张新宇,唐聿明,赵旭辉,左禹.硬脂酸添加剂对AZ91D镁合金阳极氧化膜耐蚀性的影响[J].表面技术,2020,49(2):220-226.
ZHANG Xin-yu,TANG Yu-ming,ZHAO Xu-hui,ZUO Yu.Effect of Stearic Acid Additive on Corrosion Resistance of Anodized Film on AZ91D Magnesium Alloy[J].Surface Technology,2020,49(2):220-226 |
| 硬脂酸添加剂对AZ91D镁合金阳极氧化膜耐蚀性的影响 |
| Effect of Stearic Acid Additive on Corrosion Resistance of Anodized Film on AZ91D Magnesium Alloy |
| 投稿时间：2019-03-21 修订日期：2020-02-20 |
| DOI：10.16490/j.cnki.issn.1001-3660.2020.02.027 |
| 中文关键词: 镁合金 阳极氧化 硬脂酸 耐蚀性 电化学 |
| 英文关键词:magnesium alloy anodizing stearic acid corrosion resistance electrochemistry |
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| Author | Institution |
| ZHANG Xin-yu | Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing 100029, China |
| TANG Yu-ming | Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing 100029, China |
| ZHAO Xu-hui | Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing 100029, China |
| ZUO Yu | Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing 100029, China |
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| 中文摘要: |
| 目的 通过含有硬脂酸添加剂的阳极氧化工艺，获得耐蚀性优异的镁合金阳极氧化膜。方法 采用直流电源阳极氧化法，在含有2 g/L硬脂酸的碱性氧化液中进行阳极氧化。通过SEM、ImageJ软件和TT230测厚仪分析氧化膜的微观形貌和膜厚，通过FTIR、XPS和XRD分析膜层成分，通过电化学测试检测膜层的耐蚀性能。结果 氧化液中添加硬脂酸后，制备的氧化膜层孔隙率降低，孔径减小，孔洞数量下降，厚度增大，致密度提高。膜层的自腐蚀电流密度为3.15×10–7 A/cm2，与未加硬脂酸制备的氧化膜相比，降低了2个数量级，耐蚀性显著提升。结论 硬脂酸添加剂通过提升成膜电压，增强火花放电效应、表面活性剂作用，改变膜层成分等机制，提升膜层耐蚀性能。 |
| 英文摘要: |
| The paper aims to obtain magnesium alloy anodized film of good corrosion resistance through the anodizing process of stearic acid additive. Anodization was carried out in alkaline oxidizing solution containing 2 g/L of stearic acid by the DC power anodization method. The microstructure and the thickness of the oxide film were analyzed with SEM, ImageJ software and TT230 thickness gauge; the film composition was analyzed by FTIR, XPS and XRD; the corrosion resistance of the film was detected by electrochemical test. The results showed that the porosity, pore size and number of pores of the oxide film prepared by this method were reduced, while the thickness and the density of the film layer were increased. The self- corrosion current density of the film layer was reduced to 3.15×10–7 A/cm2, which was decreased by two magnitudes compared with the oxide film without stearic acid additive. The corrosion resistance of the film layer was improved significantly. The stearic acid additives can improve the corrosion resistance of the film by increasing the film formation voltage, enhancing the spark discharge effect, surfactant action and changing the composition of the film. |
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