吕显成,孙航,曹磊,秦浩峰,万勇,高建国.使用温度对特氟龙食品接触用不粘涂层摩擦学性能的影响[J].表面技术,2020,49(3):155-161.
LYU Xian-cheng,SUN Hang,CAO Lei,QIN Hao-feng,WAN Yong,GAO Jian-guo.Effects of Treatment Temperature on Tribological Performance of Teflon Food Contacting Non-sticking Coating[J].Surface Technology,2020,49(3):155-161
使用温度对特氟龙食品接触用不粘涂层摩擦学性能的影响
Effects of Treatment Temperature on Tribological Performance of Teflon Food Contacting Non-sticking Coating
投稿时间:2019-05-20  修订日期:2020-03-20
DOI:10.16490/j.cnki.issn.1001-3660.2020.03.020
中文关键词:  特氟龙  不粘涂层  热处理  润湿性  摩擦学性能  磨损机制
英文关键词:Teflon  non-sticking coatings  thermal treatment  wettability  tribological properties  wear mechanism
基金项目:国家自然科学基金(51975304);山东省重点研发计划资助项目(2017GSF220012);山东省自然科学基金资助项目(ZR2017PEE013)
作者单位
吕显成 1.青岛理工大学 机械与汽车工程学院,山东 青岛 266520 
孙航 2.青岛市第九人民医院,山东 青岛 266001 
曹磊 1.青岛理工大学 机械与汽车工程学院,山东 青岛 266520 
秦浩峰 1.青岛理工大学 机械与汽车工程学院,山东 青岛 266520 
万勇 1.青岛理工大学 机械与汽车工程学院,山东 青岛 266520 
高建国 3.山东出入境检验检疫局检验检疫技术中心,山东 青岛 266001 
AuthorInstitution
LYU Xian-cheng 1.School of Mechanical and Automotive Engineering, Qingdao University of Technology, Qingdao 266520, China 
SUN Hang 2.The Ninth People’s Hospital of Qingdao, Qingdao 266001, China 
CAO Lei 1.School of Mechanical and Automotive Engineering, Qingdao University of Technology, Qingdao 266520, China 
QIN Hao-feng 1.School of Mechanical and Automotive Engineering, Qingdao University of Technology, Qingdao 266520, China 
WAN Yong 1.School of Mechanical and Automotive Engineering, Qingdao University of Technology, Qingdao 266520, China 
GAO Jian-guo 3.Inspection and Quarantine Center, Shandong Exit & Entry Inspection and Quarantine Bureau, Qingdao 266001, China 
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中文摘要:
      目的 模拟日常使用情况,考察使用温度对食品接触用特氟龙不粘涂层表面特性及摩擦学性能的影响。方法 利用马弗炉,在大气环境下,对特氟龙不粘涂层在不同温度下加热处理30 min。采用扫描电子显微镜、Raman光谱仪、接触角测量仪、摩擦磨损试验机等对热处理前后涂层的结构及摩擦学性能进行测试。结果 当热处理温度低于500 ℃时,不粘涂层的表面润湿性、硬度及摩擦学性能变化不大。当热处理温度达到550 ℃时,涂层的表面结构发生明显的变化,部分涂层从底材剥落,同时观察到涂层中含氟树脂已完全分解。此时涂层的表面对去离子水和橄榄油的接触角分别为10°和12°,表现为明显的亲水和亲油性能,硬度仅为未处理涂层的1/5。涂层在干摩擦条件下及去离子水介质中,摩擦系数和磨损体积均急剧增大。 结论 使用温度对食品接触用特氟龙不粘涂层的表面结构及摩擦学行为影响较大。
英文摘要:
      The work aims to simulate daily application to investigate the effects of temperature on the surface and tribological properties of food contacting Teflon non-sticking coating. Teflon non-sticking coatings were heated in a muffle furnace for 30 mins and their surface morphology and tribological properties before and after thermal treatment were investigated with scanning electron microscope, Raman spectrometer, contact angle measuring instrument, friction and wear tester. When the thermal treatment temperature was lower than 500 ℃, the surface wettability, hardness and tribological performance of the treated coatings remained unchanged. However, when the temperature was raised to 550 ℃, the structure of the coating changed significantly. Parts of coatings were peeled off from the substrate. Moreover, the fluorine-containing polymer was totally decomposed. In this case, the contact angle of the treated coating for deionized water and olive oil reduced to 10° and 12° respectively, showing apparent hydrophilicity and lipophilicity. The hardness of the treated coating was only 1/5 of the untreated sample. At the same time, the friction coefficient and wear volume increased sharply under dry friction and in presence of deionized water. Thus, the application temperature is found to have a great influence on the surface structure and tribological behavior of the Teflon coating.
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