牛赢,王壮飞,孙海猛,楚帅震,焦锋.表面纳米化对材料性能影响的研究进展与展望[J].表面技术,2023,52(4):15-30.
NIU Ying,WANG Zhuang-fei,SUN Hai-meng,CHU Shuai-zhen,JIAO Feng.Research Progress and Prospect of the Effect of Surface Nanocrystallization on Material Properties[J].Surface Technology,2023,52(4):15-30
表面纳米化对材料性能影响的研究进展与展望
Research Progress and Prospect of the Effect of Surface Nanocrystallization on Material Properties
  
DOI:10.16490/j.cnki.issn.1001-3660.2023.04.002
中文关键词:  表面纳米化  纳米晶结构表面层  材料性能  超声振动辅助加工
英文关键词:surface nanocrystallization  nanocrystalline surface layer  material properties  ultrasonic vibration assisted machining
基金项目:河南省自然科学基金(202300410172);国家自然科学基金(52175399);河南省高校基本科研业务费专项资金资助(NSFRF230409)
作者单位
牛赢 河南理工大学 机械与动力工程学院,河南 焦作 454003;西峡县内燃机进排气管有限责任公司,河南 南阳 474500 
王壮飞 河南理工大学 机械与动力工程学院,河南 焦作 454003 
孙海猛 河南理工大学 机械与动力工程学院,河南 焦作 454003 
楚帅震 河南理工大学 机械与动力工程学院,河南 焦作 454003 
焦锋 河南理工大学 机械与动力工程学院,河南 焦作 454003 
AuthorInstitution
NIU Ying School of Mechanical and Power Engineering, Henan Polytechnic University, Henan Jiaozuo 454003, China;Xixia Internal Combustion Engine Intake and Exhaust Pipe Co., Ltd., Henan Nanyang 474500, China 
WANG Zhuang-fei School of Mechanical and Power Engineering, Henan Polytechnic University, Henan Jiaozuo 454003, China 
SUN Hai-meng School of Mechanical and Power Engineering, Henan Polytechnic University, Henan Jiaozuo 454003, China 
CHU Shuai-zhen School of Mechanical and Power Engineering, Henan Polytechnic University, Henan Jiaozuo 454003, China 
JIAO Feng School of Mechanical and Power Engineering, Henan Polytechnic University, Henan Jiaozuo 454003, China 
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中文摘要:
      工程零部件失效常源于表面,微组织结构显著影响甚至决定工程零部件使役性能,表面纳米化技术可诱导材料微组织结构变化产生纳米晶结构表面层,增大表层残余压应力,对材料性能有极其重要的影响。首先综述了表面纳米化诱导微组织结构变化的过程及机理,诱导材料产生晶粒细化、位错运动、残余压应力增大、相变等微观变化,诱因有塑性变形、温度变化、元素渗入等。其次归纳了表面纳米化对材料性能的影响及其机理,上述微观变化对材料疲劳强度、耐腐蚀性、摩擦磨损性能、生物学性能等产生显著影响。总结了各个典型表面纳米化工艺的特点,相比于其他表面纳米化技术,超声振动辅助加工具有不需引入其他元素、不污染环境、原理简单、高速高质量、成本低廉、可依托于各种传统加工工艺等优势,对材料摩擦磨损性能、疲劳性能、生物学性能、表面浸润性和耐腐蚀性等具有积极作用。最后对表面纳米化工艺的未来发展做了展望,其中针对性分析了超声振动辅助加工。针对纳米晶结构表面层的数字化仿真模拟极其匮乏这一现状,将模拟仿真与试验相结合,分析微组织结构与加工参数、微组织结构与材料性能的映射关系并建立模型直观反映尚需更全面系统的研究。材料的某些性能可能不会同时达到最优值,依托于上述模型的综合评价体系有待建立,纳米晶结构表面层基于相变动力学的高温稳定性等仍需深入分析探索。超声振动辅助加工技术的关键制约因素有待完善,新材料的开发和技术手段的改进都是重要研究内容。超声振动辅助加工与其他表面纳米化方法组合使用是可探讨研究之处,优势互补或许可进一步诱导产生更优异的材料性能。
英文摘要:
      The failure of engineering parts was often caused by the surface, and the working performance of engineering parts was significantly affected or even determined by the microstructural structure. The microstructural structure of materials was induced by the surface nanocrystalline surface layer, and the residual compressive stress on the surface layer increased, and the material performance was greatly affected. According to their characteristics, surface nanocrystalline technologies could be divided into three categories:surface self-nanocrystalline (mechanical and thermodynamic methods), surface coating/deposition and hybrid nanocrystalline. Firstly, the process and mechanism of microstructural changes induced by surface nanocrystallization were reviewed. The materials were induced to produce microscopic changes such as grain refinement, dislocation movement, increase of residual compressive stress and phase transformation, which were induced by plastic deformation, temperature change and element infiltration. Secondly, the influence and mechanism of surface nanocrystallization on material properties were summarized, and the fatigue strength, corrosion resistance, friction and wear properties and biological properties of materials were significantly affected by the above microscopic changes. The application, advantages and limitations of cold rolling, laser shock peening, shot peening, high pressure torsion, supersonic fine particles bombarding, surface coating/deposition and equal channel angular extrusion were summarized. Compared to other surface nano technology, ultrasonic vibration assisted treatment had no need to introduce other elements, no pollution, simple principle, high speed and high quality, low cost, could be on various advantages of the traditional processing technology, it had a positive effect on the friction and wear properties, fatigue properties, biological properties, surface wettability and corrosion resistance of materials. Finally, the future development of surface nanocrystalline technology was prospected, and the ultrasonic vibration assisted processing was analyzed. Digital simulation of the surface layer of nanocrystalline structure was extremely scarce. It needed more comprehensive and systematic research to combine simulation and experiment, analyze the mapping relationship between microstructure and processing parameters, microstructure and material properties, and establish a model for direct reflection. Some properties of the materials might be difficult to reach the optimal value at the same time, an evaluation system based on the above model needed to be established in order to improve the comprehensive properties of materials. The mechanism of nanocrystalline surface layer improving material properties was limited by existing observation methods and processing technology, the mechanism of surface nanocrystalline surface layer induced by surface nanocrystalline surface layer and high temperature stability based on phase transformation dynamics still need to be further analyzed and explored. The key of ultrasonic vibration assisted machining technology included ultrasonic vibration unit, ultrasonic cutting tool, ultrasonic cutting machine tool, ultrasonic system, CNC machine tool integration technology, etc. These key restricting factors needed to be improved, the development of new materials and the improvement of technical means were important research contents. Surface nanocrystalline methods generally affected only relatively shallow layers of materials, the improvement of the overall properties of the material was restricted. The combination of ultrasonic vibration-assisted machining with other surface nanocrystallization methods was an area that could be explored, and complementary advantages might further induce better material properties.
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