杨旭,李兰兰,贺建,张丁非,潘复生.镁合金的微观结构对其上制备植酸转化膜的影响[J].表面技术,2012,(4):27-30,62.
YANG Xu,LI Lan-lan,HE Jian,ZHANG Ding-fei,PAN Fu-sheng.The Effect of Microstructure of Magnesium Alloys on Preparation of Phytic Acid Conversion Coatings.Surface Technology,2012,(4):27-30,62.
镁合金的微观结构对其上制备植酸转化膜的影响
The Effect of Microstructure of Magnesium Alloys on Preparation of Phytic Acid Conversion Coatings
投稿时间:2012-04-25  修订日期:2012-08-20
DOI:
中文关键词:  镁合金  微观结构  植酸  转化膜
英文关键词:magnesium alloys  microstructure  phytic acid  conversion coatings
基金项目:重庆市科技攻关项目(CSTC,2010AB5116)
作者单位
杨旭 第三军医大学化学教研室,重庆400038 
李兰兰 第三军医大学化学教研室,重庆400038 
贺建 第三军医大学化学教研室,重庆400038 
张丁非 重庆大学材料科学与工程学院,重庆400044 
潘复生 重庆大学材料科学与工程学院,重庆400044 
AuthorInstitution
YANG Xu Chemistry Department, Third Military Medical University, Chongqing 400038, China 
LI Lan-lan Chemistry Department, Third Military Medical University, Chongqing 400038, China 
HE Jian Chemistry Department, Third Military Medical University, Chongqing 400038, China 
ZHANG Ding-fei College of Materials Science and Engineering, Chongqing University, Chongqing 400044, China 
PAN Fu-sheng College of Materials Science and Engineering, Chongqing University, Chongqing 400044, China 
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中文摘要:
      采用浸没法,以纯Mg及AZ91D,AZ61,ZK60,ZM21镁合金为基体材料,在植酸水溶液中制备植酸转化膜。观察了植酸转化膜的形貌,分析了转化膜的元素组成及浓度分布,进而研究了镁合金的微观结构对制备表面植酸转化膜的影响。结果表明:合金元素对植酸转化膜的形成起着决定性的作用,高价合金元素(Al和Zr)比低价合金元素(Zn和Mn)更有利于植酸转化膜的形成,以固溶体存在的Al比以化合态(Mg17Al12)存在的Al更有利于转化膜的形成。
英文摘要:
      To study the influence of microstructure of magnesium alloys on preparation of phytic acid conversion coatings, the phytic acid coatings were prepared on AZ91D,AZ61,ZK60,ZM21 magnesium alloys in phytic acid aqueous solution by immersion method, and pure magnesium were used to compare. The surface morphologies of conversion coating were observed, and surface element compositions and concentration distribution of conversion coating were analyzed, and the effect of the microstructure on preparation of phytic acid conversion coating was studied. The results show that alloying elements play a definitive role in forming conversion coatings. Tetravalent and trivalent alloying elements are more helpful than divalent alloying elements. Alloying elements dissolved in the magnesium matrix(alpha-phase)are more beneficial for forming coatings than that in the second-p hase.
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