张帆,叶辰,崔乃元,郭沛,吴明亮,吕乐,林正得,詹肇麟.表面活性剂辅助的水相剥离法制备石墨烯研究进展[J].表面技术,2019,48(6):20-29.
ZHANG Fan,YE Chen,CUI Nai-yuan,GUO Pei,WU Ming-liang,LYU Le,LIN Cheng-te,ZHAN Zhao-lin.Recent Advances in Surfactant Assisted Water-phase Exfoliation for Graphene Preparation[J].Surface Technology,2019,48(6):20-29
表面活性剂辅助的水相剥离法制备石墨烯研究进展
Recent Advances in Surfactant Assisted Water-phase Exfoliation for Graphene Preparation
投稿时间:2018-10-31  修订日期:2019-06-20
DOI:10.16490/j.cnki.issn.1001-3660.2019.06.002
中文关键词:  表面活性剂  石墨烯  液相剥离    分散  环境友好
英文关键词:surfactant  graphene  liquid-phase exfoliation  water  dispersion  environmentally friendly
基金项目:中国科学院科研装备研制项目(YZ201640);浙江省公益项目(2016C31026);宁波市科技重大专项(2016B10038,2016S1002);宁波市国际合作项目(2017D10016);3315团队-先进碳材料与工业化应用基金
作者单位
张帆 1.昆明理工大学 材料科学与工程学院,昆明650093;2.中国科学院宁波材料技术与工程研究所 中国科学院海洋新材料与应用技术重点实验室 浙江省海洋材料与防护技术重点实验室表面事业部,浙江宁波315201 
叶辰 2.中国科学院宁波材料技术与工程研究所 中国科学院海洋新材料与应用技术重点实验室 浙江省海洋材料与防护技术重点实验室表面事业部,浙江宁波315201 
崔乃元 2.中国科学院宁波材料技术与工程研究所 中国科学院海洋新材料与应用技术重点实验室 浙江省海洋材料与防护技术重点实验室表面事业部,浙江宁波315201 
郭沛 2.中国科学院宁波材料技术与工程研究所 中国科学院海洋新材料与应用技术重点实验室 浙江省海洋材料与防护技术重点实验室表面事业部,浙江宁波315201 
吴明亮 2.中国科学院宁波材料技术与工程研究所 中国科学院海洋新材料与应用技术重点实验室 浙江省海洋材料与防护技术重点实验室表面事业部,浙江宁波315201 
吕乐 2.中国科学院宁波材料技术与工程研究所 中国科学院海洋新材料与应用技术重点实验室 浙江省海洋材料与防护技术重点实验室表面事业部,浙江宁波315201 
林正得 2.中国科学院宁波材料技术与工程研究所 中国科学院海洋新材料与应用技术重点实验室 浙江省海洋材料与防护技术重点实验室表面事业部,浙江宁波315201 
詹肇麟 1.昆明理工大学 材料科学与工程学院,昆明650093 
AuthorInstitution
ZHANG Fan 1.School of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China; 2.Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Division of Surface Engineering and Remanufacturing, Ningbo Institute of Materials Technology and Engineering of Chinese Academy of Sciences, Ningbo 315201,China 
YE Chen 2.Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Division of Surface Engineering and Remanufacturing, Ningbo Institute of Materials Technology and Engineering of Chinese Academy of Sciences, Ningbo 315201,China 
CUI Nai-yuan 2.Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Division of Surface Engineering and Remanufacturing, Ningbo Institute of Materials Technology and Engineering of Chinese Academy of Sciences, Ningbo 315201,China 
GUO Pei 2.Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Division of Surface Engineering and Remanufacturing, Ningbo Institute of Materials Technology and Engineering of Chinese Academy of Sciences, Ningbo 315201,China 
WU Ming-liang 2.Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Division of Surface Engineering and Remanufacturing, Ningbo Institute of Materials Technology and Engineering of Chinese Academy of Sciences, Ningbo 315201,China 
LYU Le 2.Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Division of Surface Engineering and Remanufacturing, Ningbo Institute of Materials Technology and Engineering of Chinese Academy of Sciences, Ningbo 315201,China 
LIN Cheng-te 2.Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Division of Surface Engineering and Remanufacturing, Ningbo Institute of Materials Technology and Engineering of Chinese Academy of Sciences, Ningbo 315201,China 
ZHAN Zhao-lin 1.School of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China 
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中文摘要:
      表面活性剂辅助水相剥离法是一种制备较高质量石墨烯的方法。概述了表面活性剂辅助的水相剥离方法的技术优势,包括方法绿色环保、便于规模化、所得石墨烯质量高和产量大等特点。在此基础上,重点综述了近年来不同种类表面活性剂辅助水相剥离石墨烯的研究进展,其中离子型表面活性剂辅助剥离石墨烯,包括烷基阴离子表面活性剂辅助剥离石墨、胆盐类表面活性剂辅助剥离石墨、芘衍生物辅助剥离石墨、阳离子型表面活性剂辅助剥离石墨等;非离子性表面活性剂辅助剥离石墨,包括聚乙烯吡咯烷酮辅助剥离石墨、聚醚表面活性剂辅助剥离石墨、聚乙烯基咪唑类高分子辅助水相剥离石墨等。针对各种形式的表面活性剂辅助水相剥离石墨方法,分别从制备流程、表面活性剂物理化学性能、制得的石墨烯的结构与性能等方面进行了归纳与对比。最后展望了液相剥离制备石墨烯方法在未来的发展方向。
英文摘要:
      Surfactant-assisted aqueous phase exfoliation is an effective method for preparing high-quality graphene. The advantages of surfactant-assisted aqueous phase exfoliation method were summarized, including environmentally-friendly, suitable for large-scale production and can easily obtained high quality and high yield of graphene. On this basis, the research progress of different surfactant-assisted aqueous phase exfoliation methods in recent years was reviewed. Among them, ionic sur-factant-assisted exfoliation of graphene, including alkyl anionic surfactant-assisted exfoliation of graphite, biliary surfactant-assisted exfoliation of graphite and pyrene derivative-assisted exfoliation of graphite were emphasized. Non-ionic surfactant assisted graphene stripping, including polyvinyl pyrrolidone assisted graphite stripping, polyether surfactant assisted graphite stripping and polyvinyl imid-azole polymer assisted graphite stripping. The preparation process, physicochemical properties of surfactants and the structure and properties of prepared graphene were summarized and compared for various surfactant-assisted aqueous phase stripping methods. Finally, we prospected the development trend of liquid phase exfoliation method for preparing graphene.
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