王国凡,苗磊,罗辉,张维义.紫铜表面渗铝层的高温抗氧化性能[J].表面技术,2008,37(3):19-21.
WANG Guo-fan,MIAO Lei,LUO Hui,ZHANG Wei-yi.Oxidation Resistance of Aluminized Layer on Red Copper at Hight Temperature[J].Surface Technology,2008,37(3):19-21
紫铜表面渗铝层的高温抗氧化性能
Oxidation Resistance of Aluminized Layer on Red Copper at Hight Temperature
投稿时间:2008-03-04  修订日期:2008-06-10
DOI:
中文关键词:  紫铜  渗铝层  高温氧化  氧化铝膜  光学分析
英文关键词:Red copper  Aluminized coating  High-temperature oxidation  Al203 scale  Optical analysis
基金项目:山东省自然科学基金资助项目( Y2005F18)
作者单位
王国凡 山东建筑大学材料科学与工程学院,山东济南250101 
苗磊 山东建筑大学材料科学与工程学院,山东济南250101 
罗辉 山东建筑大学材料科学与工程学院,山东济南250101 
张维义 山东建筑大学材料科学与工程学院,山东济南250101 
AuthorInstitution
WANG Guo-fan College of Materials Science and Engineering, Shandong Jianzhu University, Jinan 250101, China 
MIAO Lei College of Materials Science and Engineering, Shandong Jianzhu University, Jinan 250101, China 
LUO Hui College of Materials Science and Engineering, Shandong Jianzhu University, Jinan 250101, China 
ZHANG Wei-yi College of Materials Science and Engineering, Shandong Jianzhu University, Jinan 250101, China 
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中文摘要:
      采用粉末包装法在紫铜表面渗铝。研究了紫铜和渗铝后的紫铜在空气中的高温氧化行为。用扫描电子显微镜( SEM)和X射线衍射仪(XRD)观察、分析了氧化膜的微观形貌和相组成,并讨论其氧化机理。结果表明:紫铜渗铝后不仅提高了高温抗氧化性能,而且氧化行为及其氧化层的结构也发生了变化。未渗铝的紫铜试样700℃氧化100 h后相组成为Cu2O和CuO,而渗铝后试样表面优先形成Al2 03氧化膜。氧化动力学曲线为抛物线型。
英文摘要:
      Red copper was aluminized by means of pack cementation. The oxidation behavior of red copper and aluminized copper in air at high temperature was investigated. The micromorphology and phase composition of the formed oxide scales were examined by SEM and XRD, and the oxidation mechanism was discussed. The results indicate that the oxidation resistance of Cu is significantly improved by aluminizing treatment. The oxidation behavior and the structure of the oxide scale were changed after red copper was aluminized, too. After oxidation at 7000C for lOOh, the formed oxide scale on red copper consists of Cu20, Cuo and that on aluminized Cu is mainly composed of Al203. The oxidation kinetic curves follow parabolic rate law.
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