孙延安,李春福,张家林,张雷,张凤春,许萍.Ni-Fe-P 化学镀层抗 CO2 腐蚀性机理研究[J].表面技术,2014,43(6):1-5.
SUN Yan-an,LI Chun-fu,ZHANG Jia-lin,ZHANG Lei,ZHANG Feng-chun,XU Ping.Investigation on the Protective Mechanism of Ni-Fe-P Electroless Plating Against CO2 Corrosion[J].Surface Technology,2014,43(6):1-5
Ni-Fe-P 化学镀层抗 CO2 腐蚀性机理研究
Investigation on the Protective Mechanism of Ni-Fe-P Electroless Plating Against CO2 Corrosion
投稿时间:2014-08-08  修订日期:2014-12-10
DOI:
中文关键词:  化学镀  Ni-Fe-P 镀层  抗 CO2 腐蚀
英文关键词:electroless plating  Ni-Fe-P coating  CO2 corrosion resistance
基金项目:国家高技术研究发展计划(863 计划,2006AA06A105)
作者单位
孙延安 1. 西南石油大学 材料科学与工程学院, 成都 610500; 2. 大庆油田有限责任公司采油工程研究院, 黑龙江 大庆 163453 
李春福 西南石油大学 材料科学与工程学院, 成都 610500 
张家林 西南石油大学 材料科学与工程学院, 成都 610500 
张雷 西南石油大学 材料科学与工程学院, 成都 610500 
张凤春 西南石油大学 材料科学与工程学院, 成都 610500 
许萍 大庆油田有限责任公司 第三采油厂, 黑龙江 大庆 163453 
AuthorInstitution
SUN Yan-an 1. School of Materials Science and Engineering, Southwest Petroleum University, Chengdu 610500, China;2. Oil Production Technology Research Institute, Daqing Oilfield Company Ltd, Daqing 163453, China; 
LI Chun-fu School of Materials Science and Engineering, Southwest Petroleum University, Chengdu 610500, China 
ZHANG Jia-lin School of Materials Science and Engineering, Southwest Petroleum University, Chengdu 610500, China 
ZHANG Lei School of Materials Science and Engineering, Southwest Petroleum University, Chengdu 610500, China 
ZHANG Feng-chun School of Materials Science and Engineering, Southwest Petroleum University, Chengdu 610500, China 
XU Ping No. 3 Oil Production Company, Daqing Oilfield Company Ltd, Daqing 163453, China 
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中文摘要:
      目的 研究 Ni-Fe-P 化学镀层抗 CO2 腐蚀性机理。 方法 通过 SEM,EDS,XRD 以及 EIS 等技术对经化学镀 Ni-Fe-P 处理后的 35CrMo 钢表面进行表征,分析其抗 CO2 的腐蚀性能。 结果 处理后的35CrMo 钢表面为非晶态组织,硬度高达 570. 12HV。 Ni-Fe-P 镀层钢腐蚀倾向减小,极化电阻增大,镀层对基体形成了较好保护。 镀层的腐蚀过程受溶液双电层和钝化膜的影响。 结论 Ni-Fe-P 镀层在 CO2 水溶液中具有极强的钝化倾向,可显著提高材料的抗 CO2 腐蚀性能。
英文摘要:
      Objective To investigate the mechanism of CO2 corrosion resistance of Ni-Fe-P coating. Methods By means of SEM,EDS,XRD and EIS, CO2 corrosion resistance behavior at the surface of 35CrMo with Ni-Fe-P coating was characterized and analyzed. Results The results showed that after Ni-Fe-P coating, the surface of 35CrMo was turned into amorphous microstructure and its hardness reached up to 570. 12HV. The polarization resistance increased and the corrosion tendency decreased, which provided good protection for the matrix. During the corrosion process, the corrosion behavior of the coating was affected by electric double layer capacitance and passivated film. Conclusion The Ni-Fe-P coating could significantly improve the resistance to CO2 due to its great passivation tendency in CO2 solution.
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