冯磊,徐壁,蔡再生.导电双疏涤纶织物制备与性能研究[J].表面技术,2015,44(5):91-95.
FENG Lei,XU Bi,CAI Zai-sheng.Preparation and Properties of Conductive,Superhydrophobic and Oleophobic Polyester Fabrics[J].Surface Technology,2015,44(5):91-95 |
| 导电双疏涤纶织物制备与性能研究 |
| Preparation and Properties of Conductive,Superhydrophobic and Oleophobic Polyester Fabrics |
| 投稿时间：2015-01-08 修订日期：2015-05-20 |
| DOI：10.16490/j.cnki.issn.1001-3660.2015.05.017 |
| 中文关键词: 化学镀 化学气相沉积 双疏 导电 |
| 英文关键词:chemical plating chemical vapor deposition amphiphobicity electric conduction |
| 基金项目:纺织面料技术教育部重点实验室开放课题资助(14D110533);上海市自然科学基金(13ZR1451100, 12ZR1400400) |
| 作者 | 单位 |
| 冯磊 | 东华大学 纺织面料技术教育部重点实验室, 上海 201620 |
| 徐壁 | 东华大学 纺织面料技术教育部重点实验室, 上海 201620 |
| 蔡再生 | 东华大学 纺织面料技术教育部重点实验室, 上海 201620 |
|
| Author | Institution |
| FENG Lei | Key Laboratory of Textile Fabric Technology, Ministry of Education, Donghua University, Shanghai 201620, China |
| XU Bi | Key Laboratory of Textile Fabric Technology, Ministry of Education, Donghua University, Shanghai 201620, China |
| CAI Zai-sheng | Key Laboratory of Textile Fabric Technology, Ministry of Education, Donghua University, Shanghai 201620, China |
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| 中文摘要: |
| 目的 制备具有良好导电性能的超疏水疏油纺织品。 方法 首先利用化学镀方法在涤纶织物表面镀铜,构筑微米-亚微米粗糙结构,然后利用全氟辛基三甲氧基硅烷(PFTMS)通过化学气相沉积方法在镀铜织物表面覆盖一层低表面能基团,制备导电超疏水疏油织物。 采用电子扫描电镜(SEM)、能量色散 X 射线光谱仪(EDXS)、接触角测试仪和方阻测试仪对其表面形貌、表面元素分布、疏水疏油性、导电性能进行研究。 结果 PFTMS 修饰的镀 Cu 织物导电性能优异,方阻为 230 mΩ 左右,织物抗紫外线指数达到 50+;织物与水滴接触角达 152. 0°,与十六烷油滴接触角达 120. 7°。 结论 将化学镀和化学气相沉积法相结合,在涤纶纤维表面化学镀铜并用 PFTMS 进行低表面能物质修饰,可以成功制备具有导电功能的超疏水疏油纺织品。 |
| 英文摘要: |
| Objective To prepare superhydrophobic and oleophobic textile fabrics with good conductive property. Methods The surface of polyester fabric was first coated with copper using the chemical copper-plating method to build a micron-submicron structure. Then the superhydrophobic and oleophobic conductive fabrics were fabricated through chemical vapor deposition of 1H,1H, 2H,2H-perfluorooctyltrimethoxysilane (PFTMS) to generate a layer of low surface energy group on the surface of the Cu-planted polyester fabrics. The properties of amphiphobic polyester fabrics including surface morphology, element distribution, amphiphobicity and electrical conductivity were investigated with scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDXS), contact angle tester and square resistance tester. Results It showed that the PFTMS-Cu-modified polyester fabrics had outstanding conductive capability, the sheet resistance was about 230 mΩ, and the resistance to UV performance was up to 50+. The contact angles of the modified polyester fabrics with water and n-hexadecane were 152. 0° and 120. 7°, respectively. Conclusion Superhydrophobic and oleophobic fabrics with good conductive property could be successfully fabricated using PFTMS by chemical copper-plating and chemical vapor deposition method. |
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