张译文,李垚,强亮生,郝健,刘旭松,安小坤,赵九蓬.电沉积乙炔黑 / 锗材料及其性能研究[J].表面技术,2014,43(6):11-15.
ZHANG Yi-wen,LI Yao,QIANG Liang-sheng,HAO Jian,LIU Xu-song,AN Xiao-kun,ZHAO Jiu-peng.Research on the Properties of Acetylene Black/ Ge Prepared by Electrochemical Deposition[J].Surface Technology,2014,43(6):11-15
电沉积乙炔黑 / 锗材料及其性能研究
Research on the Properties of Acetylene Black/ Ge Prepared by Electrochemical Deposition
投稿时间:2014-06-14  修订日期:2014-12-10
DOI:
中文关键词:  锂离子电池  负极  乙炔黑/ 锗  电化学性能
英文关键词:lithium-ion battery  negative electrode  acetylene black/ Ge  electrochemical properties
基金项目:
作者单位
张译文 哈尔滨工业大学 理学院, 哈尔滨 150001 
李垚 哈尔滨工业大学 复合材料与结构研究所,哈尔滨 150001 
强亮生 哈尔滨工业大学 理学院, 哈尔滨 150001 
郝健 哈尔滨工业大学 化工学院,哈尔滨 150001 
刘旭松 哈尔滨工业大学 化工学院,哈尔滨 150001 
安小坤 哈尔滨工业大学 化工学院,哈尔滨 150001 
赵九蓬 哈尔滨工业大学 化工学院,哈尔滨 150001 
AuthorInstitution
ZHANG Yi-wen School of Science, Harbin Institute of Technology, Harbin 150001, China 
LI Yao Center for Composite Material, Harbin Institute of Technology, Harbin 150001, China 
QIANG Liang-sheng School of Science, Harbin Institute of Technology, Harbin 150001, China 
HAO Jian School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001, China 
LIU Xu-song School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001, China 
AN Xiao-kun School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001, China 
ZHAO Jiu-peng School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001, China 
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中文摘要:
      目的 提高锂离子电池锗基材料的电化学性能。 方法 采用电泳和离子液体电沉积制备乙炔黑/ 锗负极材料,用 SEM,Raman 和充放电循环等手段表征其结构和性能。 结果 乙炔黑/ 锗负极材料在0. 2C 倍率下循环 100 次,比容量依然可达到 600 mAh/ g 以上。 结论 乙炔黑/ 锗负极材料的电化学性能明显优于单独锗材料和碳材料。
英文摘要:
      Objective To improve the electrochemical performance of the germanium materials of lithium-ion batteries. Methods Germanium nanoparticles (Ge-NPs) and acetylene black anodes were fabricated through electrodeposition of Ge in the new-genera-tion ionic liquids on the surface of acetylene black which was electrophoretically deposited on a copper current collector. The structure and electrochemical properties were characterized by electron microscopy, Raman spectroscopy and constant current chargedischarge methods. Results The acetylene black-Ge nanocomposite exhibited the electrochemical cycling properties of over 600 mAh/ g at 0. 2C after 100 cycles. Conclusion The electrochemical performance of composite was obviously better than Ge or acetylene black by itself as anode electrode material.
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