邵蓉,刘永壮,董妮妮,李润昌,刘新华,刘洋,黎敏,李学涛,曹建平.DP980表面氧化物对胶接性能的影响[J].表面技术,2023,52(3):370-378.
SHAO Rong,LIU Yong-zhuang,DONG Ni-ni,LI Run-chang,LIU Xin-hua,LIU Yang,LI Min,LI Xue-tao,CAO Jian-ping.Effect of Surface Oxides on Bonding Properties of DP980[J].Surface Technology,2023,52(3):370-378 |
| DP980表面氧化物对胶接性能的影响 |
| Effect of Surface Oxides on Bonding Properties of DP980 |
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| DOI：10.16490/j.cnki.issn.1001-3660.2023.03.035 |
| 中文关键词: DP980 氧化物 表面处理 润湿性 界面结合力 胶接性能 |
| 英文关键词:DP980 oxides surface treatment wettability interfacial binding force bonding performance |
| 基金项目: |
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| Author | Institution |
| SHAO Rong | Research Institute of Technology of Shougang Group Co., Ltd., Beijing 100041, China |
| LIU Yong-zhuang | Research Institute of Technology of Shougang Group Co., Ltd., Beijing 100041, China |
| DONG Ni-ni | Shougang Jingtang United Iron and Steel Co., Ltd., Hebei Tangshan 063200, China |
| LI Run-chang | Shougang Jingtang United Iron and Steel Co., Ltd., Hebei Tangshan 063200, China |
| LIU Xin-hua | Shougang Jingtang United Iron and Steel Co., Ltd., Hebei Tangshan 063200, China |
| LIU Yang | Shougang Jingtang United Iron and Steel Co., Ltd., Hebei Tangshan 063200, China |
| LI Min | Research Institute of Technology of Shougang Group Co., Ltd., Beijing 100041, China |
| LI Xue-tao | Research Institute of Technology of Shougang Group Co., Ltd., Beijing 100041, China |
| CAO Jian-ping | Research Institute of Technology of Shougang Group Co., Ltd., Beijing 100041, China |
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| 中文摘要: |
| 目的 明确高强钢DP980表面氧化物的组成及含量对胶接性能的影响规律，从而改善双相高强钢的胶接性能。方法 通过采用1%(质量分数)的醋酸溶液对双相高强钢DP980表面进行不同时间的酸蚀处理，结合扫描电子显微镜(SEM)、透射电子显微镜(TEM)对高强钢表面氧化物的微观形貌进行观察，通过电子探针(EPMA)表征酸洗前后高强钢表面元素分布变化，采用辉光放电发射光谱仪(GDS)对不同酸洗时间处理的高强钢表面元素的含量随深度变化进行分析，同时通过对Si、Mn元素的高分辨X射线光电子能谱(XPS)分峰拟合，表征高强钢表面不同氧化物成分。通过接触角测试分析酸洗处理对高强钢表面润湿性的影响。最后对不同酸洗时间处理的高强钢进行了胶接试验，探究高强钢表面氧化物含量、形貌及种类对胶接性能的影响规律。结果 DP980表面存在Si、Mn、O元素的富集，其中氧化物以SiOx、Mn2SiO4、MnSiO3、MnO等形式存在。随着酸洗时间的延长，DP980表面氧化物尤其是SiOx含量显著降低，颗粒尺寸明显减小，同时表面纳米尺度的结构起伏增加，表面接触角减小。经过酸洗处理的高强钢胶接性能得到了明显提升，酸洗400 s后，样品的内聚破坏比例由初始85%提升至100%，平均剪切强度由0.54 MPa提升至0.66 MPa，最大剪切力由168.1 N提升至206.4 N。结论 DP980表面氧化物的减少，可以有效提高高强钢表面的润湿性，增强胶黏剂与DP980基体的界面结合力，进而提升材料胶接性能。因此可以通过合金成分设计、退火工艺控制等方法改变表面氧化物类型以及含量，从而提升汽车板的胶接性能。 |
| 英文摘要: |
| The purpose of this study was to investigate the effect of composition and content of surface oxides of high strength steel DP980 on bonding properties, so as to improve the bonding properties of dual-phase high strength steel. In this paper, 1wt.% acetic acid solution was used to etch the surface of high strength dual phase steels DP980 at different times. Scanning electron microscope (SEM) and transmission electron microscope (TEM) were used to observe the microstructures of oxides on the surface of high strength steel. Electro-Probe Microanalyzer (EPMA) were used to identify the elements distribution of DP980 before and after acid pickling. Glow discharge spectroscopy (GDS) were used to explore the variation of surface elements content with depth of DP980 treated with different pickling times. The XPS sputtering results further confirmed this conclusion. According to the peak fitting results of the high resolution X-ray photoelectron spectroscopy (XPS) spectra for Si and Mn elements, different kinds of surface oxides for high strength steel DP980 were characterized. In addition, the influence of pickling treatment on surface wettability of high strength steel was also analyzed by contact angle test. Finally, the bonding experiments of high strength steel treated with different pickling time were carried out to explore the influence of the content, morphologies and types of surface oxides on bonding properties of high strength steel surface. |
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