苟海龙,贾均红,陈体军,杨杰,何乃如,陈威.等离子喷涂NiAl-V2O5/CuO复合涂层的宽温域摩擦学行为[J].表面技术,2022,51(4):112-120.
GOU Hai-long,JIA Jun-hong,CHEN Ti-jun,YANG Jie,HE Nai-ru,CHEN Wei.Tribological Behaviors of Plasma Sprayed NiAl-V2O5/CuO Composite Coatings at Wide Temperature Range[J].Surface Technology,2022,51(4):112-120 |
| 等离子喷涂NiAl-V2O5/CuO复合涂层的宽温域摩擦学行为 |
| Tribological Behaviors of Plasma Sprayed NiAl-V2O5/CuO Composite Coatings at Wide Temperature Range |
| 投稿时间：2021-02-05 修订日期：2021-08-19 |
| DOI：10.16490/j.cnki.issn.1001-3660.2022.04.010 |
| 中文关键词: 大气等离子喷涂 氧化物 宽温域 摩擦 润滑 磨损机理 |
| 英文关键词:atmospheric plasma spraying oxide wide temperature range friction lubrication wear mechanism |
| 基金项目:国家自然科学基金(51575505，51675508);陕西省重点研发计划项目(2019GY-173) |
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| Author | Institution |
| GOU Hai-long | Co-constructing State Key Laboratory by Province of Advanced Processing and Recycling of Nonferrous Metal, Lanzhou University of Technology, Lanzhou 730050, China;College of Mechanical & Electrical Engineering, Shaanxi University of Science & Technology, Xi’an 710021, China |
| JIA Jun-hong | College of Mechanical & Electrical Engineering, Shaanxi University of Science & Technology, Xi’an 710021, China;State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China |
| CHEN Ti-jun | Co-constructing State Key Laboratory by Province of Advanced Processing and Recycling of Nonferrous Metal, Lanzhou University of Technology, Lanzhou 730050, China |
| YANG Jie | College of Mechanical & Electrical Engineering, Shaanxi University of Science & Technology, Xi’an 710021, China |
| HE Nai-ru | College of Mechanical & Electrical Engineering, Shaanxi University of Science & Technology, Xi’an 710021, China |
| CHEN Wei | College of Mechanical & Electrical Engineering, Shaanxi University of Science & Technology, Xi’an 710021, China |
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| 中文摘要: |
| 目的 以具有较好低温润滑性能的V2O5和CuO为复合润滑相，设计并制备在宽温域下具有良好摩擦学性能的NiAl基高温润滑耐磨涂层。方法 采用大气等离子喷涂技术(APS)制备了不同配比的NiAl-V2O5/ CuO复合涂层，并探究其在宽温域内(RT~800 ℃)的摩擦学性能。利用SEM(扫描电子显微镜)、XRD(X射线衍射仪)和Raman(激光拉曼散射仪)等，分析了涂层在宽温域下的摩擦表面结构和物相变化及磨损机理。结果 复合涂层为典型的等离子喷涂层状结构，氧化物分布较为均匀，随氧化物含量的增加，涂层孔隙率上升。复合涂层在宽温域内有良好的润滑性能，室温和高温(800 ℃)下NiAl-10% V2O5/CuO涂层的摩擦因数分别低至0.39和0.21。磨损率随复合氧化物含量的增加而增大，但在室温和高温段均较低，其中10% V2O5/CuO添加的复合涂层在室温和高温下的磨损率分别为4.3×10‒5 mm3/(N∙m)和5.1×10‒5 mm3/(N∙m)。高温摩擦促使三元氧化物Ni3V2O8、Cu3V2O8和CuV2O6的生成，这些新生相与CuO、V2O5、NiO等在磨损表面形成润滑层。结论 V2O5/CuO的复配明显改善了涂层在室温和高温段的摩擦学性能，但随着氧化物含量的增加，涂层力学性能下降，磨损率随之增大。高温下涂层润滑性能的明显提升归因于磨损表面形成的三元氧化物高温润滑膜。 |
| 英文摘要: |
| This work aims to design and prepare NiAl based high temperature lubricating and wear-resistant coatings with good tribological properties in a wide temperature range using V2O5 and CuO as composite lubricating phases. The composite coatings with different mass ratios are fabricated by atmospheric plasma spraying technology (APS), and investigated tribological properties in a wide temperature range (RT~800 ℃); used SEM (scanning electron microscope), XRD (X-ray diffraction) and Raman (laser Raman scattering) to analyze the friction surface structure, phase change and wear mechanism of the coating in a wide temperature range. The composite coating is a typical plasma sprayed layered structure, and the oxide distribution is relatively uniform. With the increase of oxide content, the porosity of the coating increases; The composite coating has good lubrication performance in a wide temperature range. The friction coefficients of NiAl-10wt.% V2O5/CuO coating at room temperature and high temperature (800 ℃) are as low as 0.39 and 0.21 respectively. The wear rate increases with the increase of composite oxide content, but it is low at room temperature and high temperature. The wear rate of composite coating added with 10wt.% V2O5/CuO is 4.3×10‒5 mm3/(N∙m) and 5.1×10‒5 mm3/(N∙m) at room temperature and high temperature respectively. High temperature friction promotes the formation of ternary oxides Ni3V2O8, Cu3V2O8 and CuV2O6. These new phases form a lubricating layer on the wear surface with Cuo, V2O5 and NiO. The combination of V2O5/CuO significantly improved the tribological properties of the coating at room temperature and high temperature, but with the increase of oxide content, the mechanical properties of the coating decreased and the wear rate increased. The obvious improvement of the lubricating performance of the coating at high temperature is attributed to the ternary oxide high temperature lubricating film formed on the wear surface. |
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