李道华.镍镀层表面钼酸盐一磷酸盐阴极彩色配合物膜的光电子能谱表征[J].表面技术,2008,37(2):26-27,36.
LI Dao-hua.Photoelectron Spectrometer Characterization on the Colored Coordination Compound Films of Molybdate-inorganic Phosphates on Nickel Plate[J].Surface Technology,2008,37(2):26-27,36 |
| 镍镀层表面钼酸盐一磷酸盐阴极彩色配合物膜的光电子能谱表征 |
| Photoelectron Spectrometer Characterization on the Colored Coordination Compound Films of Molybdate-inorganic Phosphates on Nickel Plate |
| 投稿时间：2007-10-29 修订日期：2008-04-10 |
| DOI： |
| 中文关键词: 镍镀层 阴极彩色配合物着色膜 钼酸盐．磷酸盐 光电子能谱 结构表征 |
| 英文关键词:Nickel plate Colored coordination compound films Molybdate-inorganic phosphates Photoelectron spectroscopy Structure characterization |
| 基金项目:四川省教育厅资助科研项目(20068075)；内江师范学院自然科学基金资助项目(200604) |
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| 中文摘要: |
| 为了赋予金属表面美观的外表，提高表面的光洁度和清洁度，增强金属的抗腐蚀性能，用含Mo、P的钼酸盐．磷酸盐着色液对镍镀层进行阴极着色处理，得到蓝紫色、金黄色、绿色和草绿色等多种不溶性的彩色配合物着色膜，膜层具有良好的装饰性能。光电子能谱(XPS和AES)分析结果表明，膜层的厚度分别为300、175、80、120nm，膜层中Mo以+6、+4价共存，P为+5价。从其AES深度剥蚀曲线的组成恒定区求得金黄色膜层的组成约为：26. 60-/oMo、11.8 0-/oP、5.30-/oNa、56.3 0-100。 |
| 英文摘要: |
| In order to give the appearance of the metal surface and improve the surface finish and cleanliness, reinforce metal corrosion resistance, by means of the interface reactions of nickel plate surface, insoluble coordination compound films were formed with a metallic luster of various colors changing in accordance with the reaction time. The films are functional finishing layers , possessing not only decorative properties, but also improving the brightness and clealiness of the metal surface. The results of the photoelectron spectrometer ( XPS and AES) analyses show that the thicknesses of the films are about 300, 175, 80 and 120 nm. Mo existed as +6, +4 in the film, and P existed as +5. The elemental compositions in golden-yellow film were caculated on the AES depth profile curves : M0 26. 60-/o ,P 11. 80-/o , Na 5. 30-/o , 0 56. 3 0-10 . |
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