李红伟,李雯,付涛,杨水云.低模量钛合金表面水热法制备含银二氧化钛抗菌薄膜[J].表面技术,2015,44(9):50-55.
LI Hong-wei,LI Wen,FU Tao,YANG Shui-yun.Hydrothermal Preparation of Antibacterial Ag-containing TiO2 Film on a Low-modulus Titanium Alloy[J].Surface Technology,2015,44(9):50-55
低模量钛合金表面水热法制备含银二氧化钛抗菌薄膜
Hydrothermal Preparation of Antibacterial Ag-containing TiO2 Film on a Low-modulus Titanium Alloy
投稿时间:2015-05-07  修订日期:2015-09-20
DOI:10.16490/j.cnki.issn.1001-3660.2015.09.009
中文关键词:  医用钛合金  水热处理  二氧化钛  纳米银  抗菌薄膜
英文关键词:biomedical titanium alloy  hydrothermal treatment  titanium dioxide  nano silver  antimicrobial film
基金项目:国家自然科学基金(50901058);中央高校基本科研业务费专项资金资助(CHD2011JC001)
作者单位
李红伟 长安大学, 西安 710064 
李雯 长安大学, 西安 710064 
付涛 西安交通大学, 西安 710049 
杨水云 西安交通大学, 西安 710049 
AuthorInstitution
LI Hong-wei Chang'an University, Xi'an 710064, China 
LI Wen Chang'an University, Xi'an 710064, China 
FU Tao Xi'an Jiaotong University, Xi'an 710049, China 
YANG Shui-yun Xi'an Jiaotong University, Xi'an 710049, China 
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中文摘要:
      目的 提高医用低模量近 β 型 TLM(Ti-25Nb-3Zr-2Sn-3Mo)钛合金的抗菌性能。 方法 在 200 ℃条件下,在硝酸银溶液中对 TLM 合金分别进行 12,24 h 水热处理,在其表面制备含银 TiO2 抗菌薄膜。 通过 SEM,XRD,XPS 等表征薄膜的微观结构及状态。 以去离子水水热处理 TLM 合金作为参照,比较薄膜的亲水性,并采用抑菌圈法研究其抗菌性能。 结果 SEM,XRD 及 XPS 分析表明,水热处理后,TLM 合金表面形成了 TiO2 纳米晶粒组成的薄膜,薄膜中的钛和铌分别以 TiO2 和 Nb2O5 形式存在,银以金属态存在。 接触角测试结果表明,水热处理试样表面具有良好的光致亲水性,紫外光照射 30 min 后,水接触角从 108°降低到 10°以下。 抗菌实验中,水热处理试样在对大肠杆菌和金黄葡萄球菌培养 24 h 后,产生了明显的抑菌圈,相比之下,对金黄葡萄球菌的抑菌圈较宽。 结论 硝酸银溶液水热法在医用钛合金表面可以合成含银 TiO2 薄膜,具有工艺简便、处理温度低、抗菌效果明显等优点。
英文摘要:
      Objective To improve the antimicrobial properties of near β-type biomedical titanium alloy TLM (Ti-25Nb-3Zr-2Sn-3Mo) with low modulus. Methods TLM alloy was hydrothermally treated in silver nitrate solution at 200 ℃ with AgNO3 solution for 12 h and 24 h respectively to prepare antibacterial Ag-containing TiO2 film on its surface. The microstructure and status of the film were characterized by SEM, XRD and XPS. Using the TLM alloy hydrothermally treated in deionized water as the control, the hydrophilicity of the film was compared, and the antimicrobial properties were studied using the inhibition zone method. Results SEM, XRD and XPS analyses showed that the film consisting of TiO2 nanocrystals was formed on the surface of TLM alloy after the hydrothermal treatment. X-ray photoelectron spectroscopy analysis illustrated that Ti and Nb on sample surface existed as TiO2 and Nb2 O5 respectively, and Ag was in the metallic form. Contact angle measurement indicated that the treated sample had good photoinduced hydrophilicity, and the contact angle decreased from 108° to below 10° after 30 min of UV irradiation. In the antibacterial test, obvious inhibition zones against E. coli and S. aureus were observed for the treated sample after 24 h culture, and the inhibition zone was wider against S. aureus. Conclusion Through hydrothermal treatment at 200 ℃ with 10 mmol / L of AgNO3 solution, Ag-containing TiO2 film with antimicrobial properties could be synthesized. The hydrothermal method to prepare Ag-containing TiO2 film in medical titanium alloy has the merits of easy operation, low processing temperature, evident antibacterial effect, etc.
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