佟欣佳,柳鑫华,丁云飞,张雪明.环境友好型聚天冬氨酸衍生物的合成及其阻垢性能[J].表面技术,2013,42(5):62-65,80.
TONG Xin-jia,LIU Xin-hua,DING Yun-fei,ZHANG Xue-ming.Synthesis of Friendly-to-environment Polyaspartic Acid Derivative and Its Characteristics in Scale Inhibition[J].Surface Technology,2013,42(5):62-65,80 |
| 环境友好型聚天冬氨酸衍生物的合成及其阻垢性能 |
| Synthesis of Friendly-to-environment Polyaspartic Acid Derivative and Its Characteristics in Scale Inhibition |
| 投稿时间：2013-04-26 修订日期：2013-06-10 |
| DOI： |
| 中文关键词: 聚天冬氨酸 开环改性 阻垢剂 阻垢性能 |
| 英文关键词:PASP ring-opening to improve performance scale inhibitor scale inhibition properties |
| 基金项目:河北省科技局科技攻关项目(06213027) |
| 作者 | 单位 |
| 佟欣佳 | 河北联合大学 轻工学院, 唐山 063000 |
| 柳鑫华 | 河北联合大学 轻工学院, 唐山 063000 |
| 丁云飞 | 河北联合大学 轻工学院, 唐山 063000 |
| 张雪明 | 河北联合大学 轻工学院, 唐山 063000 |
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| Author | Institution |
| TONG Xin-jia | College of Light Industry, Hebei United University, Tangshan 063000 , China |
| LIU Xin-hua | College of Light Industry, Hebei United University, Tangshan 063000 , China |
| DING Yun-fei | College of Light Industry, Hebei United University, Tangshan 063000 , China |
| ZHANG Xue-ming | College of Light Industry, Hebei United University, Tangshan 063000 , China |
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| 中文摘要: |
| 利用马来酸酐热缩聚产物聚琥珀酰亚胺( PSI ) 和硫脲,合成了一种聚天冬氨酸衍生物。 优化了PSI 与硫脲的反应条件,通过红外光谱对聚天冬氨酸衍生物的结构进行了表征,考察了聚天冬氨酸衍生物的阻垢性能,分析了其阻垢机制。 结果表明:以硫脲对 PSI 进行开环,当硫脲用量为 1 g,改性缩聚温度为 100 ℃ ,反应时间为 2 . 5 h 时,获得改性 PASP 产品的阻垢效果最佳;红外光谱证明了硫脲的一个氨基与原支链上的羧基发生缩合,生成酰胺键,在聚天冬氨酸侧链上增加了新的官能团;聚天冬氨酸衍生物用量为 10 mg / L 时,阻垢率可达到90% 以上。 |
| 英文摘要: |
| Polyaspartic acid derivative was synthesised with sulfourea ( CSN) and polysuccinimide ( PSI ) that was the thermal condensation polymer of MA. The reaction condition of PSI and CSN was optimized. The product structure was characterized by FT-IR. And the scale inhibition properties and mechanism of CSN-PASP were studied. The result indicates that the scale inhibition efficiency of CSN-PASP is optimum in CSN with 1 . 0 g under the condition of 100 ℃ and 2 . 5 h with CSN to ring opening of PSI. FT-IR proves that amide bond was generated through aminos of sulfourea and carboxyls and the new functional groups are increased on the side chain. CSN-PASP with 10 mg / L, the scale inhibition efficiency is up to 90 % . |
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