周富威,佘家璇,罗伍庆,赵云鹏,夏恩杰,方文强,邓姝皓.高氯酸掺杂聚苯胺复合阴极的制备及性能研究[J].表面技术,2022,51(4):348-355, 384.
ZHOU Fu-wei,SHE Jia-xuan,LUO Wu-qing,ZHAO Yun-peng,XIA En-jie,FANG Wen-qiang,DENG Shu-hao.Preparation and Properties of Perchloric Acid Doped Polyaniline Composite Cathode[J].Surface Technology,2022,51(4):348-355, 384 |
| 高氯酸掺杂聚苯胺复合阴极的制备及性能研究 |
| Preparation and Properties of Perchloric Acid Doped Polyaniline Composite Cathode |
| 投稿时间：2021-04-11 修订日期：2022-02-12 |
| DOI：10.16490/j.cnki.issn.1001-3660.2022.04.037 |
| 中文关键词: 氧化石墨烯 导电聚苯胺 复合阴极 海水电池 电化学性能 |
| 英文关键词:graphene oxide conductive polyaniline composite cathode sea water battery electrochemical property |
| 基金项目: |
|
|
| Author | Institution |
| ZHOU Fu-wei | School of Materials Science and Engineering Changsha 410083, China |
| SHE Jia-xuan | School of Materials Science and Engineering Changsha 410083, China |
| LUO Wu-qing | School of Materials Science and Engineering Changsha 410083, China |
| ZHAO Yun-peng | School of Materials Science and Engineering Changsha 410083, China |
| XIA En-jie | School of Materials Science and Engineering Changsha 410083, China |
| FANG Wen-qiang | School of Materials Science and Engineering Changsha 410083, China |
| DENG Shu-hao | School of Materials Science and Engineering Changsha 410083, China;Key Laboratory of Nonferrous Metal Materials Science and Engineering Ministry of Education, Central South University, Changsha 410083, China |
|
| 摘要点击次数: |
| 全文下载次数: |
| 中文摘要: |
| 目的 为提高聚苯胺海水电池正极的导电性和放电性能，研究各种制备工艺条件对电极性能的影响。方法 采用电化学的方法，以石墨纸为载体，在高氯酸体系中制备聚苯胺(PANI)/二氧化锰(MnO2)/氧化石墨烯(GO)复合电极，研究复合电极制备的最优条件。采用X射线衍射仪、红外光谱仪和扫描电镜表征复合电极，采用交流阻抗法、循环伏安法和极化曲线研究电极的电化学性能。结果 石墨纸在室温下经30 mA/cm2的电流密度氧化60 min后，在磺基水杨酸(SSA)质量浓度为15 g/L，硫酸锰浓度为0.2 mol/L的苯胺-高氯酸溶液里以电流密度18 mA/cm2聚合20 min，可制备出较优的PMGO复合电极，它与镁合金组成海水电池，以200 mA/g恒流放电至1 V，其比能量可达600 W.h/kg。PMGO复合电极的表面微观形貌是由纳米线组成的三维立体网状结构，聚苯胺与二氧化锰成功复合到氧化石墨烯表面。结论 高氯酸体系掺杂的聚苯胺导电性增强，氧化使石墨纸表面形成大量的氧化石墨烯，为苯胺聚合、复合提供大量活性点，复合后电极比表面积增大，与电解液充分接触，使电极活性物质利用率提高，并降低了电极的极化，电化学性能也远优于AgCl电极。 |
| 英文摘要: |
| The work aims to study the effect of various preparation technologies on properties of electrode so as to improve the conductivity and discharge property of positive electrode of polyaniline seawater battery. The polyaniline (PANI)/manganese dioxide (MnO2)/graphene oxide (GO) composite electrode was synthesized by electrochemical method on graphite paper and the optimum synthesis condition of the composite electrode was studied. The XRD, SEM and FT-IR were used to characterize the composite electrode. The electrochemical property of the composite electrode was measured by the AC impedance method, cyclic voltammetry and polarization curve. After the graphite paper was oxidized at room temperature for 60 minutes under the oxidation current density of 30 mA/cm2, the optimal PMGO composite electrode was synthesized at the polymerization current density of 18 mA/cm2 in HClO4-aniline solution containing sulfosalicylic acid (SSA) of 15 g/Land 0.2 mol/L MnSO4 for 20 minutes of polymerization. The seawater battery composed of composite electrode and magnesium alloy discharged to 1 V at a constant current of 200 mA/g, and the specific energy reached 600 W·h/kg. The surface microstructure of the PMGO composite electrode showed a complex 3D network structure constructed by nanowires on graphite paper. Polyaniline and manganese dioxide were successfully compounded on the surface of graphene oxide. The conductivity of polyaniline doped with perchloric acid has been enhanced. A large amount of GO is formed on the surface of graphite paper by oxidation, providing numerous active sites for the polymerization of PANI. Thus, specific surface area of electrode prepared increases and fully contacts electrolyte, which improves the utilization of active material and reduces the composite electrode polarization. The electrochemical property of PMGO is much better than that of AgCl electrode. |
| 查看全文 查看/发表评论 下载PDF阅读器 |
| 关闭 |
|
|
|
渝公网安备 50010702501715号