陈庚,屈钧娥,刘少波,王海人,聂德键.溶剂中水对2024铝合金表面膦酸自组装膜缓蚀性能的影响[J].表面技术,2012,(2):5-7,60.
CHEN-Geng,QU Jun-e,LIU Shao-bo,WANG Hai-ren,,NIE De-jian.Effect of Water in the Solvent on the Corrosion Inhibition Performance of TDPA SAMs on the Surface of 2024 Aluminum Alloy[J].Surface Technology,2012,(2):5-7,60
溶剂中水对2024铝合金表面膦酸自组装膜缓蚀性能的影响
Effect of Water in the Solvent on the Corrosion Inhibition Performance of TDPA SAMs on the Surface of 2024 Aluminum Alloy
投稿时间:2011-12-19  修订日期:2012-04-20
DOI:
中文关键词:  2024铝合金  膦酸自组装膜  自组装行为  缓蚀性能
英文关键词:2024 aluminum alloy  TDPASAMs  self-assembly behavior  corrosion inhibition performance
基金项目:国家自然科学基金(51001045);湖北省自然科学基金(2009CDB347)
作者单位
陈庚 湖北大学材料科学与工程学院,武汉430062 
屈钧娥 湖北大学材料科学与工程学院,武汉430062 
刘少波 湖北大学材料科学与工程学院,武汉430062 
王海人 湖北大学材料科学与工程学院,武汉430062 
聂德键 湖北大学材料科学与工程学院,武汉430062 
AuthorInstitution
CHEN-Geng Faculty of Materials Science and Engineering, Hubei University, Wuhan 430062, China 
QU Jun-e Faculty of Materials Science and Engineering, Hubei University, Wuhan 430062, China 
LIU Shao-bo Faculty of Materials Science and Engineering, Hubei University, Wuhan 430062, China 
WANG Hai-ren, Faculty of Materials Science and Engineering, Hubei University, Wuhan 430062, China 
NIE De-jian Faculty of Materials Science and Engineering, Hubei University, Wuhan 430062, China 
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中文摘要:
      以无水乙醇以及无水乙醇和水的混合液作为溶剂,分别配制5mmol/L的十四烷基膦酸溶液,并采用浸泡法在2024铝合金表面制备了十四烷基膦酸自组装膜。根据接触角、动电位扫描、交流阻抗以及腐蚀形貌分析,研究了采用不同溶剂时十四烷基膦酸自组装膜对Harrison溶液中2024铝合金的缓蚀作用,探讨了溶剂中水对膜自组装行为及缓蚀性能的影响机理。
英文摘要:
      Two kinds of 5mmol/L 1-tetradecylphosphonic acid(TDPA) solutions were prepared using absolute ethyl alcohol and a mixture of absolute ethyl alcohol and distilled water as the solvent respectively. Then TDPA SAMs(self-assembledmonolayers)were formed on 2024 aluminum alloy surface by immersion in these two solutions. The corrosion inhibition performance of TDPA SAMs prepared in different solvent for the 2024 aluminum alloy in the Harrison solutions was investigated by contact angle, potentiodynamic scan, EIS(electrochemical impedance spectrum) and corrosion morphology analysis. And the influence mechanism of water in the solvent on the self-assembly behavior and the corrosion inhibition performance of the inhibitor molecules were discussed also.
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