缪跃琼,林晨,高玉新,郑少梅,程虎.304 不锈钢低温离子渗氮及氮碳共渗处理[J].表面技术,2015,44(8):61-64,102.
MIAO Yue-qiong,LIN Chen,GAO Yu-xin,ZHENG Shao-mei,CHENG Hu.Low-temperature Plasma Nitriding and Plasma Nitrocarburing of 304 Stainless Steel[J].Surface Technology,2015,44(8):61-64,102
304 不锈钢低温离子渗氮及氮碳共渗处理
Low-temperature Plasma Nitriding and Plasma Nitrocarburing of 304 Stainless Steel
投稿时间:2015-01-10  修订日期:2015-08-20
DOI:10.16490/j.cnki.issn.1001-3660.2015.08.011
中文关键词:  304 不锈钢  离子渗氮  氮碳共渗  S 相  耐磨性能  耐蚀性能
英文关键词:304 stainless steel  plasma nitriding  nitrocarburizing  S-phase  wear resistance  corrosion resistance
基金项目:国家自然科学基金项目(51307091);浙江省科技计划项目(2013C1117);浙江省大学生科技计划项目(2015R430019)
作者单位
缪跃琼 台州学院 机械工程学院, 浙江 台州 318000 
林晨 台州学院 机械工程学院, 浙江 台州 318000 
高玉新 台州学院 机械工程学院, 浙江 台州 318000 
郑少梅 青岛理工大学 机械工程学院, 山东 青岛 266033 
程虎 台州学院 机械工程学院, 浙江 台州 318000 
AuthorInstitution
MIAO Yue-qiong College of Mechanical Engineering, Taizhou University, Taizhou 318000, China 
LIN Chen College of Mechanical Engineering, Taizhou University, Taizhou 318000, China 
GAO Yu-xin College of Mechanical Engineering, Taizhou University, Taizhou 318000, China 
ZHENG Shao-mei College of Mechanical Engineering, Qingdao Technological University, Qingdao 266033, China 
CHENG Hu College of Mechanical Engineering, Taizhou University, Taizhou 318000, China 
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中文摘要:
      目的 研究 304 不锈钢离子渗氮层和氮碳共渗层的组织、硬度及耐磨、耐蚀性能,并考察渗层的磨损机理。 方法 利用离子渗氮及氮碳共渗工艺在 304 不锈钢表面获得硬化层,利用 XRD,OM 及共聚焦显微镜、显微硬度仪、电化学测试仪,分析处理前后渗层的组织、相结构及渗层的硬度及耐磨耐蚀性能。结果 304 不锈钢氮碳共渗和渗氮层主要为 S 相层,在相同工艺条件下,氮碳共渗工艺获得的渗层为 γN+γC 的复合渗层,且厚度大于单一渗氮层。 渗氮层和氮碳共渗层硬度约为基体硬度的 3. 5 倍。 在干滑动摩擦条件下,氮碳共渗层比渗氮层具有更好的耐磨性能;渗氮层的磨损机理为磨粒磨损的犁沟效应和断裂,氮碳共渗层的磨损机理为磨粒磨损的犁沟和微切削。 电化学测试表明,渗氮层和氮碳共渗层的耐蚀性能均优于基体。 结论 304 不锈钢在 420 ℃进行离子渗氮和氮碳共渗处理后,硬度和耐磨性能可大幅提高,且氮碳共渗处理效果更佳。
英文摘要:
      Objective To study the microstructure, hardness and wear and corrosion properties of plasma nitrided and nitrocar-burized layers of 304 austenitic stainless steel, and investigate the wear mechanism of the layers. Methods A nitrided or nitrocar-burized layer was formed on 304 stainless steel substrate by low-temperature plasma nitriding (PN) or plasma nitrocarburizing (PNC) technique. The phase structure, hardness and wear and corrosion properties were comparatively analyzed with XRD, OM, microhardness tester and electrochemical measurement system. Results The nitrided or nitrocarburized layer consisted of expanded austenite (S-phase). The composite γN +γC layer was formed by PNC technique with larger thickness under the same process condition. The hardness of the two layers was 3. 5 times higher than that of the substrate. The wear property of nitrocarburized layer was better than that of the nitrided layer under dry sliding friction condition. The wear mechanism of PN layer was ploughing actions and fracture, while the wear mechanism of PNC layer was ploughing actions and micro-cutting. The corrosion resistance of both the nitrided and nitrocarburized layers was better than that of the substrate as revealed by electrochemical test. Conclusion PN and PNC treatment at 420 ℃ could effectively improve the hardness and wear resistance of 304 stainless steel, and the treatment of PNC was better.
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