XU Bin,QIAN Jian-cai,XIANG Yun-liang,ZOU Hong-qing,WU Hou-chang,LYU Ji-cheng,FANG Min.Study on Wear Resistance and Corrosion Resistance of Electroless Ni-P Plating with PTFE Composite Coating on Steel Substrate[J],50(9):261-268
Study on Wear Resistance and Corrosion Resistance of Electroless Ni-P Plating with PTFE Composite Coating on Steel Substrate
Received:September 30, 2020  Revised:December 16, 2021
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DOI:10.16490/j.cnki.issn.1001-3660.2021.09.027
KeyWord:Ni-P alloy  electrochemical etching  PTFE  composite modification, wear resistance  corrosion resistance
                    
AuthorInstitution
XU Bin Southwest Institute of Technology and Engineering, Chongqing , China;CSGC Key Laboratory of Ammunition Storage Environmental Effects, Chongqing , China
QIAN Jian-cai Southwest Institute of Technology and Engineering, Chongqing , China;CSGC Key Laboratory of Ammunition Storage Environmental Effects, Chongqing , China
XIANG Yun-liang Southwest Institute of Technology and Engineering, Chongqing , China
ZOU Hong-qing Southwest Institute of Technology and Engineering, Chongqing , China;CSGC Key Laboratory of Ammunition Storage Environmental Effects, Chongqing , China
WU Hou-chang Southwest Institute of Technology and Engineering, Chongqing , China
LYU Ji-cheng Southwest Institute of Technology and Engineering, Chongqing , China
FANG Min Southwest Institute of Technology and Engineering, Chongqing , China
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Abstract:
      The purpose is to study the wear resistance and corrosion resistance mechanism of Ni-P electroless plating with PTFE composite coating on steel substrate. Electroless Ni-P alloy coating is prepared on the surface of steel materials. The nanoporous layer is prepared on the surface of the Ni-P alloy coating by electrochemical etching technology, and the composite coating with wear and corrosion resistance is prepared after the composite modification of PTFE. The microstructure of the composite coating is characterized with SEM. The wear resistance and corrosion resistance of the composite coating are evaluated by ball-disc wear test and electrochemical test. The wear scar morphology of the composite coating is analyzed by white light interferometer. The hardness of the composite coating does not change. In the ball-disc friction test, the friction coefficient of Ni-P electroless plating increases from 0.12 to 0.4. The friction coefficient of the composite coating increases from 0.08 to 0.2 and remained stable, which effectively reduces the friction coefficient of the coating and improves the wear resistance of the coating. According to the polarization curve,the corrosion current of the composite coating is the lowest,which is 1.88 μA, and there is a passivation range. The fitting results of equivalent circuit in electrochemical impedance spectroscopy show that the impedance modulus of the Ni-P alloy and the composite coating at 0.01 Hz is 1.44×104 Ω.cm2 and 2.75× 104 Ω.cm2. The electrochemical etching+PTFE composite modification can effectively improve the wear and corrosion resistance of Ni-P electroless plating.
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