张亮,陈胜利,王秀通,宋积文,王润,王在峰.纳米 CdTe/TiO2复合材料对 304 不锈钢的光生阴极保护行为[J].表面技术,2016,45(7):80-84.
ZHANG Liang,CHEN Sheng-li,WANG Xiu-tong,SONG Ji-wen,WANG Run,WANG Zai-feng.Nano-CdTe/TiO2 Composite Material for Photogenerated Cathodic Protection of 304 Stainless Steel[J].Surface Technology,2016,45(7):80-84
纳米 CdTe/TiO2复合材料对 304 不锈钢的光生阴极保护行为
Nano-CdTe/TiO2 Composite Material for Photogenerated Cathodic Protection of 304 Stainless Steel
投稿时间:2016-01-22  修订日期:2016-07-20
DOI:10.16490/j.cnki.issn.1001-3660.2016.07.014
中文关键词:  光生阴极保护  纳米 CdTe/TiO2 复合材料  腐蚀  不锈钢  电化学
英文关键词:photogenerated cathodic protection  nano-CdTe/TiO2 composite material  corrosion  stainless steel  electrochemistry
基金项目:
作者单位
张亮 中海油信息科技有限公司北京分公司,北京 100027 
陈胜利 中海油信息科技有限公司北京分公司,北京 100027 
王秀通 中国科学院海洋研究所,山东 青岛 266071 
宋积文 中海油信息科技有限公司北京分公司,北京 100027 
王润 中海油信息科技有限公司北京分公司,北京 100027 
王在峰 中海油信息科技有限公司北京分公司,北京 100027 
AuthorInstitution
ZHANG Liang China National Offshore Oil Informtion Technology Beijing Branch, Beijing 100027, China 
CHEN Sheng-li China National Offshore Oil Informtion Technology Beijing Branch, Beijing 100027, China 
WANG Xiu-tong Institutes of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China 
SONG Ji-wen China National Offshore Oil Informtion Technology Beijing Branch, Beijing 100027, China 
WANG Run China National Offshore Oil Informtion Technology Beijing Branch, Beijing 100027, China 
WANG Zai-feng China National Offshore Oil Informtion Technology Beijing Branch, Beijing 100027, China 
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中文摘要:
      目的 研究纳米 CdTe/TiO2 复合材料对 304 不锈钢的光生阴极保护行为。 方法 采用阳极氧化法制备二氧化钛纳米管,通过循环伏安沉积法在纳米管上进行 CdTe 修饰。应用扫描电镜(SEM)、 X 射线衍射(XRD)等测试方法对比纯 TiO2 与 CdTe/TiO2的表面形貌与晶相特征。结合开路电位(OCP)、光电流密度-时间曲线(J-t)、 Tafel 极化曲线等电化学方法,研究复合材料的光电转化性能及其对 304不锈钢的阴极保护行为。 结果 在光照条件下,耦连 CdTe/TiO2复合材料的 304 不锈钢的开路电位从初始的?190 mV 负移至?730 mV,光电流密度可达 0.15 mA/cm2,闭光后,开路电位上升至?350 mV,仍然具有保护作用,说明制备的纳米 CdTe/TiO2 复合材料具有储存电子的能力。 结论 在可见光照射下,与纯二氧化钛相比,制备的 CdTe/TiO2复合材料对 304 不锈钢的阴极保护性能显著提高,且在闭光状态下仍能维持对不锈钢的保护,对不锈钢起到一定的延时保护效果。
英文摘要:
      Objective To study nano-CdTe/TiO2 composite material for photogenerated cathodic protection of 304 stainless steel. Methods TiO2 nanotubes were fabricated by anode oxidation method, and the CdTe deposition was prepared in the nanotubes by potentiodynamic deposition. By changing the acidity of the electrolyte, CdTe/TiO2 composites with the best optical properties were obtained. Scanning electron microscopy (SEM) and X ray diffraction (XRD) test were used to observe the surface morphology and phase characteristics of the composite materials. Using open circuit potential (OCP), amperometric J-t curve, tafel polarization curve and other electrochemical methods, the cathodic protection of 304 stainless steel was investigated. Results Under the visible light illumination, the open circuit potential of 304 stainless steel connected with the composite material could shift from ?190 mV to ?730 mV. The photocurrent density could reach 0.15 mA/cm2, after the light was turned off, the OCP of 304 kept ?350 mV, which was lower than its corrosion potential. It indicated that the composite material was capable of electron storage. Conclusion The cathodic protection performance of CdTe/TiO2 composite material was significantly improved compared with pure TiO2 in the visible range. And it could maintain the protection of stainless steel in dark environment. Comparing with TiO2, this material had the captivity of prolonging protection of the 304 stainless steel.
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