张译文,李垚,强亮生,郝健,刘旭松,安小坤,赵九蓬.电沉积乙炔黑 / 锗材料及其性能研究[J].表面技术,2014,43(6):11-15.
ZHANG Yi-wen,LI Yao,QIANG Liang-sheng,HAO Jian,LIU Xu-song,AN Xiao-kun,ZHAO Jiu-peng.Research on the Properties of Acetylene Black/ Ge Prepared by Electrochemical Deposition[J].Surface Technology,2014,43(6):11-15 |
| 电沉积乙炔黑 / 锗材料及其性能研究 |
| Research on the Properties of Acetylene Black/ Ge Prepared by Electrochemical Deposition |
| 投稿时间：2014-06-14 修订日期：2014-12-10 |
| DOI： |
| 中文关键词: 锂离子电池 负极 乙炔黑/ 锗 电化学性能 |
| 英文关键词:lithium-ion battery negative electrode acetylene black/ Ge electrochemical properties |
| 基金项目: |
| 作者 | 单位 |
| 张译文 | 哈尔滨工业大学 理学院, 哈尔滨 150001 |
| 李垚 | 哈尔滨工业大学 复合材料与结构研究所,哈尔滨 150001 |
| 强亮生 | 哈尔滨工业大学 理学院, 哈尔滨 150001 |
| 郝健 | 哈尔滨工业大学 化工学院,哈尔滨 150001 |
| 刘旭松 | 哈尔滨工业大学 化工学院,哈尔滨 150001 |
| 安小坤 | 哈尔滨工业大学 化工学院,哈尔滨 150001 |
| 赵九蓬 | 哈尔滨工业大学 化工学院,哈尔滨 150001 |
|
| Author | Institution |
| ZHANG Yi-wen | School of Science, Harbin Institute of Technology, Harbin 150001, China |
| LI Yao | Center for Composite Material, Harbin Institute of Technology, Harbin 150001, China |
| QIANG Liang-sheng | School of Science, Harbin Institute of Technology, Harbin 150001, China |
| HAO Jian | School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001, China |
| LIU Xu-song | School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001, China |
| AN Xiao-kun | School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001, China |
| ZHAO Jiu-peng | School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001, China |
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| 中文摘要: |
| 目的 提高锂离子电池锗基材料的电化学性能。 方法 采用电泳和离子液体电沉积制备乙炔黑/ 锗负极材料,用 SEM,Raman 和充放电循环等手段表征其结构和性能。 结果 乙炔黑/ 锗负极材料在0. 2C 倍率下循环 100 次,比容量依然可达到 600 mAh/ g 以上。 结论 乙炔黑/ 锗负极材料的电化学性能明显优于单独锗材料和碳材料。 |
| 英文摘要: |
| Objective To improve the electrochemical performance of the germanium materials of lithium-ion batteries. Methods Germanium nanoparticles (Ge-NPs) and acetylene black anodes were fabricated through electrodeposition of Ge in the new-genera-tion ionic liquids on the surface of acetylene black which was electrophoretically deposited on a copper current collector. The structure and electrochemical properties were characterized by electron microscopy, Raman spectroscopy and constant current chargedischarge methods. Results The acetylene black-Ge nanocomposite exhibited the electrochemical cycling properties of over 600 mAh/ g at 0. 2C after 100 cycles. Conclusion The electrochemical performance of composite was obviously better than Ge or acetylene black by itself as anode electrode material. |
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