管靖远,陈泉志,马晓欣,唐仕光,黄祖江,李伟洲.添加硫酸铜对 TC4 钛合金微弧氧化膜性能的影响[J].表面技术,2015,44(12):62-68.
GUAN Jing-yuan,CHEN Quan-zhi,MA Xiao-xin,TANG Shi-guang,HUANG Zu-jiang,LI Wei-zhou.Effect of Adding Copper Sulfate to Micro-arc Oxidation on Properties of Coating on TC4 Ti Alloy[J].Surface Technology,2015,44(12):62-68
添加硫酸铜对 TC4 钛合金微弧氧化膜性能的影响
Effect of Adding Copper Sulfate to Micro-arc Oxidation on Properties of Coating on TC4 Ti Alloy
投稿时间:2015-07-06  修订日期:2015-12-20
DOI:10.16490/j.cnki.issn.1001-3660.2015.12.010
中文关键词:  TC4 钛合金  微弧氧化  CuSO4  着色剂  电压  氧化时间
英文关键词:TC4 Ti alloy  micro-arc oxidation  CuSO4  colorant  voltage  oxidation time
基金项目:国家自然科学基金 (51371059);广西自然科学基金(2014GXNSFCA118013,2010GXNSFD013006);广西高等学校高水平创新团队项目(第二批);广西自然科学基金创新研究团队项目(2011GXNSFF018001)
作者单位
管靖远 广西大学 材料科学与工程学院, 南宁 530004 
陈泉志 广西大学 材料科学与工程学院, 南宁 530004 
马晓欣 广西大学 材料科学与工程学院, 南宁 530004 
唐仕光 广西大学 材料科学与工程学院, 南宁 530004 
黄祖江 广西大学 材料科学与工程学院, 南宁 530004 
李伟洲 广西大学 材料科学与工程学院, 南宁 530004 
AuthorInstitution
GUAN Jing-yuan College of Materials Science and Engineering, Guangxi University, Nanning 530004, China 
CHEN Quan-zhi College of Materials Science and Engineering, Guangxi University, Nanning 530004, China 
MA Xiao-xin College of Materials Science and Engineering, Guangxi University, Nanning 530004, China 
TANG Shi-guang College of Materials Science and Engineering, Guangxi University, Nanning 530004, China 
HUANG Zu-jiang College of Materials Science and Engineering, Guangxi University, Nanning 530004, China 
LI Wei-zhou College of Materials Science and Engineering, Guangxi University, Nanning 530004, China 
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中文摘要:
      目的 研究 CuSO4 浓度和微弧氧化工艺参数(电压、氧化时间)对 TC4 钛合金微弧氧化膜颜色及性能的影响。 方法 在磷酸钠电解液中,对 TC4 钛合金进行微弧氧化处理,并添加 CuSO4 获得不同颜色的陶瓷膜,对氧化膜的宏观形貌、微观形貌、物相结构以及硬度进行分析。 结果 添加 CuSO4 能使陶瓷膜颜色变深,随着 CuSO4 浓度升高,膜层由灰色逐渐变为红褐色。 当 CuSO4 质量浓度为 0. 5 g/ L 时,氧化膜表面均匀致密,显微硬度最高(627. 1HV);当 CuSO4 质量浓度为 1. 5 g/ L 时,氧化膜显微硬度最低(382. 8HV)。 随着电压升高,膜层颜色加深,色泽更均匀,但表面硬度下降。 在 400 V 条件下制备的氧化膜硬度最低,但是色泽最均匀。 随着氧化时间的延长,氧化膜厚度增加,颜色加深,色泽更为均匀,但是当氧化时间超过 15 min 后,氧化膜颜色变浅。 结论 CuSO4 对微弧氧化膜的显色作用明显,其浓度及微弧氧化工艺参数(电压、氧化时间)均对涂层性能、色泽、致密性、厚度及相组成具有很大的影响。
英文摘要:
      Objective To investigate the effect of CuSO4 concentration and micro-arc oxidation process parameters (voltage, oxidation time) on the color and properties of the micro-arc oxidation coating. Methods TC4 titanium alloy was treated in sodium phosphate electrolyte to obtain a surface ceramic coating by using micro-arc oxidation technology. The macroscopic and microscopic morphology, phase structure and hardness of the oxidation coating were analyzed. Results By adding of CuSO4 of different concentrations, the color of coating samples was darkened which turned from gray to red-brown when the CuSO4 concentration was increased. The surface coating was uniformly dense with the highest microhardness of 627. 1HV when the concentration of CuSO4 was 0. 5 g / L. And the coating microhardness was decreased to the lowest 382. 8HV when the concentration of CuSO4 was 1. 5 g / L. With the increasing of voltage, the color of coating got deeper and more uniform, while the coating hardness decreased. The hardness of coating was the lowest and the color was the most uniform at 400 V. When the oxidation time was prolonged, the coating thickness was increased and the color became deeper and more uniform. However, the coating color tended to be lighter when the oxidation time was over 15 min. Conclusion CuSO4 has significant coloration effect on micro-arc oxidation coating and the concentration and process parameters (voltage, oxidation time) have great influence on performance, color, density, thickness and phase structure of the coating.
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