李峰,张建周,马慧媛,刘慧丛,朱立群.稀土盐对铝合金硼硫酸阳极氧化膜层性能的影响[J].表面技术,2014,43(6):95-99.
LI Feng,ZHANG Jian-zhou,MA Hui-yuan,LIU Hui-cong,ZHU Li-qun.Study on Impact of Rare Earth Salts on the Properties of Aluminum Alloy Anodic Oxidation Film Prepared in Boron Sulfuric Acid Solution[J].Surface Technology,2014,43(6):95-99
稀土盐对铝合金硼硫酸阳极氧化膜层性能的影响
Study on Impact of Rare Earth Salts on the Properties of Aluminum Alloy Anodic Oxidation Film Prepared in Boron Sulfuric Acid Solution
投稿时间:2014-06-30  修订日期:2014-12-10
DOI:
中文关键词:  铝合金  硼硫酸阳极氧化  稀土盐  代铬氧化  氧化膜层  耐腐蚀性能
英文关键词:aluminum alloy  boron sulfuric acid anodic oxidation  rare earth salt  anodic oxidation without chromic acid  anodic oxidation film  anti-corrosion property
基金项目:
作者单位
李峰 西安飞行自动控制研究所, 西安 710065 
张建周 西安飞行自动控制研究所, 西安 710065 
马慧媛 北京航空航天大学 材料科学与工程学院, 北京 100191 
刘慧丛 北京航空航天大学 材料科学与工程学院, 北京 100191 
朱立群 北京航空航天大学 材料科学与工程学院, 北京 100191 
AuthorInstitution
LI Feng Xi'an Flight Automatic Control Research Institute, Xi'an 710065, China 
ZHANG Jian-zhou Xi'an Flight Automatic Control Research Institute, Xi'an 710065, China 
MA Hui-yuan School of Materials Science and Engineering, Beihang University, Beijing 100191, China 
LIU Hui-cong School of Materials Science and Engineering, Beihang University, Beijing 100191, China 
ZHU Li-qun School of Materials Science and Engineering, Beihang University, Beijing 100191, China 
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中文摘要:
      目的 研究代替铬酸阳极氧化和稀铬酸氧化膜层封闭处理的工艺。 方法 在硼硫酸阳极氧化溶液中添加不同的稀土盐对铝合金进行阳极氧化,采用稀土盐对氧化膜层进行封闭处理,分析对比膜质量及膜层耐腐蚀性能。 结果 在硼硫酸阳极氧化溶液中加入稀土 A 盐能够提高氧化膜层的耐腐蚀性能,用稀土 C 盐溶液对该阳极氧化膜层进行封闭处理,可以进一步提高氧化膜层的耐腐蚀性能,耐中性盐雾腐蚀时间达到 336 h。 结论 稀土 A 盐改进的硼硫酸阳极氧化/ C 盐封闭技术有望代替铬酸阳极氧化技术。
英文摘要:
      Objective To study the technology of anodic oxidation without chromate acid and sealing the oxidation film without dilute chromic acid. Methods The anodic oxidation film was prepared in the boron sulfuric acid anodic oxidation solution containing different rare earth salts, and then sealed in solutions containing rare earth salts. The film quality and corrosion resistance of the films were comparatively analyzed. Results Adding rare earth A salt into boron sulfuric acid anodic oxidation solution could improve the anti-corrosion property of the oxidation film, and sealing the as-prepared anodic oxidation film with rare earth C salt could further improve the anti-corrosion property of the oxidation film. This film could be intact after being placed for 336 h in NSS environment. Conclusion The boron sulfuric acid anodic oxidation modified by rare earth A salt and sealed by rare earth C salt is expected to replace the chromic acid anodizing technology.
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