宋东东,高瑾,李瑞凤,李晓刚.碳纳米管复合水性丙烯酸涂层的腐蚀性能研究[J].表面技术,2015,44(3):47-51.
SONG Dong-dong,GAO Jin,LI Rui-feng,LI Xiao-gang.Study on Corrosion Performance of Acrylic-based Waterborne Coating Containing Carbon Nanotubes[J].Surface Technology,2015,44(3):47-51
碳纳米管复合水性丙烯酸涂层的腐蚀性能研究
Study on Corrosion Performance of Acrylic-based Waterborne Coating Containing Carbon Nanotubes
投稿时间:2014-10-21  修订日期:2015-03-20
DOI:10.16490/j.cnki.issn.1001-3660.2015.03.008
中文关键词:  碳纳米管  水性涂料  EIS  附着力
英文关键词:carbon nanotube  waterborne coating  EIS  adhesion
基金项目:国家自然科学基金(51071027)
作者单位
宋东东 北京科技大学 腐蚀与防护中心, 北京 100083 
高瑾 北京科技大学 腐蚀与防护中心, 北京 100083 
李瑞凤 北京科技大学 腐蚀与防护中心, 北京 100083 
李晓刚 北京科技大学 腐蚀与防护中心, 北京 100083 
AuthorInstitution
SONG Dong-dong Corrosion and Protection Center, University of Science and Technology Beijing, Beijing 100083, China 
GAO Jin Corrosion and Protection Center, University of Science and Technology Beijing, Beijing 100083, China 
LI Rui-feng Corrosion and Protection Center, University of Science and Technology Beijing, Beijing 100083, China 
LI Xiao-gang Corrosion and Protection Center, University of Science and Technology Beijing, Beijing 100083, China 
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中文摘要:
      目的 制备碳纳米管复合水性丙烯酸涂层,探索分析碳纳米管含量对涂层力学和防腐性能的影响规律。 方法 采用高速球磨方式制备 3% ,1% ,0. 5% 三种含量(以质量分数计)的碳纳米管复合涂层,对涂层附着力、耐冲击性、耐弯曲性等力学性能进行测试,以电化学阻抗技术来评价碳纳米管复合涂层的防腐性能。 结果 添加碳纳米管显著提高了涂层的附着力,并且随着碳纳米管含量的增加,附着力上升;其他力学性能,如耐冲击性、耐弯曲性,在不同含量下均保持良好。 对改性和未改性的涂层进行了电化学阻抗测试,其中 1% 的碳纳米管涂层电化学性能最优,在浸泡 36 h 后,未改性涂层低频区阻抗模值| Z | 0. 01为 2. 5×103 Ω·cm2,0. 5% 的碳纳米管涂层为 1. 1×106 Ω·cm2,1% 的为 1. 4×108 Ω·cm2,3% 的为 7×102Ω·cm2。 结论 由于碳纳米管本身的纳米效应,在较低含量时即可提高涂层的性能,并存在最优含量,超过此含量后性能有所下降。
英文摘要:
      Objective To develop an acrylic-based waterborne coating system by using MWCNT as the additive and examine the effect of the carbon nanotube content on the mechanical property and corrosion resistance of the coating. Methods The MWCNTs were dispersed in the acrylic resin by high-speed ball-milling. And acrylic composite coatings containing 0, 0. 5, 1, 3wt% MWCNT were prepared. The mechanical property and corrosion resistance of the coatings were evaluated using mechanical tests such as adhesion, impact resistance, bending resistance, and electrochemical impedance spectroscopy (EIS). Results The addition of carbon nanotubes obviously increased the adhesion of the coating, and the adhesion increased with increasing MWCNT content in the acrylic composite coatings, and there was no loss in other mechanical properties such as impact resistance and bending resistance at different MWCNT contents. Electrochemical impedance tests on the modified and unmodified coatings revealed that the coating containing 1% carbon nanotubes had the best electrochemical property. After 36 h immersion in 3. 5 wt% NaCl, the total impedance magnitude ( | Z | ) at 0. 01 Hz of acrylic coating and 0. 5% , 1% , 3% composite coating was 2. 5×103 Ω·cm2 , 1. 1×106 Ω· cm2, 1. 4×108 Ω·cm2 and 7×102 Ω·cm2 , respectively. Conclusion Due to the nano effect of the carbon nanotubes, the performance of the coating could be improved by low content of carbon nanotubes, but there was an optimal content, if the content exceeded this value the performance would decrease.
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