胡峰帆,范秀娟,彭峰,邓春明,刘敏,曾德长,宁成云.医用材料聚醚醚酮等离子喷涂表面改性研究进展[J].表面技术,2022,51(7):53-62.
HU Feng-fan,FAN Xiu-juan,PENG Feng,DENG Chun-ming,LIU Min,ZENG De-chang,NING Cheng-yun.Research Advance in Medical Material Polyether-ether-ketone of Surface Modification by Plasma Spraying[J].Surface Technology,2022,51(7):53-62
医用材料聚醚醚酮等离子喷涂表面改性研究进展
Research Advance in Medical Material Polyether-ether-ketone of Surface Modification by Plasma Spraying
  
DOI:10.16490/j.cnki.issn.1001-3660.2022.07.005
中文关键词:  聚醚醚酮  等离子喷涂  机械性能  生物性能  
英文关键词:PEEK  plasma spraying  mechanical property, biological property
基金项目:广东省特支本土团队计划项目(2019BT02C629);广东省现代表面工程技术重点实验室项目(2020B1212060049);广东省科学院建设国内一流研究机构行动专项资金项目(2021GDASYL–20210103062);顺德区2020年核心技术攻关项目(2030218000189)
作者单位
胡峰帆 华南理工大学 材料科学与工程学院,广州510640;广东省科学院新材料研究所 现代材料表面工程技术国家工程实验室 广东省现代表面工程技术重点实验室,广州510651 
范秀娟 广东省科学院新材料研究所 现代材料表面工程技术国家工程实验室 广东省现代表面工程技术重点实验室,广州510651 
彭峰 广东省人民医院,广州 510080 
邓春明 广东省科学院新材料研究所 现代材料表面工程技术国家工程实验室 广东省现代表面工程技术重点实验室,广州510651 
刘敏 广东省科学院新材料研究所 现代材料表面工程技术国家工程实验室 广东省现代表面工程技术重点实验室,广州510651 
曾德长 华南理工大学 材料科学与工程学院,广州510640 
宁成云 华南理工大学 材料科学与工程学院,广州510640 
AuthorInstitution
HU Feng-fan School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, China;Guangdong Academy of Sciences, Guangdong Institute of New Materials, National Engineering Laboratory for Modern Materials Surface Engineering Technology, the Key Lab of Guangdong for Modern Surface Engineering Technology, Guangzhou 510651, China 
FAN Xiu-juan Guangdong Academy of Sciences, Guangdong Institute of New Materials, National Engineering Laboratory for Modern Materials Surface Engineering Technology, the Key Lab of Guangdong for Modern Surface Engineering Technology, Guangzhou 510651, China 
PENG Feng Guangdong General Hospital, Guangzhou 510080, China 
DENG Chun-ming Guangdong Academy of Sciences, Guangdong Institute of New Materials, National Engineering Laboratory for Modern Materials Surface Engineering Technology, the Key Lab of Guangdong for Modern Surface Engineering Technology, Guangzhou 510651, China 
LIU Min Guangdong Academy of Sciences, Guangdong Institute of New Materials, National Engineering Laboratory for Modern Materials Surface Engineering Technology, the Key Lab of Guangdong for Modern Surface Engineering Technology, Guangzhou 510651, China 
ZENG De-chang School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, China 
NING Cheng-yun School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, China 
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中文摘要:
      聚醚醚酮材料(PEEK)具有良好的生物相容性、化学稳定性、X射线可穿透性及优异的力学性能,广泛用于创伤、脊柱和关节等生物医疗领域。然而,PEEK属于生物惰性材料,其骨整合性不足,这在一定程度上限制了该材料在骨修复与替换等领域的发展和应用。等离子喷涂技术由于工艺简单、经济,喷涂涂层的黏结强度高等特点,是解决聚醚醚酮材料骨整合能力不足的重要表面涂层改性技术。首先,简述了等离子喷涂工艺的涂层沉积机理,并分别对等离子喷涂钛以及羟基磷灰石两种常用涂层进行了介绍;其次,从不同喷涂工艺以及喷涂参数对涂层的影响出发,详细介绍了近几年对PEEK基等离子喷涂涂层的结合强度等机械性能的最新研究进展,并对等离子喷涂过程对PEEK基体的机械强度、疲劳强度、热性能和化学降解等初始性能影响进行了总结与评价,详细介绍了PEEK基等离子喷涂涂层体内外生物性能的最新研究进展;最后,展望了等离子喷涂改性PEEK基材料的临床应用前景,以期为未来设计新型PEEK基生物材料提供理论指导。
英文摘要:
      Polyether ether ketone (PEEK) has the advantages of high mechanical strength, excellent chemical stability, and transparency to diagnostic X-rays, and its density and elasticity is closer to bones compared to metals. PEEK is widely used in biomedical fields such as trauma, spine, and joints. However, PEEK is a bioinert material with insufficient osteointegration, which limits the development and application in bone repair and replacement to a certain extent. Plasma spraying (PS) technology is an important surface coating modification technology to solve the problem of bone integration of PEEK materials due to its simple process, economy, and high adhesive strength of the coatings. Firstly, this paper briefly describes the coating deposition mechanism of PS process, then titanium (Ti) and hydroxyapatite (HA) coatings manufactured by PS are introduced respectively; Secondly, based on the different spraying processes and spraying parameters, the latest research progress of plasma sprayed PEEK-based coatings on mechanical properties such as bonding strength in recent years is introduced in detail. The effects of PS process on the initial properties of PEEK substrate, such as mechanical strength, fatigue strength, thermal properties and chemical degradation are summarized and evaluated; The latest research progress of plasma sprayed PEEK-based coatings on biological properties in vitro and in vivo is also introduced in detail; Finally, the clinical application of plasma sprayed PEEK is prospected to provide theoretical guidance for the design of new PEEK-based biomaterials in the future.
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