王秀阁,蔡明建.芳香希夫碱在油田采出水中的缓蚀性能研究[J].表面技术,2017,46(1):187-192.
WANG Xiu-ge,CAI Ming-jian.Corrosion Inhibition of Aromatic Schiff Base in Oilfield Water[J].Surface Technology,2017,46(1):187-192 |
| 芳香希夫碱在油田采出水中的缓蚀性能研究 |
| Corrosion Inhibition of Aromatic Schiff Base in Oilfield Water |
| 投稿时间：2016-05-23 修订日期：2017-01-20 |
| DOI：10.16490/j.cnki.issn.1001-3660.2017.01.030 |
| 中文关键词: 缓蚀剂 希夫碱 N80碳钢 缓蚀性能 |
| 英文关键词:corrosion inhibitor Schiff base N80 carbon steel inhibiting efficiency |
| 基金项目:河北省教育厅项目（ZC2016083）；唐山师范学院2014平台（重点）团队支撑项目（2014D02） |
| 作者 | 单位 |
| 王秀阁 | 唐山师范学院 化学系，河北 唐山 063000 |
| 蔡明建 | 唐山师范学院 化学系，河北 唐山 063000 |
|
| Author | Institution |
| WANG Xiu-ge | Department of Chemistry, Tangshan Normal University, Tangshan 063000, China |
| CAI Ming-jian | Department of Chemistry, Tangshan Normal University, Tangshan 063000, China |
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| 中文摘要: |
| 目的 研究不同复配型芳香希夫碱缓蚀剂在油田采出水中对N80碳钢的缓蚀效果。方法 采用静态失重和旋转挂片实验比较四种芳香希夫碱的缓蚀速率，采用电化学测试、扫描电镜和EDS手段对N80碳钢进行表征和分析。结果 在油田采出水中添加芳香希夫碱复配型缓蚀剂后，试样表面生成以铁、碳、氧元素为主的保护膜，当四种缓蚀剂的添加量达到90 mg/L时，N80碳钢的腐蚀速率下降趋势变化缓慢，a型缓蚀剂的缓蚀效果最好，其用量为90 mg/L时，N80碳钢的腐蚀速率降低到0.0087 mm/a，自腐蚀电位由-0.8112 V提高到-0.7345 V，自腐蚀电流由77.79 μA下降到5.410 μA，缓蚀率可达到93.05%。结论 四种希夫碱复配缓蚀剂均有较好的缓蚀性能，缓蚀剂的缓蚀效果顺序为a＞b＞d＞c。 |
| 英文摘要: |
| The work aims to study corrosion inhibition effect of different composite aromatic Schiff base corrosion inhibitor for N80 steel in oilfield water. The inhibiting rate of four kinds of composite Schiff base was compared by static weight- loss and dynamic weight-loss methods. The corrosion inhibition effect of composite Schiff base in oilfield water was characterized by electrochemical test, scanning electron microscope and EDS. A layer of protective film mainly consisting of iron, carbon and oxygen elements formed on surface of the sample with composite aromatic Schiff added to the oil field water. The corrosion rate decreased slowly as addition of four corrosion inhibitors reached 90 mg/L. The inhibiting efficiency of type a was the best among all corrosion inhibitors. Provided that 90 mg/L was consumed, corrosion rate of N80 carbon steel reduced to 0.0087 mm/a, self-corrosion potential increased from -0.8112 V to -0.7345 V, self-corrosion current reduced from 77.79 μA to 5.410 μA and inhibiting rate reached 93.05%. All four composite Schiff base composite corrosion inhibitor show good inhibiting efficiency for N80 steel in oilfield water with order of inhibiting efficiency as: a>b>d>c. |
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