唐秋逸,纪秀林,段峻,王辉,张映桃.内生氧化铝颗粒增强高熵复合涂层的制备及其减摩性能的研究[J].表面技术,2021,50(11):218-225, 242.
TANG Qiu-yi,JI Xiu-lin,DUAN Jun,WANG Hui,ZHANG Ying-tao.Research on Preparation of High-entropy Composite Coating Reinforced by Endogenous Alumina Particles and Its Anti-friction Performance[J].Surface Technology,2021,50(11):218-225, 242
内生氧化铝颗粒增强高熵复合涂层的制备及其减摩性能的研究
Research on Preparation of High-entropy Composite Coating Reinforced by Endogenous Alumina Particles and Its Anti-friction Performance
投稿时间:2021-01-26  修订日期:2021-03-17
DOI:10.16490/j.cnki.issn.1001-3660.2021.11.022
中文关键词:  高熵复合涂层  Al2O3  耐磨性  摩擦磨损
英文关键词:high-entropy composite coating  Al2O3  wear resistance  friction
基金项目:国家自然科学基金(51875169,51475140)
作者单位
唐秋逸 河海大学 机电工程学院,江苏 常州 213022 
纪秀林 河海大学 机电工程学院,江苏 常州 213022 
段峻 河海大学 机电工程学院,江苏 常州 213022 
王辉 河海大学 机电工程学院,江苏 常州 213022 
张映桃 河海大学 机电工程学院,江苏 常州 213022 
AuthorInstitution
TANG Qiu-yi College of Mechanical & Electrical Engineering, Hohai University, Changzhou 213022, China 
JI Xiu-lin College of Mechanical & Electrical Engineering, Hohai University, Changzhou 213022, China 
DUAN Jun College of Mechanical & Electrical Engineering, Hohai University, Changzhou 213022, China 
WANG Hui College of Mechanical & Electrical Engineering, Hohai University, Changzhou 213022, China 
ZHANG Ying-tao College of Mechanical & Electrical Engineering, Hohai University, Changzhou 213022, China 
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中文摘要:
      目的 研究铝含量对内生氧化铝颗粒增强高熵复合涂层的组织结构及其摩擦学性能的影响。方法 在激光熔覆过程中,利用铝热反应将金属氧化物还原,并沉积在Q235钢表面,制备内生Al2O3陶瓷颗粒增强的AlxCoCrFeNi(x=0, 0.3, 1, 1.5, 2)高熵复合涂层。通过XRD、SEM、EDS、XPS、RAMAN及摩擦磨损测试仪等检测方法,研究高熵复合涂层的组织结构及其摩擦学性能。结果 涂层中含有大量弥散分布的纳米级Al2O3陶瓷颗粒。随着Al含量的增加,高熵复合涂层逐渐由FCC与BCC共存的形式转变为单相BCC的显微组织。同时,载荷为10 N时,高熵复合涂层的摩擦系数和磨损率均随着Al含量的上升而下降。Al2CoCrFeNi具有最低的平均滑动摩擦系数(0.15)和最低的磨损率(1.01×10–6 mm3/(N.m)),分别为Q235钢基体的1/4和1/38。当AlxCoCrFeNi系涂层中,当x增加至2时,磨痕表面的逐层剥落现象消失。涂层的主要磨损形式由氧化磨损和疲劳磨损转变为轻微的磨粒磨损。载荷为20 N时,Al2CoCrFeNi涂层的平均摩擦系数上升至0.325。结论 增加复合涂层中Al元素的含量可以稳定BCC相,并细化组织。同时,过量Al元素有抑制Fe元素氧化、降低摩擦表面Fe2O3含量、提高Fe3O4含量的作用,从而显著降低复合涂层的摩擦系数,并提高其减摩和耐磨性能。
英文摘要:
      This paper is to study the effect of Al content on the microstructure and tribology performance of high-entropy composite coating reinforced by endogenous alumina particles. In the process of laser cladding, metal oxides were reduced and deposited on the surface of Q235 steel by thermite reaction to prepare AlxCoCrFeNi (x=0, 0.3, 1, 1.5, 2) high-entropy composite coating reinforced by endogenous Al2O3 ceramic particles. XRD, SEM, EDS, XPS, RAMAN, friction test and other experimental methods were used to study the microstructure and tribology performance of the high-entropy composite coatings. The results show that there are dispersed nano-sized Al2O3 ceramic particles in the coating. With the increase of Al content, the microstructure of the high-entropy composite coating gradually changes from FCC and BCC coexistence to BCC single phase. At the same time, the friction coefficient and wear rate of the high-entropy composite coating under 10 N load decreased with the increase of Al content. Al2CoCrFeNi has the lowest friction coefficient (0.15) and the lowest wear rate (1.01×10–6 mm3/(N.m)), which are 1/4 and 1/38 of the base Q235 steel respectively. When x in AlxCoCrFeNi coating increases to 2, the peeling phenomenon of the wear scar surface disappears. The main wear form of the coating changes from oxidative wear and fatigue wear to slight abrasive wear. The average friction coefficient of Al2CoCrFeNi coating increased to 0.325 under a load of 20 N. Increasing the Al element in the composite coating can stabilize the BCC phase and refine the structure. At the same time, excessive Al element can inhibit Fe element oxidation and increase the content of Fe3O4 on the surface of the wear scar, thereby significantly reducing the friction coefficient of the composite coating and improving its friction reduction and wear resistance.
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