马琳,叶剑波,黄国创,王臻,周鑫发,武敏,陈卫祥.SnS2 -SnO2 / 石墨烯复合材料的合成及其电化学储锂性能的研究[J].表面技术,2015,44(1):8-14.
MA Lin,YE Jian-bo,HUANG Guo-chuang,WANG Zhen,ZHOU Xin-fa,WU Min,CHEN Wei-xiang.Synthesis and Electrochemical Li-storage Performance of SnS2-SnO2 / Graphene Composites[J].Surface Technology,2015,44(1):8-14 |
| SnS2 -SnO2 / 石墨烯复合材料的合成及其电化学储锂性能的研究 |
| Synthesis and Electrochemical Li-storage Performance of SnS2-SnO2 / Graphene Composites |
| 投稿时间：2014-12-15 修订日期：2015-01-20 |
| DOI： |
| 中文关键词: 二硫化锡 二氧化锡 石墨烯 复合纳米材料 锂离子电池 |
| 英文关键词:tin disulfide tin oxide graphene nanocomposites Li-ion battery |
| 基金项目:国家自然科学基金项目(21473156);科技部国际合作专项(2012DFG42100);浙江省重大科技计划专项项目(2013C01077);岭南师范学院创新强校工程项目(0003014010) |
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| Author | Institution |
| MA Lin | 1. Lingnan Normal University, Zhanjiang 524048, China; 2. Department of Chemistry, Zhejiang University,Hangzhou 310027, China; |
| YE Jian-bo | Department of Chemistry, Zhejiang University,Hangzhou 310027, China; |
| HUANG Guo-chuang | Department of Chemistry, Zhejiang University,Hangzhou 310027, China; |
| WANG Zhen | Department of Chemistry, Zhejiang University,Hangzhou 310027, China; |
| ZHOU Xin-fa | Zhejiang Institute of Energy, Hangzhou 310021, China |
| WU Min | Zhejiang Institute of Energy, Hangzhou 310021, China |
| CHEN Wei-xiang | Zhejiang Institute of Energy, Hangzhou 310021, China |
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| 中文摘要: |
| 目的 制备高容量和循环性能稳定的锂离子电池复合电极材料。 方法 通过 L-半胱氨酸(L-cys)辅助水热法合成 SnS2-SnO2 / 石墨烯复合纳米材料,采用 XRD,SEM,TEM 和 HRTEM 技术对其进行结构表征,并采用循环伏安、恒流充放电和电化学阻抗技术研究了其电化学贮锂性能。 结果 随着水热溶液中 L-cys 的量增加,复合材料中少层数结构 SnS2 的含量也增加。 当 Sn4+ / L-cys 的物质的量之比为 1 : 4时,制得了 SnS2 / 石墨烯复合纳米材料,而且石墨烯的存在在一定程度上抑制了 SnS2 沿 c 轴方向的生长,减少了层状 SnS2 的层数。 结论 由于二维层状结构的 SnS2 具有与石墨烯类似的微观结构和形貌,与石墨烯的复合具有更好的匹配性和相互协同效应,增强了 SnS2 / 石墨烯复合材料的电化学贮锂性能,使其具有较高的可逆储锂容量、良好的循环性能和增强的倍率特性。 |
| 英文摘要: |
| Objective To prepare the nanomaterials with high specific capacity and stable cyclic performance as Li-ion battery anode. Methods The SnO2-SnS2 / GNS composites were prepared by an L-cys-assisted hydrothermal method and characterized by XRD, SEM, TEM and HRTEM. The electrochemical performances of the composites for reversible lithium storage were measured by cyclic voltammogram, galvanostatic charge / discharge and electrochemical impedance spectroscopy. Results With the increasing amount of L-cys in the hydrothermal solution, the content of SnS2 in the low-rise structure of the composite material also increased. The SnS2 / graphene nanocomposite could be prepared when the molar ratio of Sn4+ / L-cys was 1 : 4. The presence of graphene inhibited the growth of SnS2 along the c-axis direction to some extent, and reduced the layer number of the layered SnS2 . Conclusion Because the two-dimensional layered SnS2 had similar morphology and microstructure to graphene, the compositing of the layered SnS2 with graphene exhibited better synergetic effects. Therefore, the SnS2 / graphene nanocomposite showed a high reversible specific capacity with stable cyclic performance and enhanced rate capability. |
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