙炔喷熔 AZ31B镁合金 喷熔Al涂层 等轴晶 浸泡 耐蚀性 硬度 |
| 英文关键词:oxygen acetylene spray welding AZ31B magnesium alloy sprayed Al coating equal axial grain immersion corrosion resistance hardness |
| 基金项目:国家自然科学基金资助项目（51171062） |
| 作者 | 单位 |
| 王丹 | 湖北工业大学 机械工程学院，绿色轻工材料湖北省重点实验室，武汉 430068 |
| 周小平 | 湖北工业大学 机械工程学院，绿色轻工材料湖北省重点实验室，武汉 430068 |
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| Author | Institution |
| WANG Dan | Hubei Key Laboratory of Green Light Industrial Materials, School of Mechanical Engineering, Hubei University of Technology, Wuhan 430068, China |
| ZHOU Xiao-ping | Hubei Key Laboratory of Green Light Industrial Materials, School of Mechanical Engineering, Hubei University of Technology, Wuhan 430068, China |
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| 中文摘要: |
| 目的 提高AZ31B镁合金的耐蚀性。方法 采用氧乙炔在AZ31B镁合金表面喷熔Al涂层，对喷熔的Al涂层进行扫描电镜（SEM）分析，采用能谱仪（EDS）对涂层进行面扫描检测涂层元素的分布情况。利用电化学分析法、浸泡试验检测喷熔涂层的耐蚀性，用维氏硬度计测试喷熔涂层的硬度。结果 喷熔的Al涂层与AZ31B镁合金基体结合良好，呈现冶金结合。喷涂过程中，喷熔的Al涂层呈等轴晶生长。通过面扫描结果可知，喷熔涂层中发现Mg元素，说明基体中的Mg元素发生了扩散。通过电化学测试可知，喷熔Al涂层的自腐蚀电压为1.45 V，比AZ31B镁合金的自腐蚀电压（1.5 V）降低了0.05 V；喷熔Al涂层的自腐蚀电流密度为1.58×104 A/cm2，约为AZ31B镁合金自腐蚀电流密度（8.66×104 A/cm2）的1/5。由浸泡实验可知，喷熔Al涂层的平均腐蚀速率约为AZ31B镁合金的1/5倍。喷熔Al涂层的显微硬度是AZ31B镁合金基体硬度的2.9倍。结论 喷熔Al涂层的组织较好，性能比镁合金基体有所提高。 |
| 英文摘要: |
| Objective To improve the corrosion resistance of AZ31B magnesium alloy. Methods Al coating was sprayed on AZ31B magnesium alloy by using oxygen acetylene. Then scanning electron microscope (SEM) analysis was conducted on Al coating sprayed. The distribution of coating elements was detected by using energy dispersive spectroscopy (EDS). The corrosion resistance of sprayed coating was detected by electrochemical workstation and immersion test; and the hardness was tested by Vickers. Results The combination of the Al coating and the substrate was very good, which presented metallurgical bonding. During the spraying process, sprayed Al coating showed equal axial grain growth. Through the surface scanning element distribution, Mg element was found in the spray coating, which indicated that Mg element had diffused in the substrate. According to the electrochemical workstation, the self-corrosion voltage of Al coating was 1.45 V, 0.05 V lower than AZ31B magnesium alloy (1.5 V); the self-corrosion current of Al coating was 1.58×104 A/cm2, about 1/5 of AZ31B magnesium alloy (8.66×104 A/cm2). The immersion test showed the average corrosion rate of Al coating was about 1/5 of AZ31B magnesium alloy. Conclusion The microstructure and properties of Al coating have been improved. |
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