王莉容,陈小明,吴燕明,周夏凉,赵鹏,王胄.HVAP 及 HVOF 工艺制备 WC10Co4Cr 复合涂层及其性能研究[J].表面技术,2015,44(2):14-18.
WANG Li-rong,CHEN Xiao-ming,WU Yan-ming,ZHOU Xia-liang,ZHAO Peng,WANG Zhou.Properties of WC10Co4Cr Composite Coatings Prepared Using HVAP and HVOF Technologies[J].Surface Technology,2015,44(2):14-18 |
| HVAP 及 HVOF 工艺制备 WC10Co4Cr 复合涂层及其性能研究 |
| Properties of WC10Co4Cr Composite Coatings Prepared Using HVAP and HVOF Technologies |
| 投稿时间：2014-08-29 修订日期：2015-02-20 |
| DOI：10.16490/j.cnki.issn.1001-3660.2015.02.003 |
| 中文关键词: 超音速等离子喷涂 WC10Co4Cr 涂层 电化学特性 |
| 英文关键词:high velocity air plasma WC10Co4Cr coating electrochemical property |
| 基金项目:国家“948冶项目(201218);浙江省科技计划项目(2013C31044) |
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| Author | Institution |
| WANG Li-rong | 1. Standard & Quality Control Research Institute, Ministry of Water Resources,Hangzhou 310012, China;2. Hangzhou Mechanical Research Institute, Ministry of Water Resources, Hangzhou 310012, China |
| CHEN Xiao-ming | 1. Standard & Quality Control Research Institute, Ministry of Water Resources,Hangzhou 310012, China;2. Hangzhou Mechanical Research Institute, Ministry of Water Resources, Hangzhou 310012, China |
| WU Yan-ming | Standard & Quality Control Research Institute, Ministry of Water Resources,Hangzhou 310012, China; |
| ZHOU Xia-liang | Standard & Quality Control Research Institute, Ministry of Water Resources,Hangzhou 310012, China; |
| ZHAO Peng | Hangzhou Mechanical Research Institute, Ministry of Water Resources, Hangzhou 310012, China |
| WANG Zhou | Hangzhou Mechanical Research Institute, Ministry of Water Resources, Hangzhou 310012, China |
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| 中文摘要: |
| 目的 对比研究超音速等离子喷涂 ( HVAP) 技术与超音速火焰喷涂 ( HVOF) 技术制备WC10Co4Cr 涂层,并根据涂层组织形貌与电化学特性判断两种工艺的优劣。 方法 采用 SEM 及 XRD 分析 WC10Co4Cr 复合涂层的微观形貌和物相,在 3. 5% (质量分数)NaCl 溶液中对涂层进行电化学分析。结果 WC10Co4Cr 涂层由较大的 WC 颗粒及粘结相组成,在喷涂过程中 WC 颗粒不断累积形成层片状结构,涂层有较小程度的失碳,形成了具有脆性的 W2C。 电化学极化测试表明,超音速等离子喷涂技术制备的涂层表现出优异的抗电化学腐蚀性能。 结论 超音速等离子喷涂技术制备的 WC10Co4Cr 涂层显微硬度为 1197HV,孔隙率为 0. 50% ,腐蚀电位为-0. 3947 V,腐蚀电流密度为 9. 19×10-7 A/ cm2,腐蚀速率为1. 01×10-2 g/ (m2·h),腐蚀深度为 1. 09×10-2 mm/ a,具有与超音速火焰喷涂涂层相似的耐腐蚀性能。 |
| 英文摘要: |
| Objective WC10Co4Cr coatings prepared by high velocity air plasma (HVAP) and high velocity oxy-fuel spraying (HVOF) were comparatively studied, and the advantages and disadvantages of the two technologies were judged by the morphology and electrochemical property of the coatings prepared. Methods The microstructure and phase constitution of the WC10Co4Cr composite coatings were analyzed by SEM and XRD, and the electrochemical analysis of the coatings was performed in 3. 5% (mass fraction) NaCl solution. Results The morphology results showed that the coatings were composed of relatively large WC ceramic particles and metallic binders, and lamellar structures were formed during the coating process by the steady accumulation of WC particles. The coatings showed a small degree of carbon loss, and formed W2C with brittleness. The potentiodynamic polarization test revealed that the WC10Co4Cr coating prepared by HVAP showed excellent electrochemical corrosion resistance. Conclusion The WC10Co4Cr coating prepared by HVAP had a microhardness of 1197HV, a porosity of 0. 50% , a corrosion potential of -0. 3947 V, a corrosion current density of 9. 19×10 -7 A / cm2 , a corrosion rate of 1. 01×10 -2 g / (m2 ·h), and a corrosion depth of 1. 09×10 -2 mm / a, and showed a similar corrosion resistance with the coating prepared by HVOF. |
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