徐超,陈范才,吴道明,王子天,李文珍,李林.镍铁钨合金的电沉积行为研究[J].表面技术,2010,39(5):26-29,71.
XU Chao,CHEN Fan-cai,WU Dao-ming,WANG Zi-tian,LI Wen-zhen,LI Lin.A Study on the Electrodeposition Behaviors of Nickel-iron-tungsten Alloy[J].Surface Technology,2010,39(5):26-29,71 |
| 镍铁钨合金的电沉积行为研究 |
| A Study on the Electrodeposition Behaviors of Nickel-iron-tungsten Alloy |
| 投稿时间：2010-07-19 修订日期：2010-10-10 |
| DOI： |
| 中文关键词: 镍铁钨合金 电沉积 成核机理 |
| 英文关键词:nickel-iron-tungsten electrodeposition electrocrystallization mechanism |
| 基金项目: |
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| Author | Institution |
| XU Chao | School of Chemistry and Chemical Engineering of Hunan University,Changsha 410082,China |
| CHEN Fan-cai | School of Chemistry and Chemical Engineering of Hunan University,Changsha 410082,China |
| WU Dao-ming | School of Chemistry and Chemical Engineering of Hunan University,Changsha 410082,China |
| WANG Zi-tian | School of Chemistry and Chemical Engineering of Hunan University,Changsha 410082,China |
| LI Wen-zhen | School of Chemistry and Chemical Engineering of Hunan University,Changsha 410082,China |
| LI Lin | School of Chemistry and Chemical Engineering of Hunan University,Changsha 410082,China |
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| 中文摘要: |
| 应用电化学方法研究了Ni-Fe-W合金的电沉积机理,并对Ni-Fe-W合金镀层的微观形貌和组成成分进行了表征。循环伏安测试表明,Ni-Fe-W合金电沉积是不可逆电极过程,且WO42-浓度的变化不改变电沉积机理;计时电流法研究表明,Ni-Fe-W合金在铜电极上的电结晶过程符合三维瞬时成核的生长机理;SEM和EDS结果表明,Ni-Fe-W合金镀层由纳米级的小颗粒组成,合金的组成为Ni 58.76%,Fe 32.72%,W 8.52%(原子数分数,后同)。 |
| 英文摘要: |
| The electrodeposition mechanism of nickel-iron-tungsten alloy were studied by the methods of electrochemistry, and the micromorphology and composition of nickel-iron-tungsten alloy were characterized.Cyclic voltammogram indicated that the electrodeposition of nickel-iron-tungsten alloy wasirreversible growth process,and the electrocrystal-lization mechanism didn't change with the variety of the concentration of WO42-.Chronoamperometric results indicated that the electrodeposition of nickel-iron-tungsten alloy at copperelectrode belonged to a three-dimensionalinstantaneous nucleationmech-anism. SEM images of electrodeposit showed that the nickel-iron-tungsten alloy was made of lots of crystalline grain which was several tens nanometers, and the atom composition was 58.76%Ni,32.72%Fe,8.52%W. |
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