高洁荣,刘成岑,赵彦生,郑玉刚.MMA 防水涂料固化反应过程热分析及表面封闭剂的选择[J].表面技术,2012,(6):111-114,121.
GAO Jie-rong,LIU Cheng-cen,ZHAO Yan-sheng,ZHENG Yu-gang.Thermal Analysis and Surface Blocker Choice ofMMA Waterproof Coating Curing[J].Surface Technology,2012,(6):111-114,121
MMA 防水涂料固化反应过程热分析及表面封闭剂的选择
Thermal Analysis and Surface Blocker Choice ofMMA Waterproof Coating Curing
投稿时间:2012-07-12  修订日期:2012-12-20
DOI:
中文关键词:  MMA 防水涂料  甲基丙烯酸甲酯  丙烯酸丁酯  VOC  常温固化
英文关键词:MMA waterproof coating  methyl methacrylate  butyl acrylate  VOC  normal temperature curing
基金项目:
作者单位
高洁荣 太原理工大学化学化工学院, 太原030024 
刘成岑 太原理工大学化学化工学院, 太原030024 
赵彦生 太原理工大学化学化工学院, 太原030024 
郑玉刚 太原理工大学化学化工学院, 太原030024 
AuthorInstitution
GAO Jie-rong College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China 
LIU Cheng-cen College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China 
ZHAO Yan-sheng College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China 
ZHENG Yu-gang College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China 
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中文摘要:
      以甲基丙烯酸甲酯( MMA)、丙烯酸丁酯( BA)、过氧化二苯甲酰( BPO) 及N-N 二甲基苯胺(DMA)为原料,合成了一种新型无溶剂防水涂料。采用DTA-TG 联用技术,结合涂膜性能,对反应热力学过程进行了研究。通过对反应过程中质量损失及反应热的探讨,选择了蜡类表面封闭助剂改善涂层固化初期由于热效应导致的严重质量损失现象。实验表明,加入适量固体蜡可改善涂膜性能,显著降低MMA 防水涂料在使用过程中的VOC 排放量,保证MMA/ BA 成膜的反应完全性。
英文摘要:
      MMA waterproof coating based on the self-restraint acrylic pre-polymer, methyl methacrylate, butyl acrylate, BPO and DMA were prepared. The thermodynamics of process were invested through DTA-TG and properties of film. Mass loss and reaction heat were studied. Solid paraffin as surface blocker was introduced to ameliorate the weight loss of coating in solidification process. The results show that moderate solid paraffin can improve the performance of the coating,reduce the emission of VOC in using MMA waterproof coating and ensure completeness and application performance of the reaction.
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