郭飞飞,胥光申,任明基,董光能.类金刚石膜对CoCrMo合金摩擦性能的影响[J].表面技术,2020,49(2):172-177.
GUO Fei-fei,XU Guang-shen,REN Ming-ji,DONG Guang-neng.Effect of Diamond-like Coating on Tribological Behaviour of CoCrMo Alloy[J].Surface Technology,2020,49(2):172-177
类金刚石膜对CoCrMo合金摩擦性能的影响
Effect of Diamond-like Coating on Tribological Behaviour of CoCrMo Alloy
投稿时间:2019-03-20  修订日期:2020-02-20
DOI:10.16490/j.cnki.issn.1001-3660.2020.02.021
中文关键词:  CoCrMo合金  类金刚石膜  结构  摩擦  磨损  转移层
英文关键词:CoCrMo alloy  DLC coating  structure  friction  wear  transfer layer
基金项目:陕西省自然科学基金(2018JQ5171);博士科研启动基金(BS1701)
作者单位
郭飞飞 1.西安工程大学 机电工程学院,西安 710048 
胥光申 1.西安工程大学 机电工程学院,西安 710048 
任明基 1.西安工程大学 机电工程学院,西安 710048 
董光能 2.西安交通大学 机械学院,西安 710049 
AuthorInstitution
GUO Fei-fei 1.College of Mechanical and Electrical Engineering, Xi′an Polytechnic University, Xi′an 710048, China 
XU Guang-shen 1.College of Mechanical and Electrical Engineering, Xi′an Polytechnic University, Xi′an 710048, China 
REN Ming-ji 1.College of Mechanical and Electrical Engineering, Xi′an Polytechnic University, Xi′an 710048, China 
DONG Guang-neng 2.College of Mechanical Engineering, Xi′an Jiaotong University, Xi′an 710049, China 
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中文摘要:
      目的 研究类金刚石膜(DLC)在不同工况条件下的摩擦性能。方法 使用磁控溅射技术,在CoCrMo合金表面沉积掺杂Cr元素的DLC薄膜。通过X射线衍射能谱和拉曼光谱对DLC膜表面的化学成分进行分析,采用扫描电镜(SEM)和原子力显微镜(AFM)观察DLC膜的表面形貌,借助摩擦试验仪测试DLC膜在不同工况条件下的摩擦性能。结果 薄膜表面呈现颗粒状结构,且薄膜表面粗糙度在10 nm左右,物相分析表明,DLC薄膜为非晶化结构。在牛血清白蛋白(BSA)和NaCl溶液润滑条件下,DLC/CoCrMo摩擦副的平均摩擦系数(COF)分别趋于0.08,磨损区域存在少量的刮痕;而在干摩擦条件下,摩擦系数曲线表现出由高到低的变化趋势,平均摩擦系数约为0.21,同时在销磨损表面能观察到石墨化转移层。当接触压力为1 MPa时,平均摩擦系数约为0.10;接触压力增加至8 MPa时,平均摩擦系数约为0.08。结论 润滑条件下,DLC膜表面悬键被钝化,减小其与配副表面之间的相互作用力,因此摩擦系数较低;干摩擦条件下,石墨化转移层充当固体润滑层,最终导致摩擦系数呈现下降趋势。DLC薄膜对摩擦配副具有明显的减摩效果。
英文摘要:
      The aim of the paper was to investigate the tribological behavior of DLC coating under different working conditions. The DLC coating doped with Cr element was deposited on the CoCrMo alloy by magnetron sputtering. The chemical composition of DLC coating was analyzed by X-ray diffraction energy spectrum and Raman spectrum. The surface morphology of DLC coating was observed by scanning electron microscope (SEM) and atomic force microscope (AFM). The tribological properties of DLC coating under different working conditions were studied with a tribo-tester. Results showed that the surface of DLC coating presented granular structure and the roughness value was about 10 nm. Phase analysis showed that the DLC coating had amorphous structure. The average friction coefficient of DLC/CoCrMo tribo-pair was about 0.08 with the lubrication of BSA and NaCl solution respectively, and there were a few scratches on the wear area. Under the condition of dry friction, the curve of the friction coefficient showed a change trend from high to low, and the average friction coefficient was about 0.21. Meanwhile, the graphitization transfer layer could be seen on the worn surface of the pin. When the contact pressure was 1 MPa, the average COF was about 0.10. When the contact pressure increased to 8 MPa, the average COF was about 0.08. Conclusion stated that the suspended bond on the surface of DLC coating is passivated under the condition of lubrication, which reduces the interaction force between DLC coating and the mating surface. The COF is thus low. Under dry friction, the graphitization transfer layer acts as a solid lubrication layer which leads to the decrease of COF. DLC coating has an obvious antifriction effect on the friction pair.
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