张宁,刘永畅,陶占良,陈军.钛酸锂表面碳包覆改性研究进展[J].表面技术,2015,44(1):1-7,33.
ZHANG Ning,LIU Yong-chang,TAO Zhan-liang,CHEN Jun.Research Progress in Carbon Coating on Li4Ti5O12 Anode Materials[J].Surface Technology,2015,44(1):1-7,33 |
| 钛酸锂表面碳包覆改性研究进展 |
| Research Progress in Carbon Coating on Li4Ti5O12 Anode Materials |
| 投稿时间：2015-01-01 修订日期：2015-01-20 |
| DOI： |
| 中文关键词: Li4Ti5O12 碳包覆 负极 锂离子电池 复合材料 |
| 英文关键词:Li4Ti5O12 carbon coating anode lithium ion batteries composite |
| 基金项目:国家重点基础研究发展计划(973 计划, 2011CB935900);国家自然科学基金项目(51231003);中央高校基本科研业务费资助 |
| 作者 | 单位 |
| 张宁 | 南开大学 先进能源材料化学教育部重点实验室 天津化学化工协同创新中心, 天津 300071 |
| 刘永畅 | 南开大学 先进能源材料化学教育部重点实验室 天津化学化工协同创新中心, 天津 300071 |
| 陶占良 | 南开大学 先进能源材料化学教育部重点实验室 天津化学化工协同创新中心, 天津 300071 |
| 陈军 | 南开大学 先进能源材料化学教育部重点实验室 天津化学化工协同创新中心, 天津 300071 |
|
| Author | Institution |
| ZHANG Ning | Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education),Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, Tianjin 300071, China |
| LIU Yong-chang | Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education),Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, Tianjin 300071, China |
| TAO Zhan-liang | Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education),Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, Tianjin 300071, China |
| CHEN Jun | Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education),Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, Tianjin 300071, China |
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| 中文摘要: |
| 尖晶石结构的 Li4Ti5O12由于电压平台平稳、循环寿命长、“零应变冶和安全性高等优点,成为锂离子电池的热门负极材料。 然而纯 Li4Ti5O12本身为绝缘体,导电性很差,倍率性能不佳,这限制了它的实际应用。 研究表明,对 Li4Ti5O12表面进行碳包覆可以有效改善其电化学性能。 结合最近国内外研究情况,综述了表面碳包覆对 Li4Ti5O12负极材料改性的研究进展,分析了不同的碳包覆方法、碳层厚度、碳结构和碳含量对 Li4Ti5O12 / C 复合材料电化学性能的影响,希望促进 Li4Ti5O12 / C 复合电极材料在锂离子电池领域的应用。 |
| 英文摘要: |
| Spinel Li4Ti5O12 has become a promising anode material for lithium ion batteries because of its flat voltage, long cycle life, "zero starin" and high safety. However, the electronic conductivity of pure Li4Ti5O12 is very low, leading to bad rate performance, which limits its practical application. Studies have proven that carbon coating on Li4Ti5O12 can effectively enhance the electrochemical performance. In this review, we summarized the recent developments of modification of Li4Ti5O12 anode material by carbon coating based on the studies in China and foreign countries. Moreover, the effects of different coating methods, carbon coating thickness, carbon structure and carbon content on the electrochemical properties of the Li4Ti5O12 / C composite were analyzed, shedding light on the further application of the Li4Ti5O12 / C composite as high-performance anode of lithium ion batteries. |
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