王招娣,司云森,余强,陈宁.酸性介质中曼尼希碱与KCl复配对A3钢的缓蚀性能研究[J].表面技术,2010,39(6):44-45,50. WANG Zhao-di,SI Yun-sen,YU Qiang,CHEN Ning.The Inhibitive Effect of a Mannich Corrosion Inhibitor and KCl Formulation on the Corrosion of A3 Steel in Acid Medium[J].Surface Technology,2010,39(6):44-45,50 |
酸性介质中曼尼希碱与KCl复配对A3钢的缓蚀性能研究 |
The Inhibitive Effect of a Mannich Corrosion Inhibitor and KCl Formulation on the Corrosion of A3 Steel in Acid Medium |
投稿时间:2010-07-27 修订日期:2010-12-10 |
DOI: |
中文关键词: 缓蚀剂 曼尼希碱 氯化钾 复配 A3钢 |
英文关键词:corrosion inhibitor Mannich formulation AC impedance A3 steel |
基金项目: |
作者 | 单位 |
王招娣 | 昆明理工大学冶金与能源工程学院,昆明650093 |
司云森 | 昆明理工大学冶金与能源工程学院,昆明650093 |
余强 | 昆明理工大学冶金与能源工程学院,昆明650093 |
陈宁 | 昆明理工大学冶金与能源工程学院,昆明650093 |
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Author | Institution |
WANG Zhao-di | Kunming University of Science and Technology, Kunming 650093, China |
SI Yun-sen | Kunming University of Science and Technology, Kunming 650093, China |
YU Qiang | Kunming University of Science and Technology, Kunming 650093, China |
CHEN Ning | Kunming University of Science and Technology, Kunming 650093, China |
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中文摘要: |
以乙醛、丙酮和二乙胺为原料合成了曼尼希碱酸化缓蚀剂ZD-1。在加入1 g/ L的ZD-1和不同浓度KCl的5%(质量分数)H2SO4溶液中,测试了A3钢的缓蚀率及动电位扫描极化曲线和交流阻抗谱,研究了ZD-1与KCl复配对A3钢的协同缓蚀作用。结果表明:ZD-1与KCl复配是以阴极控制为主的混合型缓蚀剂,1g/ L的ZD-1和1 mmol/ L的KCl复配对A3钢的缓蚀效果显著,缓蚀率可达93.84%。 |
英文摘要: |
A new acidizing corrosion inhibitor ZD-1 was synthesized by Mannich reaction with aldehyde, acetone and diethylamine. Tests of the corrosion inhibition efficiency,potentiodynamic polarization curve and electrochemical impedance spectroscopy(EIS)were taken in the 5%(mass fraction)H2SO4solution which ZD-1(1 g/ L)and KCl by different concentration were added in order to studying the synergistic corrosion inhibition of ZD-1 and KCl in H2SO4solution on A3 steel. The results show that ZD-1 and KCl are cathodic-controlled mixed inhibitor. The formulation of ZD-1(1 g/L)and KCl(1 mmol/ L)have outstanding corrosion inhibition effect on A3 steel, and the corrosion inhibition efficiency can reach to 93.84%. |
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