李嘉,谢铮,何箐,邹晗,吕玉芬.Gd2 O3 -Yb2 O3 -Y2 O3 -ZrO2 热障涂层材料的热物理性能[J].表面技术,2015,44(9):18-22,42.
LI Jia,XIE Zheng,HE Jing,ZOU Han,LYU Yu-fen.Thermophysical Properties of Gd2O3-Yb2O3-Y2O3-ZrO2 Thermal Barrier Coating Material[J].Surface Technology,2015,44(9):18-22,42
Gd2 O3 -Yb2 O3 -Y2 O3 -ZrO2 热障涂层材料的热物理性能
Thermophysical Properties of Gd2O3-Yb2O3-Y2O3-ZrO2 Thermal Barrier Coating Material
投稿时间:2015-06-16  修订日期:2015-09-20
DOI:10.16490/j.cnki.issn.1001-3660.2015.09.004
中文关键词:  热障涂层  稀土氧化物  掺杂改性  氧化锆  热物性  高温相稳定性
英文关键词:thermal barrier coating  rare earth oxides  doping modification  zirconia  thermophysical properties  high temperature phase stability
基金项目:
作者单位
李嘉 1. 中国农业机械化科学研究院, 北京 100083; 2. 北京金轮坤天特种机械有限公司, 北京 100083 
谢铮 1. 中国农业机械化科学研究院, 北京 100083; 2. 北京金轮坤天特种机械有限公司, 北京 100083 
何箐 1. 中国农业机械化科学研究院, 北京 100083; 2. 北京金轮坤天特种机械有限公司, 北京 100083 
邹晗 1. 中国农业机械化科学研究院, 北京 100083; 2. 北京金轮坤天特种机械有限公司, 北京 100083 
吕玉芬 1. 中国农业机械化科学研究院, 北京 100083; 2. 北京金轮坤天特种机械有限公司, 北京 100083 
AuthorInstitution
LI Jia 1. Chinese Academy of Agricultural Mechanization Sciences, Beijing 100083, China;2. Beijing Golden Wheel Special Machine Co. , Ltd, Beijing 100083, China 
XIE Zheng 1. Chinese Academy of Agricultural Mechanization Sciences, Beijing 100083, China;2. Beijing Golden Wheel Special Machine Co. , Ltd, Beijing 100083, China 
HE Jing 1. Chinese Academy of Agricultural Mechanization Sciences, Beijing 100083, China;2. Beijing Golden Wheel Special Machine Co. , Ltd, Beijing 100083, China 
ZOU Han 1. Chinese Academy of Agricultural Mechanization Sciences, Beijing 100083, China;2. Beijing Golden Wheel Special Machine Co. , Ltd, Beijing 100083, China 
LYU Yu-fen 1. Chinese Academy of Agricultural Mechanization Sciences, Beijing 100083, China;2. Beijing Golden Wheel Special Machine Co. , Ltd, Beijing 100083, China 
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中文摘要:
      目的 通过多元稀土氧化物掺杂改性 YSZ,提高传统热障涂层的性能。 方法 使用化学共沉淀法制备不同掺杂量的 Gd2O3-Yb2O3-Y2O3-ZrO2(GYYZO)材料,并分别使用冷等静压-烧结和等离子喷涂工艺制备块材和涂层。 通过测试块材的热导率和热膨胀系数,分析评价材料的热物理性能。 对高温退火处理后的涂层进行 X 射线衍射分析,评价不同成分涂层的高温相稳定性。 结果 氧化锆基材料的热导率和热膨胀系数随总掺杂量升高而降低。 氧化锆中稀土氧化物总掺杂量为 5. 5% ~ 9. 84% (摩尔分数)时,在1000 ℃下的热导率为 1. 25 ~1. 56 W/ (m·K),相对 8YSZ 材料下降了 22% ~37. 5% ;在 200 ~1300 ℃的热膨胀系数为(10 ~ 11. 1) ×10-6 / K,与传统 8YSZ 材料相当。 在 1400 ℃ 长时间退火处理后,低掺杂量GYYZO 涂层中的单斜相含量明显低于 8YSZ 涂层。 结论 多元稀土氧化物掺杂改性氧化锆材料具有良好的高温相稳定性、低热导率和适当的热膨胀系数,可以作为高性能热障涂层的备选材料。
英文摘要:
      Objective To improve the performance of traditional ceramic thermal barrier coatings by rare earth oxides doping yttria stabilized zirconia (YSZ). Methods The Gd2O3-Yb2O3-Y2O3-ZrO2(GYYZO) materials with various doped contents were prepared by co-precipitation, and the GYYZO bulk materials and coatings were prepared by cold isostatic pressing (CIP) and plasma spraying(PS), respectively. The thermal conductivity and thermal expansion coefficient tests of materials with different compositions were taken to analyze and evaluate the thermophysical properties of GYYZO materials. X-ray diffraction (XRD) analysis of the coatings was conducted after high-temperature annealing treatment to evaluate the high temperature stability of coatings with different compositions. Results The thermal conductivities and coefficient of thermal expansion (CTEs) of zirconia based bulk materials decreased with the increasing doped content. The thermal conductivity of bulk GYYZO doped with 5. 5% ~9. 84% mole fraction of rare earth oxides at 1000 ℃ was 1. 25 ~1. 56 W/ (m·K), which was reduced by 22% ~37. 5% as compared with that of bulk 8YSZ, and the CTEs was (10 ~ 11. 1) ×10 -6 / K, which was closed to that of the tradition 8YSZ materials. After long-term heat treatment at 1400 ℃ , the content of monoclinic phase for GYYZO coating with low doped content was obviously lower than that of 8YSZ coating. Conclusion The multiple rare earth oxides doped YSZ has good high temperature phase stability, low thermal conductivity and suitable thermal expansion coefficient, and can be used as candidate ceramic materials for high-performance thermal barrier coatings.
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